Pretreatment and pre-cooling of natural gas by high pressure compression and expansion

Patent metadata

Field	Value
Publication number	US-11536510-B2
Application number	US-201916410607-A
Country	US
Kind code	B2
Filing date	May 13, 2019
Priority date	Jun 7, 2018
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

A method and apparatus for producing liquefied natural gas. A pretreated natural gas stream is compressed in at least two serially arranged compressors to a pressure of at least 1,500 psia and cooled. The resultant cooled compressed natural gas stream is expanded in at least one work producing natural gas expander to a pressure less than 2,000 psia and no greater than the pressure to which natural gas stream has been compressed, thereby forming a chilled natural gas stream that is separated into a refrigerant stream and a non-refrigerant stream. The refrigerant stream is warmed in a heat exchanger through heat exchange with one or more process streams associated with pretreating the natural gas stream, thereby generating a warmed refrigerant stream. The warmed refrigerant stream and the non-refrigerant stream are then liquefied.

First claim

What is claimed is:

1. A method of producing liquefied natural gas (LNG) from a natural gas stream, the method comprising:
removing heavy hydrocarbons from the natural gas stream to thereby generate a separated natural gas stream;
partially condensing the separated natural gas stream in a first heat exchanger to thereby generate a partially condensed natural gas stream;
separating liquids from the partially condensed natural gas stream to thereby generate a pretreated natural gas stream;
compressing the pretreated natural gas stream in at least two serially arranged compressors to a pressure of at least 1,500 psia to form a compressed natural gas stream;
cooling the compressed natural gas stream to form a cooled compressed natural gas stream;
expanding, in at least one work producing natural gas expander, the cooled compressed natural gas stream to a pressure that is less than 2,000 psia and no greater than the pressure to which the at least two serially arranged compressors compress the pretreated natural gas stream, to thereby form a chilled natural gas stream;
separating the chilled natural gas stream into a refrigerant stream and a non-refrigerant stream;
warming the refrigerant stream through heat exchange with one or more process streams comprising at least one stream selected from the natural gas stream, the separated natural gas stream, the partially condensed natural gas stream, and the pretreated natural gas stream, thereby generating a warmed refrigerant stream; and
liquefying the warmed refrigerant stream and the non-refrigerant stream, further comprising:
prior to compressing the pretreated natural gas stream, warming the pretreated natural gas stream through heat exchange with the separated natural gas stream in the first heat exchanger.

2. The method of claim 1 , wherein the refrigerant stream is warmed through heat exchange with the separated natural gas stream.

3. The method of claim 1 , wherein the heavy hydrocarbons are separated from the natural gas stream in a scrub column, and further comprising:
directing the separated liquids to the scrub column as a column reflux stream;
wherein the one or more process streams optionally further comprises the column reflux stream.

4. The method of claim 1 , wherein liquefying the chilled pretreated natural gas stream is performed in one or more expander-based liquefaction modules, and wherein the expander-based liquefaction module is a nitrogen gas expander-based liquefaction module or a feed gas expander-based liquefaction module.

5. The method of claim 1 , wherein the at least two compressors compress the natural gas stream to a pressure greater than 3,000 psia, and wherein the work producing natural gas expander expands the cooled compressed natural gas stream to a pressure less than 2,000 psia.

6. The method of claim 1 , wherein cooling the compressed natural gas stream comprises cooling the compressed natural gas stream in at least one heat exchanger that exchanges heat with an environment.

7. The method of claim 1 , wherein one of the at least two serially arranged compressors is driven by the natural gas expander.

8. The method of claim 1 , further comprising:
performing the removing, partially condensing, separating, compressing, cooling, expanding, separating, warming, combining, and liquefying steps on a topside of a floating LNG structure.

9. The method of claim 8 , wherein the removing, partially condensing, separating, compressing, cooling, expanding, separating, warming, and combining steps are performed within a single module on the topside of the floating LNG structure.

10. An apparatus for the liquefaction of natural gas, comprising:
a first separation device configured to remove heavy hydrocarbons from a natural gas stream to thereby generate a separated natural gas stream;
a first heat exchanger that partially condenses the separated natural gas stream, thereby forming a partially condensed natural gas stream;
a second separation device that separates liquids from the partially condensed natural gas stream to thereby generate a liquids stream and a pretreated natural gas stream;
at least two serially arranged compressors configured to compress the pretreated natural gas stream to a pressure greater than 1,500 psia, thereby forming a compressed natural gas stream;
a cooling element configured to cool the compressed natural gas stream, thereby forming a cooled compressed natural gas stream;
at least one work-producing expander configured to expand the cooled compressed natural gas stream to a pressure which is less than 2,000 psia and is no greater than the pressure to which the at least two serially arranged compressors compress the pretreated natural gas stream, to thereby form a chilled natural gas stream;
wherein the chilled natural gas stream is separated into a refrigerant stream and a non-refrigerant stream, and wherein the refrigerant stream is warmed through heat exchange in the first heat exchanger with one or more of the natural gas stream, the separated natural gas stream, the partially condensed natural gas stream, the pretreated natural gas stream, and the liquids stream, thereby generating a warmed refrigerant stream; and
at least one liquefaction train configured to liquefy the warmed refrigerant stream and the non-refrigerant stream,
wherein, prior to compressing the pretreated natural gas stream, the pretreated natural gas stream is directed to the first heat exchanger to be warmed through heat exchange with the separated natural gas stream therein.

11. The apparatus of claim 10 , wherein the first separation device is a scrub column, and wherein the liquids stream is directed to the scrub column as a column reflux stream.

12. The apparatus of claim 10 , wherein the at least one liquefaction train comprises at least one single mixed refrigerant (SMR) liquefaction module or at least one expander-based liquefaction module.

13. The apparatus of claim 12 , wherein the at least one liquefaction train comprises at least one expander-based liquefaction module that is one of a nitrogen gas expander-based liquefaction module and a feed gas expander-based liquefaction module.

14. The apparatus of claim 10 , wherein the at least one work-producing expander is a work producing expander configured to expand the cooled compressed natural gas stream to a pressure less than 2,000 psia.

15. The apparatus of claim 10 , wherein the at least one work-producing expander is mechanically coupled to at least one compressor.

16. The apparatus of claim 10 , wherein the cooling element comprises a heat exchanger configured to cool the compressed natural gas stream by exchanging heat with an environment.

17. The apparatus of claim 10 , wherein one of the at least two serially arranged compressors is driven by the natural gas expander.

18. The apparatus of claim 10 , wherein the at least two serially arranged compressors comprise three serially arranged compressors, and wherein one of the three serially arranged compressors is driven by the natural gas expander.

19. The apparatus of claim 13 , wherein the first and second separation devices, the first heat exchanger, at least two serially arranged compressors, the cooling element, the at least one work-producing expander, and the liquefaction train are disposed on a floating LNG structure.

20. The apparatus of claim 19 , wherein the at least two serially arranged compressors, the cooling element, the first heat exchanger, the first and second separation devices, and the at least one

Assignees

• Liu Yijun
• Pierre Jr Fritz
• Exxonmobil Upstream Res Co

Inventors

• Liu Yijun
• Pierre Jr Fritz

Classifications

• F25J2220/64

  Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general · CPC title

• F25J2205/30

  using a washing, e.g. "scrubbing" or bubble column for purification purposes · CPC title

• F25J2240/80

  Hot exhaust gas turbine combustion engine · CPC title

• F25J1/0241

  wherein the overhead cooling comprises providing reflux for a fractionation step · CPC title

• F25J2205/02

  using simple phase separation in a vessel or drum · CPC title