Polymer-modified silicon-carbon composite and use thereof

Patent metadata

Field	Value
Publication number	US-11539049-B2
Application number	US-201916527194-A
Country	US
Kind code	B2
Filing date	Jul 31, 2019
Priority date	Jul 31, 2018
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

The present invention provides a silicon-carbon composite which contains a body having a core-shell structure and a polymer modification layer. The core of the body contains a silicon-containing particle. The shell of the body is a carbon encapsulation layer. The polymer modification layer is located on the external surface of the shell of the body and encapsulates the body. The polymer modification layer comprises a polymer selected from the group consisting of polyester, polyfluorocarbon, polyvinyl alcohol, polyacrylic acid, cellulose and a combination thereof.

First claim

What is claimed is:

1. A silicon-carbon composite, comprising a body having a core-shell structure and a polymer modification layer, wherein:
(a) the core of the body is a silicon-containing particle, and the shell of the body is a carbon encapsulation layer; and
(b) the polymer modification layer is located on the external surface of the shell of the body and encapsulates the body, and the polymer modification layer comprises a polymer selected from the group consisting of polyester, polyfluorocarbon, polyvinyl alcohol, polyacrylic acid, cellulose and a combination thereof,
wherein the carbon encapsulation layer comprises pyrolytic carbon formed by incompletely carbonizing erythritol and at least one organic substance selected from the group consisting of trehalose, xylose and isomalt, and
wherein the ratio of the integral area of a characteristic peak of sp 2 carbon to the total integral area of the characteristic peaks of C1s orbital measured by use of X-ray photoelectron spectroscopy for the carbon encapsulation layer is in a range from 0.5 to 0.7.

2. The silicon-carbon composite according to claim 1 , wherein the content of the polymer modification layer is in a range from 5 wt % to 15 wt %, based on the total amount of the silicon-carbon composite being 100 wt %.

3. The silicon-carbon composite according to claim 1 , which has a thermal weight loss between 5 wt % and 20 wt % at 250 to 600° C., as measured in a thermogravimetric analysis (TGA) test.

4. The silicon-carbon composite according to claim 1 , wherein the pyrolytic carbon is formed by incompletely carbonizing erythritol and trehalose.

5. The silicon-carbon composite according to claim 1 , further comprising a conductive material, wherein the conductive material is selected from the group consisting of a conductive polymer, graphite, graphene, carbon nano-tubes and any combination thereof, and the content of the conductive material is in a range from 0.1 wt % to 10 wt %, based on the total amount of the silicon-carbon composite being 100 wt %.

6. The silicon-carbon composite according to claim 1 , wherein the silicon-containing particle comprises elementary silicon, a silicon-oxygen compound represented as SiO x (0<x≤2), a silicon-containing solid solution or a silicon-containing intermetallic compound.

7. The silicon-carbon composite according to claim 1 , wherein the content of the silicon-containing particle is in a range from 55 wt % to 80 wt %, and the content of pyrolytic carbon is in a range from 0.1 wt % to 30 wt %, based on the total weight of the silicon-carbon composite being 100 wt %.

8. A lithium battery negative electrode, comprising the silicon-carbon composite according to claim 1 .

Assignees

• Eternal Mat Co Ltd

Inventors

• Tsai Lin Jen
• Huang Chiyu
• Wang Chihhsien

Classifications

• H01M4/625

  Carbon or graphite · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• C01B33/02

  Silicon (forming single crystals or homogeneous polycrystalline material with defined structure C30B) · CPC title