Water loss separators used with lead acid batteries, systems for improved water loss performance, and methods of manufacture and use thereof

Patent metadata

Field	Value
Publication number	US-11539084-B2
Application number	US-202016878655-A
Country	US
Kind code	B2
Filing date	May 20, 2020
Priority date	Feb 26, 2015
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

In at least select embodiments, the instant disclosure is directed to new or improved battery separators, components, materials, additives, surfactants, lead acid batteries, systems, vehicles, and/or related methods of production and/or use. In at least certain embodiments, the instant disclosure is directed to surfactants or other additives for use with a battery separator for use in a lead acid battery, to battery separators with a surfactant or other additive, and/or to batteries including such separators. In at least certain select embodiments, the instant disclosure relates to new or improved lead acid battery separators and/or systems including improved water loss technology and/or methods of manufacture and/or use thereof. In at least select embodiments, the instant disclosure is directed toward a new or improved lead acid battery separator or system with one or more surfactants and/or additives, and/or methods for constructing lead acid battery separators and batteries with such surfactants and/or additives for improving and/or reducing water loss from the battery.

First claim

The invention claimed is:

1. A battery separator for reduced water-loss comprising a surfactant in or on the battery separator, wherein the surfactant comprises an ethylene oxide/propylene oxide block copolymer, having an HLB from 1 to 1.5 and at least one of metallic zinc, bismuth, silver, selenium, and cadmium in or on the battery separator.

2. The battery separator of claim 1 , wherein the surfactant further comprises a non-ionic surfactant.

3. The battery separator of claim 2 , wherein the non-ionic surfactant comprises a methallyl-capped non-ionic surfactant.

4. The battery separator of claim 1 , wherein the separator comprises a microporous membrane or a microporous membrane laminated to a nonwoven.

5. The battery separator of claim 4 , wherein the battery separator comprises polyethylene (PE), silica, and processing oil, and the surfactant is present in an amount of 0.5 to 60% of the PE, silica, and processing oil.

6. The battery separator of claim 5 , wherein the surfactant is present in an amount of 1 to 20% of the PE, silica, and processing oil.

7. The battery separator of claim 1 , wherein the battery separator comprises polyethylene (PE), silica, and processing oil, and the surfactant is present in an amount of 0.5 to 60% of the PE, silica, and processing oil.

8. The battery separator of claim 7 , wherein the surfactant is present in an amount of 1 to 20% of the PE, silica, and processing oil.

9. The battery separator of claim 1 , further comprising an alkoxylated alcohol additive in or on the battery separator.

10. A battery comprising the battery separator of claim 1 , wherein the battery exhibits reduced water-loss.

Assignees

• Daramic Llc

Inventors

• Chambers Jeffrey K

Classifications

• H01M4/628

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M50/431

  Inorganic material · CPC title

• H01M10/4235 Primary

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• H01M50/40 Primary

  Separators; Membranes; Diaphragms; Spacing elements inside cells · CPC title

• H01M50/454

  comprising a non-fibrous layer and a fibrous layer superimposed on one another · CPC title