Alumina-ceramic-based electrical insulator, method for producing the insulator, and vacuum tube comprising the insulator

Patent metadata

Field	Value
Publication number	US-11538604-B2
Application number	US-201716346508-A
Country	US
Kind code	B2
Filing date	Nov 2, 2017
Priority date	Nov 2, 2016
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

An alumina-ceramic-based electrical insulator, to a method for producing the insulator, and to a vacuum tube includes the insulator. The electrical insulator is for insulating two electrodes of a vacuum tube through which a charged particle beam flows, the electrical insulator being formed of an alumina-based ceramic. The ceramic comprises a vitreous phase of between 2% and 8% by weight into which at least one metal oxide is diffused from a face of the electrical insulator.

First claim

The invention claimed is:

1. An electrical insulator for insulating at least one electrode of a vacuum tube through which a charged particle beam flows, the electrical insulator being formed of an alumina-based ceramic, wherein the ceramic is formed of a polycrystalline material having boundaries, between the boundaries of which a vitreous phase of between 2% and 8% by weight is present and into which at least one metal oxide is diffused from a face of the electrical insulator, the metal oxide concentration decreasing gradually with distance from the face.

2. The electrical insulator as claimed in claim 1 , wherein it exhibits a continuous variation in electrical resistance and a continuous variation in dielectric permittivity from the face down to a depth of the insulator to which the at least one metal oxide has not diffused.

3. The electrical insulator as claimed in claim 1 , wherein the vitreous phase is between 5% and 7% by weight.

4. The electrical insulator as claimed in claim 1 , wherein the vitreous phase comprises one or more alkaline-earth compounds mixed with fillers comprising at least one element from the group consisting of silica and zirconia.

5. The electrical insulator as claimed in claim 1 , wherein the at least one metal oxide comprises a chromium oxide and a titanium oxide.

6. The electrical insulator as claimed in claim 1 , wherein the electrical insulator is tubular in shape and in that the face from which the at least one metal oxide is diffused is an internal face of the tubular shape.

7. A process for producing an electrical insulator as claimed in claim 1 , wherein it comprises a first step of depositing at least one metal oxide in solution in a solvent on the face of the insulator followed by a second step of heat treating the insulator, allowing the at least one metal oxide to diffuse into the vitreous phase of the ceramic.

8. The process for producing an electrical insulator as claimed in claim 6 , wherein in the second step, periods under a reducing atmosphere are employed in series with periods under a more oxidizing atmosphere.

9. The process for producing an electrical insulator as claimed in claim 7 , wherein before the second, heat treatment step, the alumina is substoichiometric with respect to oxygen.

10. A vacuum tube, wherein it comprises an electrical insulator as claimed in claim 1 , and at least one electrode insulated by the electrical insulator.

11. The vacuum tube as claimed in claim 10 , the electrical insulator of which is produced according to a process comprising a first step of depositing at least one metal oxide in solution in a solvent on the face of the insulator followed by a second step of heat treating the insulator, allowing the at least one metal oxide to diffuse into the vitreous phase of the ceramic, wherein
the electrical insulator is partly covered by a first metallization making electrical contact with the at least one electrode, and in that the deposit partly covers the first metallization.

12. The vacuum tube as claimed in claim 11 , wherein the electrical insulator is partly covered by a second metallization arranged over the first metallization, including over the portion of the first metallization that is covered by the deposit.

13. The vacuum tube as claimed in claim 10 , wherein the tube is an X-ray generator.

14. The vacuum tube as claimed in claim 10 , wherein the tube is a radiofrequency amplifier.

Assignees

• Thales Sa

Inventors

• Ponard Pascal
• Bourat Christophe

Classifications

• C04B41/5041

  Titanium oxide or titanates · CPC title

• C04B2235/75

  Products with a concentration gradient · CPC title

• C04B2235/3418

  Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint · CPC title

• C04B2235/3208

  Calcium oxide or oxide-forming salts thereof, e.g. lime · CPC title

• H01B3/10

  metallic oxides (ceramics H01B3/12) · CPC title