Highly dense red mud shields for x-ray and gamma-ray attenuation
US-2024018050-A1 · Jan 18, 2024 · US
US11542203B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11542203-B2 |
| Application number | US-202017626064-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 17, 2020 |
| Priority date | Jul 18, 2019 |
| Publication date | Jan 3, 2023 |
| Grant date | Jan 3, 2023 |
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A cubic boron nitride sintered material includes: 20 to 80 volume % of cBN grains; and 20 to 80 volume % of a binder phase, wherein the binder phase includes first binder grains and second binder grains, in each of the first binder grains, a ratio of the number of atoms of the first metal element to a total of the number of atoms of the titanium and the number of atoms of the first metal element is more than or equal to 0.01% and less than 10%, in each of the second binder grains, this ratio is more than or equal to 10% and less than or equal to 80%, and in an X-ray diffraction spectrum of the cubic boron nitride sintered material, one or both of conditions 1 and 2 are satisfied.
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The invention claimed is: 1. A cubic boron nitride sintered material comprising: more than or equal to 20 volume % and less than or equal to 80 volume % of cubic boron nitride grains; and more than or equal to 20 volume % and less than or equal to 80 volume % of a binder phase, wherein the binder phase includes first binder grains and second binder grains, each of the first binder grains and the second binder grains includes one compound composed of titanium, at least one first metal element selected from a group consisting of zirconium, hafnium, a group 5 element, a group 6 element in a periodic table, and aluminum, and one or both of nitrogen and carbon, in each of the first binder grains, a ratio of the number of atoms of the first metal element to a total of the number of atoms of the titanium and the number of atoms of the first metal element is more than or equal to 0.01% and less than 10%, in each of the second binder grains, a ratio of the number of atoms of the first metal element to a total of the number of atoms of the titanium and the number of atoms of the first metal element is more than or equal to 10% and less than or equal to 80%, in an X-ray diffraction spectrum of the cubic boron nitride sintered material, one or both of the following conditions 1 and 2 are satisfied, the condition 1 is such a condition that 2θ of a first A peak originated from a (220) plane of the first binder grain falls within a range of more than or equal to 59.9° and less than or equal to 62.3°, 2θ of a second A peak originated from a (220) plane of the second binder grain falls within a range of more than or equal to 56.3° and less than or equal to 65.8°, and peak positions of the first A peak and the second A peak are different from each other, and the condition 2 is such a condition that 2θ of a first B peak originated from a (222) plane of the first binder grain falls within a range of more than or equal to 75.4° and less than or equal to 78.7°, 2θ of a second B peak originated from a (222) plane of the second binder grain falls within a range of more than or equal to 70.6° and less than or equal to 83.5°, and peak positions of the first B peak and the second B peak are different from each other. 2. The cubic boron nitride sintered material according to claim 1 , wherein in the X-ray diffraction spectrum of the cubic boron nitride sintered material, a half width of a second C peak originated from a (200) plane of the second binder grain is more than or equal to 0.1° and less than 1°. 3. The cubic boron nitride sintered material according to claim 1 , wherein in the X-ray diffraction spectrum of the cubic boron nitride sintered material, a half width of a second C peak originated from a (200) plane of the second binder grain is more than or equal to 0.1° and less than 0.6°. 4. The cubic boron nitride sintered material according to claim 1 , wherein the first metal element consists of at least one metal element selected from a group consisting of zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. 5. The cubic boron nitride sintered material according to claim 1 , wherein the first metal element consists of one or both of zirconium and niobium. 6. The cubic boron nitride sintered material according to claim 1 , wherein a content ratio of the cubic boron nitride grains is more than or equal to 35 volume % and less than or equal to 75 volume %. 7. The cubic boron nitride sintered material according to claim 1 , wherein a ratio of a mass of the first binder grains to a total mass of the first binder grains and the second binder grains is more than or equal to 10% and less than or equal to 95%.
Titanium carbides · CPC title
Flame, plasma or melting treatment · CPC title
Carbonitrides, e.g. titanium carbonitride, zirconium carbonitride · CPC title
micrometer sized, i.e. from 1 to 100 micron · CPC title
Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof · CPC title
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