Processes and systems for treating sour water

Patent metadata

Field	Value
Publication number	US-11542184-B2
Application number	US-201916701332-A
Country	US
Kind code	B2
Filing date	Dec 3, 2019
Priority date	Dec 3, 2019
Publication date	Jan 3, 2023
Grant date	Jan 3, 2023

Abstract

Processes for producing olefins may include electrolyzing an aqueous solution comprising metal chloride, where electrolyzing the aqueous solution causes at least a portion of the metal chloride to undergo chemical reaction to produce a treatment composition comprising hypochlorite. The processes may further include contacting at least a portion of the treatment composition with the sour water at a pH from 8 to 12, where the sour water comprises sulfides and the contacting causes reaction of the sulfides in the sour water with the hypochlorite to produce a treated aqueous mixture comprising at least metal sulfates and metal chlorides, where the metal sulfates are present in the treated aqueous mixture as precipitated solids. The processes may further include separating the precipitated solids from the treated aqueous mixture to produce a treated effluent comprising at least the metal chloride.

First claim

What is claimed is:

1. A process for treating sour water, the process comprising:
combining water, metal chloride, and metal hydroxide to produce an aqueous solution, where a metal of the metal chloride and a metal of the metal hydroxide comprises strontium, barium, or both, where the aqueous solution comprises from 15 percent by weight (wt. %) to 30 wt. % of the metal chloride and 1 wt. % to 10 wt. % the metal hydroxide;
after the combining, electrolyzing the aqueous solution, where electrolyzing the aqueous solution causes at least a portion of the metal chloride to undergo chemical reaction to produce a treatment composition comprising hypochlorite;
contacting at least a portion of the treatment composition with the sour water at a pH from 8 to 12, where the sour water comprises sulfides and the contacting causes reaction of the sulfides in the sour water with the hypochlorite to produce a treated aqueous mixture comprising at least metal sulfates and metal chlorides, where the metal sulfates are present in the treated aqueous mixture as precipitated solids; and
separating the precipitated solids from the treated aqueous mixture to produce a treated effluent comprising at least the metal chlorides.

2. The process of claim 1 , where electrolyzing the aqueous solution comprises contacting the aqueous solution with an anode and a cathode and passing an electric current through the aqueous solution, where:
contacting the metal chloride with the anode causes at least a portion of ions present in the metal chloride to react to form hypochlorite; and
contacting water with the cathode causes at least a portion of the water to react to form hydrogen.

3. The process of claim 1 , in which the metal sulfates in the treated aqueous mixture comprise strontium sulfate, barium sulfate, or both.

4. The process of claim 1 , in which separating the treated aqueous mixture comprises filtering the treated aqueous mixture to produce a solid product comprising the precipitated solids and the treated effluent.

5. The process of claim 1 , in which the sour water comprises hydrogen cyanide and contacting the at least a portion of the treatment composition with the sour water causes reactions between the hydrogen cyanide, the hypochlorite, and water to produce at least metal chlorides, nitrogen gas, and metal carbonates, where at least a portion of the metal carbonates are present in the treated aqueous mixture as a portion of the precipitated solids.

6. The process of claim 1 , in which the sour water comprises phenolic compounds and contacting the at least a portion of the treatment composition with the sour water causes reactions between the phenolic compounds and the hypochlorite to produce at least metal chlorides, metal carbonates, and water, where at least a portion of the metal carbonates are present in the treated aqueous effluent as a portion of the precipitated solids.

7. The process of claim 1 , further comprising subjecting the treated effluent to vacuum crystallization, where:
the treated effluent further comprises metal hydroxides; and
vacuum crystallization causes at least a portion of the metal chlorides in the treated effluent to crystallize to form solid metal chloride and at least a portion of metal hydroxides in the treated effluent to form solid metal hydroxide.

8. The process of claim 7 , in which subjecting the treated effluent to vacuum crystallization comprises recovering a water vapor effluent from the vacuum crystallization.

