Resistivity adjustment device and resistivity adjustment method

Patent metadata

Field	Value
Publication number	US-11542185-B2
Application number	US-201716324973-A
Country	US
Kind code	B2
Filing date	Aug 10, 2017
Priority date	Aug 12, 2016
Publication date	Jan 3, 2023
Grant date	Jan 3, 2023

Abstract

A specific resistance value adjustment apparatus includes: a hollow fiber membrane module; a module passing pipe which passes through the hollow fiber membrane module; a bypassing pipe which bypasses the hollow fiber membrane module; a liquid discharge pipe which communicates with the module passing pipe and the bypassing pipe through a joint portion; a first flow rate detection unit which detects a first flow rate of a liquid flowing to at least one of a liquid supply pipe and the liquid discharge pipe; a control valve which opens and closes the module passing pipe; and a control unit which sets an opening degree of the control valve in response to the first flow rate detected by the first flow rate detection unit.

First claim

The invention claimed is:

1. A specific resistance value adjustment apparatus comprising:
a hollow fiber membrane module having a configuration in which a liquid phase side area to which an ultrapure water is supplied and a gas phase side area to which an adjustment gas for adjusting a specific resistance value of the ultrapure water is supplied is divided by a hollow fiber membrane and the adjustment gas permeating the hollow fiber membrane is dissolved in the ultrapure water to produce an adjustment gas addition liquid in which the adjustment gas is dissolved in the ultrapure water;
a gas supply pipe which supplies the adjustment gas to the hollow fiber membrane module;
a liquid supply pipe to which the ultrapure water is supplied;
a module passing pipe which communicates with the liquid supply pipe through a branch portion branching the liquid supply pipe and passes through the hollow fiber membrane module;
a bypassing pipe which communicates with the liquid supply pipe through the branch portion and bypasses the hollow fiber membrane module;
a liquid discharge pipe which communicates with the module passing pipe and the bypassing pipe through a joint portion in which the module passing pipe and the bypassing pipe are joined to each other at a downstream side of the hollow fiber membrane module;
a first flow rate detection unit which detects a first flow rate of the ultrapure water supplied to the liquid supply pipe;
a control valve which opens and closes the module passing pipe; and
a control unit which sets an opening degree of the control valve in response to the first flow rate detected by the first flow rate detection unit,
wherein the module passing pipe includes a supply side module passing pipe which is disposed at an upstream side of the hollow fiber membrane module and supplies the ultrapure water to the hollow fiber membrane module and a discharge side module passing pipe which is disposed at a downstream side of the hollow fiber membrane module and discharges the adjustment gas addition liquid from the hollow fiber membrane module,
wherein the control valve is attached to the discharge side module passing pipe and opens and closes the discharge side module passing pipe, and
wherein the first flow rate detection unit detects a flow rate of the ultrapure water flowing through the liquid discharge pipe as the first flow rate.

2. The specific resistance value adjustment apparatus according to claim 1 , further comprising:
a second flow rate detection unit which detects a second flow rate of the ultrapure water flowing through the module passing pipe,
wherein the control unit corrects the opening degree in response to the second flow rate detected by the second flow rate detection unit.

3. The specific resistance value adjustment apparatus according to claim 1 ,
wherein when the first flow rate is equal to or smaller than a set flow rate, the control unit increases the opening degree as compared with a case in which the first flow rate is larger than the set flow rate.

4. The specific resistance value adjustment apparatus according to claim 3 ,
wherein when the first flow rate is equal to or smaller than the set flow rate, the control unit increases the opening degree as the first flow rate decreases.

5. The specific resistance value adjustment apparatus according to claim 4 ,
wherein when the first flow rate is larger than the set flow rate, the control unit increases the opening degree as the first flow rate decreases.

6. The specific resistance value adjustment apparatus according to claim 5 ,
wherein when the first flow rate is equal to or smaller than the set flow rate, the control unit increases a ratio of a change rate of the opening degree with respect to a change rate of the first flow rate as compared with a case in which the first flow rate is larger than the set flow rate.

7. The specific resistance value adjustment apparatus according to claim 1 ,
wherein the adjustment gas addition liquid is an adjustment gas saturation liquid in which the adjustment gas is dissolved in the ultrapure water in a saturated state.

8. A specific resistance value adjustment method using the specific resistance value adjustment apparatus according to claim 1 , comprising:
supplying the ultrapure water to a liquid supply pipe;
distributing the ultrapure water supplied to the liquid supply pipe to a module passing pipe passing through the hollow fiber membrane module and a bypassing pipe bypassing the hollow fiber membrane module;
producing the adjustment gas addition liquid in which the adjustment gas is dissolved in the ultrapure water in a saturated state in the hollow fiber membrane module by supplying the adjustment gas to the hollow fiber membrane module;
joining the adjustment gas addition liquid produced by the hollow fiber membrane module to the ultrapure water bypassing the hollow fiber membrane module and discharging a resultant liquid to a liquid discharge pipe; and
setting an opening degree of a control valve opening and closing the module passing pipe in response to a first flow rate of the ultrapure water supplied to the liquid supply pipe.

9. The specific resistance value adjustment method according to claim 8 ,
wherein when the first flow rate is equal to or smaller than a set flow rate, the opening degree is increased as compared with a case in which the first flow rate is larger than the set flow rate.

10. The specific resistance value adjustment method according to claim 8 ,
wherein a second flow rate of the ultrapure water flowing through the module passing pipe is detected and the opening degree is corrected in response to the second flow rate.

11. The specific resistance value adjustment method according to claim 8 ,
wherein when the first flow rate is equal to or smaller than the set flow rate, the opening degree is increased as compared with a case in which the first flow rate is larger than the set flow rate, the opening degree is increased as the first flow rate decreases, and a ratio of a change rate of the opening degree with respect to a change rate of the first flow rate is increased as compared with a case in which the first flow rate is larger than the set flow rate, and
wherein when the first flow rate is larger than the set flow rate, the opening degree is increased as the first flow rate decreases.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Saito Masato
• Oi Kazumi
• Hada Naoki

Classifications

• B01F35/833

  Flow control by valves, e.g. opening intermittently · CPC title

• B01F35/8331

  the flow of one component operating the actuator of the valve, e.g. by deforming a membrane which operates de valve actuator · CPC title

• B01F25/40

  Static mixers (colloid-mills B02C; mixing valves F16K11/00) · CPC title

• C02F2103/04

  for obtaining ultra-pure water · CPC title

• B01F25/32

  wherein the additional components are added in a by-pass of the main flow · CPC title