Multichroic glasses with praseodymium and neodymium

Patent metadata

Field	Value
Publication number	US-11535549-B2
Application number	US-201716093459-A
Country	US
Kind code	B2
Filing date	Apr 13, 2017
Priority date	Apr 14, 2016
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

A glass that includes Pr 2 O 3 and Nd 2 O 3 such that the sum of Pr 2 O 3 and Nd 2 O 3 is greater than 0.2 mole % and the ratio of Nd 2 O 3 to Pr 2 O 3 is greater than 0.5 and less than 3. Further, the sum of any chromophores in the glass from the group V 2 O 5 , Cr 2 O 3 , MnO, Mn 2 O 3 , Fe 2 O 3 , CoO, Co 3 O 4 , CuO, NiO, Nb 2 O 5 , CeO 2 , Ho 2 O 3 and Er 2 O 3 is less than 0.1 mole %. The glass can be characterized by a substantially pink color upon exposure to an incandescent light source and a substantially green color upon exposure to a fluorescent light source. The glass can optionally include one or more fluorescent ions selected from oxides of Cu, Sn, Mn, Ag, Sb, Ce, Sm, Eu, Tb, Dy, Tm, and combinations thereof, such that a total concentration of fluorescent ions is from greater than or equal to about 0.01 mole % to less than or equal to about 5.0 mole %.

First claim

What is claimed is:

1. A glass, comprising:
Pr 2 O 3 ranging from 0.7 to 3.0 mole %; and
Nd 2 O 3 , ranging from 1.0 to 4 mole %,
wherein and the ratio of Nd 2 O 3 to Pr 2 O 3 is greater than 1.1 and less than 1.5, and
further wherein CoO, if present, is less than 0.01 mole % and Fe 2 O 3 , if present, is less than 0.004 mole %.

2. The glass according to claim 1 , wherein Nb 2 O 5 , if present, is less than 0.5 mole %, Ce 2 O 3 , if present, is less than 1 mole %, and Er 2 O 3 , if present, is less than 1 mole %.

3. The glass according to claim 1 , further comprising:
one or more fluorescent ions selected from the group consisting of oxides of Yb, Cu, Sn, Mn, Ag, Sb, Ce, Sm, Eu, Tb, Dy, Tm, and combinations thereof,
wherein a total concentration of fluorescent ions is from greater than or equal to about 0.01 mole % to less than or equal to about 5.0 mole %.

4. A glass, comprising:
Pr 2 O 3 ; and
Nd 2 O 3 ,
wherein (Pr 2 O 3 +Nd 2 O 3 ) is greater than 0.2 mole % and the ratio of Nd 2 O 3 to Pr 2 O 3 is greater than 1 and less than 1.9, and
further wherein CoO, if present, is less than 0.01 mole % and Fe 2 O 3 , if present, is less than 0.004 mole %, and
one or more chromophores selected from the group consisting of V 2 O 5 , Cr 2 O 3 , MnO, Mn 2 O 3 , Fe 2 O 3 , CoO, CO 3 O 4 , CuO, NiO, Nb 2 O 5 , CeO 2 , Ho 2 O 3 and Er 2 O 3 ,
wherein the sum of V 2 O 5 , Cr 2 O 3 , MnO, Mn 2 O 3 , Fe 2 O 3 , CoO, CO 3 O 4 , CuO, NiO, Nb 2 O 5 , CeO 2 , Ho 2 O 3 and Er 2 O 3 chromophores is less than 0.1 mole %.

5. The glass according to claim 1 , wherein the glass is characterized by a first color upon exposure to an incandescent light source and a second color upon exposure to a fluorescent light source, the first and second colors distinct from one another.

6. The glass according to claim 1 , wherein the glass is further characterized by a color difference (CD) of at least 3.0 from being subjected to a D65-10 illumination condition and an F02-10 illumination condition.

