Antifog sealant composition and coextruded multilayer polyester film including the same

Patent metadata

Field	Value
Publication number	US-11535018-B2
Application number	US-201816488074-A
Country	US
Kind code	B2
Filing date	Feb 26, 2018
Priority date	Feb 27, 2017
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

The invention relates to a sealant antifog composition for polyester films comprising anionic and non-ionic surfactants in a mixture of amorphous and (semi)crystalline polyesters. The invention also relates to a multi-layer film comprising a sealant layer having the above composition, to the use of said films in food packaging and to the packages obtained therefrom.

First claim

The invention claimed is:

1. A sealant antifog composition for polyester films comprising
a1) an anionic surfactant, in an amount of at least 1% by weight,
a2) a non-ionic surfactant, in an amount of at least 0.5% by weight,
b) at least one amorphous (co)polyesters in an amount between 10% and 85% by weight,
c) at least one (semi)crystalline polyester in an amount between 10% and 85% by weight, and
wherein component b) and c) are present in a total amount of at least 70% by weight, all the percentages by weight being referred to the total weight of the composition.

2. The sealant antifog composition according to claim 1 , wherein said anionic surfactant a1) is in an amount, with respect to the total weight of the composition, of at least 1.5%, and less than 8% and said non ionic surfactant a2) is in an amount, with respect to the total weight of the composition, of between 1 and 3%, the ratio between said anionic surfactant a1) and said non ionic surfactant a2) is lower than 2.

3. The sealant antifog composition according to claim 1 , wherein said anionic surfactant a1) is selected from the group consisting of: sodium lauryl sulfate; 2-ethylhexylsulfate; polyoxyethylene alkyl ether acetates; alkylsulphonates; sodium dodecylbenenzesulfonate; alkyl-aryl phosphates; ether-phosphates; phosphate esters; ethylene oxide adduct phosphate esters; and acyl-N-methyltaurin; sulfosuccinates; alkyl ether sulfonic acids; linear benzenesulfonic acids; α-olefinsulfonic acids; dialkylsulfosuccinic acids; arylsulfonic acids; esters of polyoxyethylenealkylphenyl; and ethersulfuric acids; and a2) is selected from the group consisting of: glycol alkyl ethers; glycerol alkyl esters; sorbitan alkyl esters; organosiloxanes; functionalized organosiloxanes; alkyl-substituted pyrrolidone; polyoxyalkylene ethers; and ethyleneoxidepropylenenoxide block copolymer.

4. The sealant antifog composition according to claim 1 , wherein said at least one amorphous (co)polyesters b) is present in an amount, with respect to the total weight of the composition, of at least 60% or said at least one (semi)crystalline polyester c) is present in an amount, with respect to the total weight of the composition, of at least 60%.

5. The sealant antifog composition according to claim 1 , which comprises between 60 and 85% of at least one amorphous (co)polyesters b) and between 10 and 35% of at least one (semi)crystalline polyester c) or between 60 and 85% of at least one (semi)crystalline polyester c) and between 10 and 35% of at least one amorphous (co)polyesters b).

6. The sealant antifog composition according to claim 1 , wherein the composition comprises an ethylene-alpha-olefin copolymer, an amount between 5 and 28.5 and said ethylene-alpha-olefin is a linear low density polyethylene (LLDPE) with a density between 0.900 g/cc and 0.930 g/cc as measured by ASTM D792.

7. The sealant antifog composition according to claim 1 , wherein component b) and c) total to include at least 45% by weight of aromatic polyesters and (co)polyesters in which the only or the prevalent dicarboxylic acid is terephtalic acid and said amorphous (co)polyester b) is a poly(ethylene terephthalate) copolymer or is a co-polyester of terephthalic acid with an aliphatic diol and a cycloaliphatic diol and said (semi)crystalline polyester c) is poly(ethylene terephthalate) (PET); percentages by weight being referred to the total weight of the composition.

8. The sealant antifog composition according to claim 1 further comprising d) an ethylene-alpha-olefin copolymer.

9. The sealant antifog composition according to claim 8 , wherein the composition does not comprise an ethylene-alpha-olefin copolymer d) and components b) and c) are present in a total amount of at least 90% with respect to the total weight of said sealant composition.

10. An antifog heat-sealable multilayer packaging film comprising at least:
1) A sealant layer consisting of
a1) an anionic surfactant, in an amount of at least 1% by weight,
a2) a non-ionic surfactant, in an amount of at least 0.5% by weight,
b) at least one amorphous (co)polyesters in an amount between 10% and 85% by weight,
c) at least one (semi)crystalline polyester in an amount between 10% and 85% by weight, and
wherein component b) and c) are present in a total amount of at least 70% by weight,
all the percentages by weight being referred to the total weight of the composition; and
d) optionally an ethylene-alpha-olefin copolymer,

2) a polyester containing layer, and
3) an outer polyester containing layer.

11. The film according to claim 10 , having a number of layers between 2 and 10.

12. The film according to claim 10 , which is mono oriented and is heat shrinkable.

13. The film according to claim 10 , wherein any of i) the total thickness of the film is between 10 and 100 microns; and a first layer has a thickness between 1 and 30 microns; and a second layer has a thickness of between 5 and 70 microns; or ii) the ratio between the thickness of the first layer and that of the second layer is between 1:3 and 1:10 or iii) both i) and ii).

14. The film according to claim 10 , wherein the film is oriented.

15. The film according to claim 10 , wherein the film is a coextruded film.

16. The film according to claim 10 , wherein the film is biaxially oriented and is heat shrinkable.

17. A wrapped package comprising a product, placed on a support and a film wrapped around said product or around both the product and the support, wherein the sealant layer of the film is in contact with or faces the product,
wherein the film is an antifog heat-sealable multilayer packaging film comprising at least:
1) A sealant layer consisting of
a1) an anionic surfactant, in an amount of at least 1% by weight,
a2) a non-ionic surfactant, in an amount of at least 0.5% by weight,
b) at least one amorphous (co)polyesters in an amount between 10% and 85% by weight,
c) at least one (semi)crystalline polyester in an amount between 10% and 85% by weight, and
d) optionally an ethylene-alpha-olefin copolymer,
wherein component b) and c) are present in a total amount of at least 70% by weight,
all the percentages by weight being referred to the total weight of the composition; and
2) A polyester containing layer.

18. The wrapped package according to claim 17 , wherein the multilayer packaging film further comprises 3) an outer polyester containing layer.

Assignees

• Cryovac Llc

Inventors

• Forloni Roberto
• Haxhi Aida

Classifications

• B32B27/36 Primary

  comprising polyesters · CPC title

• C08L2203/162

  sealable films · CPC title

• B32B7/04

  Interconnection of layers · CPC title

• B32B2307/31

  Heat sealable · CPC title

• C08K5/06

  Ethers; Acetals; Ketals; Ortho-esters · CPC title