Drilling fluids that include water-soluble acid catalyst precursors or reaction products of such and uses for such drilling fluids

Patent metadata

Field	Value
Publication number	US-11535785-B2
Application number	US-201916449959-A
Country	US
Kind code	B2
Filing date	Jun 24, 2019
Priority date	Jun 24, 2019
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

In accordance with one or more embodiments of the present disclosure, a drilling fluid may include a base fluid and one or more formaldehyde-based resins. The drilling fluid may further comprise one or more water-soluble acid catalyst precursors or the reaction products of such water-soluble acid catalyst precursors. The base fluid may include an aqueous or non-aqueous solution. The present disclosure also describes sealed subterranean petroleum formations that include such drilling fluids and methods for sealing subterranean wellbores by utilizing such drilling fluids.

First claim

What is claimed is:

1. A drilling fluid consisting of:
a base fluid comprising an aqueous or non-aqueous solution;
one or more formaldehyde-based resins, wherein the weight ratio of the one or more formaldehyde-based resins to the base fluid is from 10:100 to 20:100;
optionally polyvinyl alcohol or vinyl alcohol copolymers, wherein if the polyvinyl alcohol or vinyl alcohol copolymers are present in the drilling fluid, the weight ratio of the sum of the polyvinyl alcohol or vinyl alcohol copolymers to the total weight of the drilling fluid is less than or equal to 1.5:100;
one or more water-soluble acid catalyst precursors, wherein the weight ratio of the sum of the one or more water-soluble acid catalyst precursors to the total weight of the drilling fluid is from 0.5:100 to 2:100;
a rheology modifier; a basic additive comprising sodium hydroxide; and
one or more weighting agents, wherein the weight ratio of the one or more weighting agents to the base fluid is from 10:100 to 100:100;
wherein:
the drilling fluid is in a gelled state such that the apparent viscosity at 300 rpm and 25° C. of the drilling fluid is greater than or equal to 50,000 centiPoise;
the drilling fluid has a density of from 50 pounds per cubic foot to 160 pounds per cubic foot;
the one or more formaldehyde based resins comprises melamine-formaldehyde resin;
the one or more water-soluble acid catalyst precursors comprises ethyl lactate;
the weight ratio of the basic additive to the base fluid is from 0.001:100 to 5:100;
the one or more weighting agents comprises barite.

2. The drilling fluid of claim 1 , wherein the base fluid comprises an aqueous solution.

3. The drilling fluid of claim 1 , wherein the base fluid comprises a non-aqueous solution.

4. The drilling fluid of claim 1 , wherein:
the one or more formaldehyde based resins consists of melamine-formaldehyde resin; and
the one or more water-soluble acid catalyst precursors consists of ethyl lactate.

5. The drilling fluid of claim 1 , wherein:
the base fluid consists of water;
the one or more formaldehyde based resins consists of melamine-formaldehyde resin;
the one or more water-soluble acid catalyst precursors consists of ethyl lactate;
the basic additive consists of sodium hydroxide;
the one or more weighting agents consists of barite; and
the rheology modifier consists of bentonite, guar gum, polyanionic cellulose polymer, and starch.

6. The drilling fluid of claim 1 , wherein the rheology modifier comprises one or more of bentonite, guar gum, polyanionic cellulose polymer, or starch.

7. The drilling fluid of claim 1 , wherein the rheology modifier comprises bentonite, guar gum, polyanionic cellulose polymer, and starch.

8. A sealed subterranean petroleum formation comprising:
a subterranean wellbore positioned adjacent a subterranean petroleum formation; and
a drilling fluid positioned in the subterranean wellbore, the drilling fluid consisting of:
a base fluid comprising an aqueous or non-aqueous solution;
one or more formaldehyde-based resins, wherein the weight ratio of the one or more formaldehyde-based resins to the base fluid is from 10:100 to 20:100;
optionally polyvinyl alcohol or vinyl alcohol copolymers, wherein if the polyvinyl alcohol or vinyl alcohol copolymers are present in the drilling fluid, the weight ratio of the sum of the polyvinyl alcohol or vinyl alcohol copolymers to the total weight of the drilling fluid is less than or equal to 1.5:100;
one or more water-soluble acid catalyst precursors, wherein the weight ratio of the sum of the one or more water-soluble acid catalyst precursors to the total weight of the drilling fluid is from 0.5:100 to 2:100;
a rheology modifier; a basic additive comprising sodium hydroxide; and
one or more weighting agents, wherein the weight ratio of the one or more weighting agents to the base fluid is from 10:100 to 100:100;
wherein:
the drilling fluid is in a gelled state such that the apparent viscosity at 300 rpm and 25° C. of the drilling fluid is greater than or equal to 50,000 centiPoise;
the drilling fluid has a density of from 50 pounds per cubic foot to 160 pounds per cubic foot;
the one or more formaldehyde based resins comprises melamine-formaldehyde resin;
the one or more water-soluble acid catalyst precursors comprises ethyl lactate;
the weight ratio of the basic additive to the base fluid is from 0.001:100 to 5:100;
the one or more weighting agents comprises barite.

9. The drilling fluid of claim 8 , wherein the rheology modifier comprises one or more of bentonite, guar gum, polyanionic cellulose polymer, or starch.

10. The drilling fluid of claim 8 , wherein the rheology modifier comprises bentonite, guar gum, polyanionic cellulose polymer, and starch.

Assignees

• Saudi Arabian Oil Co

Inventors

• Wagle Vikrant
• Al-Yami Abdullah
• Alalhareth Nasser

Classifications

• C04B26/125

  Melamine-formaldehyde condensation polymers · CPC title

• E21B21/003

  Means for stopping loss of drilling fluid (plastering the borehole wall E21B33/138) · CPC title

• C09K8/487

  Fluid loss control additives; Additives for reducing or preventing circulation loss · CPC title

• C09K8/035 Primary

  Organic additives · CPC title

• C09K8/5086

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title