Lithium-ion conducting composite material

Patent metadata

Field	Value
Publication number	US-11539072-B1
Application number	US-202217732758-A
Country	US
Kind code	B1
Filing date	Apr 29, 2022
Priority date	Apr 29, 2022
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

A lithium-ion conducting composite material includes a Li binary salt, a Li-ion conductor with a chemical composition of Li 2−3x+y−z Fe x O y (OH) 1−y Cl 1−z , and at least two of: a first inorganic compound with a chemical composition of (Fe 1−x M1 x )O 1−y (OH) y Cl 1−x ; a second inorganic compound with a chemical composition of M2OX; and a defected doped inorganic compound with a chemical composition of (M3OX)′. The value of n is 1 or 2, x is greater than 0 and less than or equal to 0.25, and y is greater than or equal to 0 and less than or equal to 0.25. Also, M1 is at least one of Mg and Ca, M2 and M3 are each at least one of Fe, Al, Sc, La, and Y, and X is at least one of F, Cl, Br, and I.

First claim

What is claimed is:

1. A Li-ion conducting composite material comprising:
a Li binary salt, a Li-ion conductor with a chemical composition of Li 2−3x+y−z Fe x O y (OH) 1−y Cl 1−z , x is greater than or equal to 0 and less than 1, y is greater than or equal to 0 and less than or equal 1, and z is greater than or equal to 0 and less than or equal 0.25, and at least two of:
a first inorganic compound with a chemical composition of (Fe 1−x M1 x )O 1−y (OH) y Cl 1−x where M1 is selected from at least one of Mg and Ca, and x is greater than 0 and less than or equal to 0.25, y is greater than or equal to 0 and less than or equal to 0.25;
a second inorganic compound with a chemical composition of M2OX where M2 is at least one of Fe, Al, Sc, La, and Y, and X is at least one of F, Cl, Br, and I; and
a defected doped inorganic compound comprising a chemical composition of (M3OX)′, where M3 is at least one of Fe, Al, Sc, La or Y, and X is at least one of F, Cl, Br, or I.

2. The Li-ion conducting composite material according to claim 1 , wherein the first inorganic compound has x-ray diffraction peaks with a 2θ between about 20.79° and about 22.79°, between about 30.03° and about 32.03°, between about 39.47° and about 41.47°, and between about 76.44° and about 78.44°.

3. The Li-ion conducting composite material according to claim 2 , wherein the first inorganic compound has a thermal decomposition temperature of about 410° C.

4. The Li-ion conducting composite material according to claim 1 , wherein the first inorganic compound further comprises at least one of LiCl, Li(OH), Li 2 CO 3 , FeCl 3 , FeCl 3 (6H 2 O), Fe(OH) 3 , FeO, Fe 2 O 3 , Fe 3 O 4 , MgCl 2 , MgCl 2 (4H 2 O), MgO, CaO, and Ca(OH).

5. The Li-ion conducting composite material according to claim 1 , wherein M2 of the second inorganic compound is at least one of Al, Sc, La, and Y, and a thermal decomposition temperature of the second inorganic compound is greater than a thermal decomposition temperature of FeOCl.

6. The Li-ion conducting composite material according to claim 5 , wherein an ionic conductivity of the second inorganic compound is equal to or greater than an ionic conductivity of FeOCl.

7. The Li-ion conducting composite material according to claim 1 , wherein the defect doped inorganic compound comprises x-ray diffraction peaks with a 2θ between about 63.3° and about 65.3°, and between about 76.6° and about 78.6°.

8. The Li-ion conducting composite material according to claim 1 , wherein the defect doped inorganic compound comprises x-ray diffraction peaks with a 2θ between about 22.12° and about 24.12°, between about 31.97° and about 33.97°, between about 39.55° and about 41.55°, between about 46.46° and about 48.46°, between about 57.77° and about 59.77°, and between about 68.04° and about 70.04°.

9. The Li-ion conducting composite material according to claim 1 further comprising an ionic conductivity of about 5×10 −4 S/cm at 25° C.