9. The process of claim 8 , further comprising:
condensing the water vapor effluent to produce a liquid water effluent; and
recycling the liquid water effluent, the solid metal chloride, and the solid metal hydroxide into the aqueous solution such that at least a portion of the aqueous solution comprises the liquid water effluent, the solid metal chloride, and the solid metal hydroxide.

10. The process of claim 1 , in which:
the sour water comprises from 100 parts per million by weight (ppmw) to 100,000 ppmw of hydrogen sulfide, from 100 ppmw to 100,000 ppmw of ammonium sulfide, from 50 ppmw to 500 ppmw of phenolic compounds, and from 300 ppmw to 500 ppmw of hydrogen cyanide; and
the treated aqueous mixture comprises less than 10 ppmw of hydrogen sulfide, less than 10 ppmw of ammonium sulfide, less than 0.05 ppmw of phenolic compounds, and less than 0.05 ppmw of hydrogen cyanide.

11. The process of claim 1 , in which the contacting step is performed at a temperature from 15 degrees Celsius (° C.) to 45° C. and at a pressure from 50 kilopascals (kPa) to 200 kPa.

12. The process of claim 1 , where a volumetric ratio of the treatment composition to the sour water during contacting is from 0.5 to 1.8.

13. A process for treating sour water, the process comprising:
combining water, metal chloride, and metal hydroxide to produce an aqueous solution, where a metal of the metal chloride, the metal hydroxide, or both comprises strontium, barium, or both;
electrolyzing the aqueous solution, where electrolyzing the aqueous solution causes at least a portion of the metal chloride to undergo chemical reaction to produce a treatment composition comprising hypochlorite;
contacting at least a portion of the treatment composition with the sour water at a pH from 8 to 12, where the sour water comprises sulfides and the contacting causes reaction of the sulfides in the sour water with the hypochlorite to produce a treated aqueous mixture comprising at least metal sulfates and metal chlorides, where the metal sulfates are present in the treated aqueous mixture as precipitated solids; and
separating the precipitated solids from the treated aqueous mixture to produce a treated effluent comprising at least the metal chloride;
recovering solid metal chlorides from the treated effluent; and
recycling the solid metal chlorides recovered from the treated effluent into the aqueous solution such that at least a portion of the aqueous solution comprises the solid metal chlorides.

14. The process of claim 13 , wherein the treated effluent comprises metal hydroxides and the process further comprises:
recovering solid metal hydroxides from the treated effluent; and
recycling the solid metal hydroxides recovered from the treated effluent into the aqueous solution such that at least a portion of the aqueous solution comprises the solid metal hydroxides.

15. The process of claim 13 , further comprising:
evaporating water from the treated effluent to produce a water vapor steam;
condensing water vapor in the water vapor steam to produce a liquid water effluent;
recycling the liquid water effluent into the aqueous solution such that at least a portion of the aqueous solution comprises the liquid water effluent.

16. The process of claim 13 , recovering solid metal chlorides from the treated effluent comprises subjecting the treated effluent to vacuum crystallization, where:
the treated effluent further comprises metal hydroxides; and
vacuum crystallization causes at least a portion of the metal chlorides in the treated effluent to crystallize to form solid metal chloride and at least a portion of metal hydroxides in the treated effluent to form solid metal hydroxide.

17. The process of claim 16 , where subjecting the treated effluent to vacuum crystallization comprises recovering a water vapor effluent from the vacuum crystallization.

18. The process of claim 17 , further comprising:
condensing the water vapor effluent to produce a liquid water effluent; and
recycling the liquid water effluent, the solid metal chloride, and the solid metal

Assignees

• Saudi Arabian Oil Co

Inventors

• Raynel Guillaume Robert Jean-Francois

Classifications

• C02F2101/345

  Phenols · CPC title

• C02F9/00 Primary

  Multistage treatment of water, waste water or sewage · CPC title

• C25B1/26

  Chlorine; Compounds thereof (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title

• C02F1/4674

  with halogen or compound of halogens, e.g. chlorine, bromine · CPC title

• C02F1/46109

  Electrodes · CPC title