Leached superabrasive elements and systems, methods and assemblies for processing superabrasive materials

Patent metadata

Field	Value
Publication number	US-11535520-B1
Application number	US-202016909838-A
Country	US
Kind code	B1
Filing date	Jun 23, 2020
Priority date	May 31, 2015
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

A method of processing a polycrystalline diamond body includes positioning an electrode near the polycrystalline diamond body such that a gap is defined between the electrode and the polycrystalline diamond body, the polycrystalline diamond body having a metallic material disposed in interstitial spaces defined within the polycrystalline diamond body. The method includes applying a voltage between the electrode and the polycrystalline diamond body, and passing a processing solution through the gap. The electrode is a cathode and the polycrystalline diamond body is an anode. An assembly for processing a polycrystalline diamond body includes the polycrystalline diamond body, an electrode positioned such that a gap is defined between the electrode and the polycrystalline diamond body, a processing solution passing through the gap such that the processing solution is in electrical communication with each of the polycrystalline diamond body and the electrode, and at least one power source.

First claim

What is claimed is:

1. A method of processing a polycrystalline diamond body, the method comprising:
positioning an electrode near a polycrystalline diamond body such that a gap is defined between the electrode and the polycrystalline diamond body, the polycrystalline diamond body comprising a metallic material disposed in interstitial spaces defined within the polycrystalline diamond body;
applying a voltage between the electrode and the polycrystalline diamond body, wherein the electrode is a cathode and the polycrystalline diamond body is an anode;
pumping a processing solution to cause flow of the processing solution within an internal passage extending through the electrode and discharge of the processing solution from the internal passage toward the diamond body.

2. The method of claim 1 , wherein the processing solution is in electrical communication with each of the electrode and the polycrystalline diamond body during the application of the voltage.

3. The method of claim 1 , wherein the processing solution leaches the metallic material from interstitial spaces within at least a volume of the polycrystalline diamond body.

4. The method of claim 1 , wherein the processing solution comprises am aqueous electrolyte solution having an electrolyte concentration between about 0.01M and about 3M.

5. The method of claim 1 , wherein the processing solution comprises an electrolyte component selected from the group consisting of acetic acid, ammonium chloride, arsenic acid, ascorbic acid, carboxylic acid, citric acid, formic acid, hydrobromic acid, hydrofluoric acid, hydroiodic acid, lactic acid, malic acid, nitric acid, oxalic acid, phosphoric acid, propionic acid, pyruvic acid, succinic acid, tartaric acid, and combinations thereof.

6. The method of claim 1 , wherein the processing solution comprises at least one of an ion, a salt, and an ester of a component selected from the group consisting of acetic acid, ammonium chloride, arsenic acid, ascorbic acid, carboxylic acid, citric acid, formic acid, hydrobromic acid, hydrofluoric acid, hydroiodic acid, lactic acid, malic acid, nitric acid, oxalic acid, phosphoric acid, propionic acid, pyruvic acid, succinic acid, tartaric acid, and combinations thereof.

7. The method of claim 1 , wherein the electrode comprises a material selected from the group consisting of copper, tungsten carbide, cobalt, zinc, iron, platinum, palladium, niobium, graphite, graphene, nichrome, gold, silver, and combinations thereof.

8. The method of claim 1 , wherein the processing solution comprises a metal salt.

9. The method of claim 1 , further comprising the step of disposing a masking layer over a least a portion of the polycrystalline diamond body.

10. A method of processing a polycrystalline diamond body, the method comprising:
positioning an electrode near a polycrystalline diamond body such that a gap is defined between the electrode and the polycrystalline diamond body, the polycrystalline diamond body comprising a metallic material disposed in interstitial spaces defined within the polycrystalline diamond body;
applying a voltage between the electrode and the polycrystalline diamond body, wherein the electrode is a cathode and the polycrystalline diamond body is an anode;
pumping a processing solution to cause flow of the processing solution into an internal passage extending through the electrode in a vertical direction toward the polycrystalline diamond body and discharge of the processing solution at an opposing end of the internal passage extending through the electrode and into and along the gap, the processing solution being discharged at a flow rate of between approximately 1 L/min and approximately 100 L/min.

11. The method of claim 10 , wherein the processing solution is in electrical communication with each of the electrode and the polycrystalline diamond body during the application of the voltage.

12. The method of claim 10 , wherein the processing solution leaches the metallic material from interstitial spaces within at least a volume of the polycrystalline diamond body.

13. The method of claim 10 , wherein the electrode does not directly contact the polycrystalline diamond body.

14. The method of claim 10 , wherein the processing solution comprises am aqueous electrolyte solution.

15. The method of claim 10 , wherein the processing solution comprises an electrolyte component selected from the group consisting of acetic acid, ammonium chloride, arsenic acid, ascorbic acid, carboxylic acid, citric acid, formic acid, hydrobromic acid, hydrofluoric acid, hydroiodic acid, lactic acid, malic acid, nitric acid, oxalic acid, phosphoric acid, propionic acid, pyruvic acid, succinic acid, tartaric acid, and combinations thereof.

16. The method of claim 10 , wherein the processing solution comprises at least one of an ion, a salt, and an ester of a component selected from the group consisting of acetic acid, ammonium chloride, arsenic acid, ascorbic acid, carboxylic acid, citric acid, formic acid, hydrobromic acid, hydrofluoric acid, hydroiodic acid, lactic acid, malic acid, nitric acid, oxalic acid, phosphoric acid, propionic acid, pyruvic acid, succinic acid, tartaric acid, and combinations thereof.

17. The method of claim 10 , wherein the processing solution comprises a metal salt.

18. The method of claim 10 , further comprising the step of disposing a masking layer over a least a portion of the polycrystalline diamond body.

19. The method of claim 12 , further comprising the step of generating a pressure of about 0.5 bar to about 20 bar of the processing solution.

20. A method of processing a polycrystalline diamond body, the method comprising:
positioning an electrode near a polycrystalline diamond body such that a gap is defined between the electrode and the polycrystalline diamond body, the polycrystalline diamond body comprising a metallic material disposed in interstitial spaces defined within the polycrystalline diamond body;
applying a voltage between the electrode and the polycrystalline diamond body, wherein the electrode is a cathode and the polycrystalline diamond body is an anode;
pumping a processing solution to cause pressurized flow of the processing solution within an internal passage extending through the electrode and discharge of the processing solution, wherein the pumping comprises creating a pressure of about 0.5 bar to about 20 bar.

Assignees

• Us Synthetic Corp

Inventors

• Chapman Mark Pehrson

Classifications

• C01B32/28 Primary

  After-treatment, e.g. purification, irradiation, separation or recovery · CPC title

• C25C1/00

  Electrolytic production, recovery or refining of metals by electrolysis of solutions (C25C5/00 takes precedence) · CPC title

• C25C7/00

  Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells (for the production of aluminium C25C3/06 - C25C3/22) · CPC title

• C25F7/00

  Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects (for both electrolytic coating and removal C25D); Servicing or operating · CPC title

• C25F3/14

  locally · CPC title