Method of filtration using porous membranes

Patent metadata

Field	Value
Publication number	US-11534723-B2
Application number	US-201816642218-A
Country	US
Kind code	B2
Filing date	Sep 4, 2018
Priority date	Sep 7, 2017
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

A filtration method that includes a cleaning step using a chemical agent, wherein provided is the filtration method with excellent chemical resistance performance. The filtration method pertaining to the present invention comprises a filtration step in which a liquid to be filtered is filtered by being passed through a porous membrane formed of a resin, and a cleaning step in which the membrane interior of the porous membrane is cleaned after the filtration step, wherein a porous membrane for which the area ratio of a resin part having an area of 1 μm 2 or less included in a cross section of the membrane interior is at least 70% of the total area of the entire resin part included in the cross section, and said cleaning step includes a step in which an aqueous solution of at least 1% sodium hydroxide is passed through the porous membrane.

First claim

The invention claimed is:

1. A method of filtration comprising:
a filtration in which a liquid to be filtered is filtered through a porous membrane formed from a resin, and cleaning an inside of the porous membrane after the filtration,
wherein the porous membrane has, in all visual fields in a cross section of the inside of the membrane, an area proportion of a resin portion having an area of 0.1 μm 2 or more and 1 μm 2 or less in each of the visual fields, which is 70% or more relative to a total area of all resin portions included in each of the visual fields, and an area proportion of a resin portion having an area of more than 1 μm 2 and less than 10 μm 2 in each of the visual fields, which is 2% to 30% relative to the total area of all the resin portions included in each of the visual fields, and an area proportion of a resin portion having an area of 10 μm 2 or more in each of the visual fields, which is 15% or less relative to the total area of all the resin portions included in each of the visual fields, and the porous membrane is formed from a fluorine resin of a polymer selected from a group consisting of vinylidene fluoride resin (PVDF), ethylene-monochlorotrifluoroethylene copolymer (ECTFE), and ethylene-tetrafluoroethylene copolymer (ETFE), and
the porous membrane is used in the cleaning comprising passing a 4% or more sodium hydroxide aqueous solution through the porous membrane,
wherein a relationship between an elongation E0 of the porous membrane before the cleaning and an elongation E10 of the porous membrane after the cleaning is E10/E0×100≥70%, and
wherein a relationship between a flux L0 of the porous membrane at a start of the cleaning and a flux L10 of the porous membrane after the cleaning is 105≥% L10/L0×100≥95%.

2. The method of filtration according to claim 1 , wherein the porous membrane is a hollow fiber membrane.

3. The method of filtration according to claim 1 , further comprising a rinsing including discharging a cleaning agent remaining inside the porous membrane after the cleaning,
wherein the cleaning includes passing a chemical solution, containing the 4% or more sodium hydroxide aqueous solution, through the porous membrane when a flux becomes 50% or less with respect to an initial flux L0 of the porous membrane,
the rinsing includes using 10 L or less of rinse water per 1 m 2 of a membrane area,
a pH of filtered water when restarting the filtration after the rinsing is 9 or less, and
a flux L20 after repeating 20 times the filtration, the cleaning, and the rinsing, has relationship represented by the following equation:
105%≥ L′ 20/ L 0×100≥80%

with respect to the initial flux L0 of the porous membrane.

Assignees

• Asahi Chemical Ind

Inventors

• Okamura Daisuke

Classifications

• B01D71/34

  Polyvinylidene fluoride · CPC title

• C02F2303/16

  Regeneration of sorbents, filters · CPC title

• C08J9/26

  by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out · CPC title

• B01D65/02 Primary

  Membrane cleaning or sterilisation {; Membrane regeneration} · CPC title

• B01D2321/164

  Use of bases · CPC title