Optochemical sensor and method

Patent metadata

Field	Value
Publication number	US-11536661-B2
Application number	US-202016993823-A
Country	US
Kind code	B2
Filing date	Aug 14, 2020
Priority date	Aug 16, 2019
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

The present disclosure discloses an optochemical sensor for determining a measurand correlating with a concentration of an analyte in a measuring fluid, comprising: a housing having an immersion region configured for immersing in the measuring fluid; a removable cap having a sensor spot, the removable cap removably arranged at the immersion region of the housing, wherein the sensor spot is disposed on a circumferential face; a radiation source disposed in the housing for radiating excitation radiation into the removable cap, wherein a deflection module is disposed in the removable cap as to deflect excitation radiation radiated into the removable cap; a radiation receiver disposed in the housing for receiving received radiation emitted by the sensor spot; and a sensor circuit disposed in the housing and configured to control the radiation source, receive signals of the radiation receiver, and generate output signals based on the signals of the radiation receiver.

First claim

The invention claimed is:

1. An optochemical sensor for determining a measurand correlated with a concentration of an analyte in a measuring fluid, comprising:
a housing having an immersion region adapted to be immersed into the measuring fluid;
a removable cap removably arranged at the immersion region of the housing, the removable cap including at least one sensor spot disposed on a lateral face of the removable cap;
a radiation source disposed in the housing and configured to emit excitation radiation into the removable cap in an axial direction toward an end face of the removable cap, wherein the end face is perpendicular to the lateral face;
a deflection module disposed in the removable cap and configured to deflect the excitation radiation in a direction of the at least one sensor spot such that the at least one sensor spot is irradiated with the excitation radiation, wherein the direction of the at least one sensor spot is perpendicular to the axial direction;
a radiation receiver disposed in the housing and configured to receive received radiation emitted by the at least one sensor spot; and
a sensor circuit disposed in the housing and configured to control the radiation source, to receive signals of the radiation receiver, and to generate and output output signals based on the signals of the radiation receiver.

2. The optochemical sensor of claim 1 , wherein the deflection module comprises a mirror, a prism or a beveled glass rod.

3. The optochemical sensor of claim 1 , wherein the deflection module is arranged in an adapter.

4. The optochemical sensor of claim 3 , wherein the sensor further comprises a light guide which conducts the excitation radiation from the radiation source in the axial direction toward the removable cap, wherein the adapter is configured to adapt to the light guide.

5. The optochemical sensor of claim 1 , wherein the housing and the removeable cap are cylindrical, wherein the lateral face of the removable cap is a circumferential face of the removable cap, and wherein the at least one sensor spot is disposed on the circumferential face of the removable cap, which includes a region translucent or transparent at least to the excitation radiation and the received radiation.

6. The optochemical sensor of claim 1 , wherein the removable cap comprises a gas ceramic, glass, borosilicate glass, quartz glass, sapphire, a transparent or translucent plastic of the series polycarbonate, cyclic olefin copolymer, polysulfones, poly(n-methyl methacrylimides), ethylene norbornene copolymers or a hybrid of stainless steel and these materials.

7. The optochemical sensor of claim 1 , wherein the at least one sensor spot of the removable cap comprises at least two sensor spots, each disposed in a separate area of the lateral face of the removable cap, wherein the removable cap is configured to enable each of the at least two sensor spots to be selectively, individually oriented relative to the deflection module as to selectively, individually irradiated a selected sensor spot of the at least two sensor spots with the excitation radiation.

8. The optochemical sensor of claim 1 , wherein the sensor comprises an orientation feature configured to enable a set orientation of the at least one sensor spot relative to the deflection module.

9. The optochemical sensor of claim 8 , wherein the orientation feature comprises a tongue-and-groove connection, wherein the removable cap includes either a tongue or a groove of the tongue-and-groove connection, and the housing includes either a complementary groove or complementary tongue, respectively.

10. The optochemical sensor of claim 1 , wherein the housing comprises a threaded portion and the removable cap comprises a corresponding counter-thread portion.

11. The optochemical sensor of claim 1 , wherein the deflection module is configured as a polyhedron or cone.

12. The optochemical sensor of claim 1 , wherein the deflection module comprises a mirror configured to be selectively activated from reflective to transparent.

13. The optochemical sensor of claim 1 , wherein the sensor circuit is configured to generate the output signals based on an intensity, a phase shift or a decay time of the signals of the radiation receiver.

14. The optochemical sensor of claim 8 , wherein the orientation feature comprises a detent, wherein the removable cap and the housing each comprise a complementary feature of the detent, respectively.

15. The optochemical sensor of claim 1 , wherein the deflection module includes a—reflective polyhedron including a face configured to be selectively switched from reflective to transparent.

Assignees

• Endress Hauser Conducta Gmbh Co Kg

Inventors

• Löbbert Andreas
• Hörig Alexander

Classifications

• G01N2021/6439

  with indicators, stains, dyes, tags, labels, marks · CPC title

• G01N2021/7786

  Fluorescence · CPC title

• G01N21/7703

  using reagent-clad optical fibres or optical waveguides (using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B) · CPC title

• G01N2021/8521

  with a combination mirror cell-cuvette · CPC title

• G01N2021/6432

  Quenching · CPC title