10. The Li-ion conducting composite material according to claim 1 further comprising and x-ray diffraction I(010)/I(total) peak intensity ratio equal to or less than 0.09.

11. The Li-ion conducting composite material according to claim 1 , wherein the at least two of the first inorganic compound, the second inorganic compound, and the defected doped inorganic compound comprises the first inorganic compound, the second inorganic compound, and the defected doped inorganic compound.

12. The Li-ion conducting composite material according to claim 1 , wherein the Li binary salt is LiCl.

13. The Li-ion conducting composite material according to claim 1 , wherein the Li-ion conductor comprises an ionic conductivity equal to or greater than 3×10 −4 S/cm.

14. The Li-ion conducting composite material according to claim 1 further comprising an ionic conductivity equal to or greater than 5×10 −4 S/cm.

15. A Li-ion conducting composite material comprising:
a Li binary salt, a Li-ion conductor with a chemical composition of Li 2−3x+y−z Fe x O y (OH) 1−y Cl 1−z , where x is greater than or equal to 0 and less than 1, y is greater than or equal to 0 and less than or equal 1, and z is greater than or equal to 0 and less than or equal 0.25;
a first inorganic compound with a chemical composition of (Fe 1−x M1 x )O 1−y (OH) y Cl 1−x where M1 is selected from at least one of Mg and Ca, and x is greater than 0 and less than or equal to 0.25, y is greater than or equal to 0 and less than or equal to 0.25;
a second inorganic compound with a chemical composition of M2OX where M2 is at least one of Fe, Al, Sc, La, and Y, and X is at least one of F, Cl, Br, and I; and
a defected doped inorganic compound comprising a chemical composition of (M3OX)′, where M3 is at least one of Fe, Al, Sc, La or Y, and X is at least one of F, Cl, Br, or I.

16. The Li-ion conducting composite material according to claim 15 further comprising an ionic conductivity equal to or greater than 3×10 −4 S/cm.

17. The Li-ion conducting composite material according to claim 15 further comprising an ionic conductivity equal to or greater than 5×10 −4 S/cm.

18. The Li-ion conducting composite material according to claim 15 further comprising and x-ray diffraction I(010)/I(total) peak intensity ratio equal to or less than 0.09.

19. A Li-ion conducting composite material comprising:
a Li binary salt, a Li-ion conductor with a chemical composition of Li 2−3x+y−z Fe x O y (OH) 1−y Cl 1−z , where x is greater than or equal to 0 and less than 1, y is greater than or equal to 0 and less than or equal 1, and z is greater than or equal to 0 and less than or equal 0.25;
a first inorganic compound with a chemical composition of (Fe 1−x M1 x )O 1−y (OH) y Cl 1−z , where M1 is selected from at least one of Mg and Ca, and x is greater than 0 and less than or equal to 0.25, y is greater than or equal to 0 and less than or equal to 0.25;
a second inorganic compound with a chemical composition of M2OX where M2 is at least one of Fe, Al, Sc, La, and Y, and X is at least one of F, Cl, Br, and I;
a defected doped inorganic compound comprising a chemical composition of (M3OX)′, where M3 is at least one of Fe, Al, Sc, La or Y, and X is at least one of F, Cl, Br, or I; and
an ionic conductivity equal to or greater than 3×10 −4 S/cm.

20. The Li-ion conducting composite material according to claim 19 , wherein the ionic conductivity is equal to or greater than 5×10 −4 S/cm.

Assignees

• Toyota Eng & Mfg North America
• Toyota Motor Co Ltd

Inventors

• Ota Shingo
• Sugiura Ryuta
• Arthur Timothy S
• Singh Nikhilendra

Classifications

• H01M10/0562 Primary

  Solid materials · CPC title

• C01G49/009 Primary

  Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C01P2002/88

  by thermal analysis data, e.g. TGA, DTA, DSC · CPC title

• H01M2300/008

  Halides · CPC title

• C01P2006/32

  Thermal properties · CPC title