Postponed differentiation of reinforced composites

Patent metadata

Field	Value
Publication number	US-11534942-B2
Application number	US-201515115981-A
Country	US
Kind code	B2
Filing date	Feb 4, 2015
Priority date	Feb 6, 2014
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

A reinforced composite is provided that includes at least one planar fiber reinforcement or fabric formed from a plurality of fibers. The fiber reinforcement or fabric has a first side and a second side. The reinforced composite further includes a chemical treatment coated on at least one of said first side and second side and a matrix material.

First claim

The invention claimed is:

1. A reinforced composite comprising:
at least one fabric formed from a plurality of fibers having a sizing composition and a single chemical treatment disposed thereon, wherein the sizing composition includes a film former and a coupling agent;
said chemical treatment being coated on a surface of the fabric, wherein the chemical treatment is present on the fabric in an amount from 1 weight percent to 20 weight percent and the chemical treatment consists of one or more of a polyamide having a melting point less than 250° C., a reactive compound selected from a primary amine, primary amide, styrene-maleic anhydride, and mixtures thereof; and
a thermoplastic matrix material, wherein the sizing composition is not compatible with the thermoplastic matrix material and the chemical treatment increases the compatibility between the sizing composition and the thermoplastic matrix material.

2. The reinforced composite of claim 1 , wherein said fibers are continuous glass fibers.

3. The reinforced composite of claim 1 , wherein said thermoplastic material comprises a polyamide.

4. The reinforced composite of claim 1 , wherein chemical treatment consists of the reactive compound selected from a primary amine, primary amide, styrene-maleic anhydride, and mixtures thereof.

5. A laminate comprising:
a first fabric formed from a plurality of fibers having at least one fabric formed from a plurality of fibers having a sizing composition and a single first chemical treatment disposed thereon, wherein the first sizing composition includes a film former and a coupling agent, the first fabric having a first side and a second side;
said first chemical treatment being coated on the first side of the first fabric, wherein the first chemical treatment is present on the first fabric in an amount from 1 weight percent to 20 weight percent and the first chemical treatment consists of one or more of a first polyamide having a melting point less than 250° C., a first reactive compound selected from a primary amine, primary amide, styrene-maleic anhydride, and mixtures thereof;
a first thermoplastic matrix material coated on the first chemical treatment, wherein the first sizing composition is not compatible with said first thermoplastic matrix material and the first chemical treatment increases the compatibility between the first sizing composition and the first thermoplastic matrix material;
a second fabric formed from a plurality of fibers having a second sizing composition at least one fabric formed from a plurality of fibers having a sizing composition and a single second chemical treatment disposed thereon, wherein the second sizing composition includes a film former and a coupling agent, the second fabric having a first side and a second side, wherein the second side of the second fabric is laminated to the first thermoplastic matrix material;
said second chemical treatment being coated on the first side of the second fabric, wherein the second chemical treatment is present on the second fabric in an amount from 1 weight percent to 20 weight percent and the second chemical treatment consists of one or more of a second polyamide having a melting point less than 250° C., a second reactive compound selected from a primary amine, primary amide, styrene-maleic anhydride, and mixtures thereof; and
a second thermoplastic matrix material coated on the second chemical treatment, wherein the second sizing composition is not compatible with said second thermoplastic matrix material and the second chemical treatment increases the compatibility between the second sizing composition and the second thermoplastic matrix material.

6. The reinforced composite of claim 1 , wherein the chemical treatment is selected from one or more of the group consisting of polyamidoamine, polyamine, 4,4′-methylenebis-(cyclohexylamine), polyoxypropylene diamine, triethyleneglycol diamine, trimethylopropane-polyoxypropylene triamine, bis(2-aminopropyl)ether, aminopropylvinyl ether, and polybutadiene diamine.

7. The laminate of claim 5 , wherein the first chemical treatment and the second chemical treatment are each individually selected from one or more of the group consisting of polyamidoamine, polyamine, 4,4′-methylenebis-(cyclohexylamine), polyoxypropylene diamine, triethyleneglycol diamine, trimethylopropane-polyoxypropylene triamine, bis(2-aminopropyl)ether, aminopropylvinyl ether, and polybutadiene diamine.

8. A reinforced composite comprising:
at least one fabric formed from a plurality of fibers having a sizing composition and a single chemical treatment disposed thereon;
said chemical treatment being coated on a surface of the fabric, wherein the chemical treatment is present on the fabric in an amount from 1 weight percent to 20 weight percent and the chemical treatment consists of one or more of the group consisting of polyamidoamine, polyamine, 4,4′-methylenebis-(cyclohexylamine), polyoxypropylene diamine, triethyleneglycol diamine, trimethylopropane-polyoxypropylene triamine, bis(2-aminopropyl)ether, aminopropylvinyl ether, and polybutadiene diamine; and
a thermoplastic matrix material, wherein the sizing composition is not compatible with the thermoplastic matrix material.

9. The reinforced composite of claim 8 , wherein the sizing composition includes a film former and a coupling agent.

Assignees

• Owens Corning Intellectual Capital Llc
• Owens Coming Intellectual Capital Llc

Inventors

• Moireau Patrick
• Roederer Francois
• Viana Jean-Louis

Classifications

• C03C25/328

  Polyamides · CPC title

• C08J5/08

  glass fibres · CPC title

• D06M15/61

  Polyamines {polyimines} · CPC title

• B32B2457/08

  PCBs, i.e. printed circuit boards · CPC title

• D06M15/53

  Polyethers (polyacetals D06M15/39) · CPC title