Sulfide-impregnated solid-state battery

Patent metadata

Field	Value
Publication number	US-11539071-B2
Application number	US-201916578880-A
Country	US
Kind code	B2
Filing date	Sep 23, 2019
Priority date	Jul 29, 2019
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

A sulfide-impregnated solid-state battery is provided. The battery comprises a cell core constructed by basic cell units. Each unit comprises a positive electrode comprising a cathode layer and a positive meshed current collector comprising a conductive material which is further coated by oxide-based solid-state electrolyte. The cell unit further comprises a negative electrode comprising an anode layer and a negative meshed current collector comprising a conductive material which is further coated by oxide-based solid-state electrolyte. The positive and negative electrodes are stacked together to form the cell unit. The two coated oxide-based solid electrolyte layers are disposed between the positive and negative electrode as dual separators. Such a cell unit may be repeated or connected in parallel or bipolar stacking to form the cell core to achieve a desired battery voltage, power and energy. The cell core comprises a sulfide-based solid-state electrolyte dispersed in the pore structures of cell core.

First claim

What is claimed is:

1. A sulfide-impregnated solid-state battery comprising:
a cell core constructed by cell units and having a pore structure, each cell unit comprising:
a positive electrode comprising a cathode layer and a positive meshed current collector comprising a conductive material, wherein the cathode layer is further coated by an oxide-based solid electrolyte layer; and
a negative electrode comprising an anode layer and a negative meshed current collector comprising a conductive material, wherein the anode layer is further coated by an oxide-based solid electrolyte layer,
wherein the positive electrode and the negative electrode are stacked together to form the cell unit, and the two of the coated oxide-based solid-state electrolyte layers are disposed between the positive electrode and the negative electrode as dual separators,
wherein the cathode layer comprises between about 30 wt % and about 98 wt % cathode active material, between about 0 wt % and about 50 wt % sulfide-based solid-state electrolyte, between about 0 wt % and about 30 wt % conductive additive, and between about 0 wt % and about 20 wt % binder,
wherein the anode layer comprises between about 30 wt % and about 98 wt % anode active material, between about 0 wt % and about 50 wt % sulfide-based solid-state electrolyte, between about 0 wt % and about 30 wt % conductive additive, and between about 0 wt % and about 20 wt % binder, and

wherein a sulfide-base solid-state electrolyte is dispersed in the pore structure of the cell core.

2. The battery of claim 1 wherein each cell unit is connected in one of parallel arrangement and bipolar arrangement.

3. The battery of claim 1 wherein the cathode active material is selected from the group consisting of a high-voltage cathode material, a rock salt layered oxide, a spinel, a polyanion cathode, a lithium transition-metal oxide, and at least one of LiNi 0.5 Mn 1.5 O 4 , LiNbO 3 -coated LiNi 0.5 Mn 1.5 O 4 , LiCoO 2 , LiNi x Mn y Co 1-x-y O 2 , LiNi x Mn 1-x O 2 , Li 1+x MO 2 , LiMn 2 O 4 , LiV 2 (PO 4 ) 3 .

4. The battery of claim 1 wherein the anode active material is selected from the group consisting of a carbonaceous material, silicon, silicon-graphite mixture, Li 4 Ti 5 O 12 , transition-metal, metal oxide, and sulfide.

5. The battery of claim 1 wherein each of the cathode layer and the anode layer has a thickness of between about 1 micrometer and about 1000 micrometers.

6. The battery of claim 1 wherein each of the positive meshed current collector and the negative meshed current collector has a thickness of between about 4 micrometers and about 200 micrometers and a pore size of between about 50 nm and 2000 um.

7. The battery of claim 1 wherein the positive meshed current collector and the negative meshed current collector is selected from the group consisting of aluminum, nickel, iron, titanium, copper, tin, and alloys thereof.

8. The battery of claim 1 wherein the positive meshed current collector and the negative meshed current collector includes flat foils of conductive material with no holes.

9. The battery of claim 1 wherein the oxide-based solid electrolyte layers disposed on the cathode layer and anode layer comprise an oxide-based solid-state electrolyte of Li 3 xLa 2/3-x TiO 3 , Li 1.4 Al 0.4 Ti 1.6 (PO 4 ) 3 and Li 1+x Al x Ge 2-x (PO 4 ) 3 , Li 2+2x Zn 1-x GeO 4 , Li 7 La 3 Zr 2 O 12 or mixtures thereof.

10. The battery of claim 1 wherein the oxide-based solid electrolyte layers disposed on the cathode layer and anode layer comprise at least one of a metal-doped and aliovalent-substituted oxide-based solid-state electrolyte, a borate and a phosphate solid-state electrolyte, and an oxide ceramic powder.

11. The battery of claim 1 wherein the oxide-based solid electrolyte layers disposed on the cathode layer and anode layer comprise same or different chemical compositions.

12. The battery of claim 1 wherein the oxide-based solid electrolyte layers disposed on the cathode layer and anode layer each have a thickness of between about 50 nanometers and about 1000 micrometers.

13. The battery of claim 1 wherein the sulfide-base solid-state electrolyte comprises at least one of a pseudobinary sulfide, a pseudoternary sulfide, and a pseudoquaternary sulfide,
wherein the pseudobinary sulfide comprises one of Li 3 PS 4 , Li 7 P 3 S 11 , Li 4 SnS 4 , and 80Li 2 S.20P 2 S 5 ,
wherein the pseudoternary sulfide comprises one of Li 3.25 Ge 0.25 P 0.75 S 4 , Li 6 PS 5 Br, Li 6 PS 5 I, Li 6 PS 5 Cl, Li 7 P 2 S 8 I, Li 4 PS 4 I, and LiI—Li 4 SnS 4 , and
wherein the pseudoquaternary sulfide comprises one of Li 9.54 Si 1.74 P 1.44 S 11.7 Cl 0.3 and Li 10.35 [Sn 0.27 Si 1.08 ]P 1.65 S 12 .

14. The battery of claim 1 wherein the cell core further includes a liquid electrolyte selected from the group consisting of Li(triethylene glycol dimethyl ether)bis(trifluoromethanesulfonyl)imide (Li(G 3 )TFSI), LiPF6-EC/DEC with additives, and LiTFSI in acetonitrile.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Li Zhe
• Que Xiaochao
• Liu Haijing
• Lu Yong
• Verbrugge Mark W
• Wu Meiyuan

Classifications

• H01M10/0585

  of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/74 Primary

  Meshes or woven material; Expanded metal · CPC title

• H01M2300/0071

  Oxides · CPC title