7. A glass, comprising:
Pr 2 O 3 ranging from 0.7 to 3.0 mole %, and
Nd 2 O 3 ranging from 1.0 to 4 mole %,
wherein the ratio of Nd 2 O 3 to Pr 2 O 3 is greater 1.1 and less than 1.5, and
further wherein the sum of V 2 O 5 , Cr 2 O 3 , MnO, Mn 2 O 3 , Fe 2 O 3 , CoO, CO 3 O 4 , CuO, NiO, Nb 2 O 5 , CeO 2 , Ho 2 O 3 and Er 2 O 3 chromophores, if any of the chromophores are present, is less than 0.1 mole %.

8. The glass according to claim 7 , wherein Mn 2 O 3 , if present, is less than 0.04 mole %.

9. The glass according to claim 7 , further comprising:
one or more chromophores selected from the group consisting of V 2 O 5 , Cr 2 O 3 , MnO, Mn 2 O 3 , Fe 2 O 3 , CoO, Co 3 O 4 , CuO, NiO, Nb 2 O 5 , CeO 2 , Ho 2 O 3 and Er 2 O 3 .

10. A glass, comprising:
Pr 2 O 3 ; and
Nd 2 O 3 ,
wherein (Pr 2 O 3 +Nd 2 O 3 ) is greater than 0.2 mole % and the ratio of Nd 2 O 3 to Pr 2 O 3 is greater than 0.5 and less than 3, and
further wherein the sum of V 2 O 5 , Cr 2 O 3 , MnO, Mn 2 O 3 , Fe 2 O 3 , CoO, CO 3 O 4 , CuO, NiO, Nb 2 O 5 , CeO 2 , Ho 2 O 3 and Er 2 O 3 chromophores, if any of the chromophores are present, is less than 0.1 mole %, and
one or more fluorescent ions selected from the group consisting of oxides of Yb, Cu, Sn, Mn, Ag, Sb, Ce, Sm, Eu, Tb, Dy, Tm, and combinations thereof,
wherein a total concentration of fluorescent ions is from greater than or equal to about 0.01 mole % to less than or equal to about 5.0 mole %.

11. The glass according to claim 7 , wherein the glass is characterized by a first color upon exposure to an incandescent light source and a second color upon exposure to a fluorescent light source, the first and second colors distinct from one another.

12. The glass according to claim 7 , wherein the glass is further characterized by a color difference (CD) of at least 3.0 from being subjected to a D65-10 illumination condition and an F02-10 illumination condition.

13. A glass, comprising:
SiO 2 at greater than 70 mole %;
Pr 2 O 3 ranging from 0.7 to 3.0 mole %; and
Nd 2 O 3 ranging from 1.0 to 4 mole %,
wherein the ratio of Nd 2 O 3 to Pr 2 O 3 is greater than 1.1 and less than 1.5, and
further wherein the sum of Fe 2 O 3 , CeO 2 , and TiO 2 , if any are present, is less than 1 mole %.

14. The glass according to claim 13 , wherein the sum of Mn 2 O 3 , Fe 2 O 3 , NiO and CeO 2 , if any are present, is less than 2 mole %.

15. A glass article, comprising:
a substrate comprising a glass according to claim 12 , wherein the substrate further comprises a compressive stress region having a maximum compressive stress of at least 50 MPa and a depth of layer (DOL) of at least 15 microns in thickness.

16. A glass article, comprising:
a substrate comprising a glass according to claim 1 , wherein the substrate further comprises a compressive stress region having a maximum compressive stress of at least 50 MPa and a depth of layer (DOL) of at least 15 microns in thickness.

17. A glass article, comprising:
a substrate comprising a glass according to claim 13 , wherein the substrate further comprises a compressive stress region having a maximum compressive stress of at least 50 MPa and a depth of layer (DOL) of at least 15 microns in thickness.

Assignees

• Corning Inc

Inventors

• Dejneka Matthew John

Classifications

• C03C3/095 Primary

  containing rare earths · CPC title

• C03C4/04

  for photosensitive glass · CPC title

• C03C4/12 Primary

  for luminescent glass; for fluorescent glass · CPC title