Polyelectrolyte-layer forming block copolymers and compositions and uses thereof

Patent metadata

Field	Value
Publication number	US-11533910-B2
Application number	US-201916653595-A
Country	US
Kind code	B2
Filing date	Oct 15, 2019
Priority date	Dec 10, 2015
Publication date	Dec 27, 2022
Grant date	Dec 27, 2022

Abstract

The present invention relates generally to polyelectrolyte-layer forming block copolymers adsorbed at colloid interfaces in aqua solution and compositions and uses thereof. In particular, the present invention relates to agricultural material compositions comprising particles of at least one agricultural material and a polyelectrolyte-layer forming block copolymer. The present invention also relates to non-agricultural material compositions comprising particles of at least one non-agricultural material and a polyelectrolyte-layer forming block co-polymer.

First claim

We claim:

1. An agricultural material composition comprising:
(i) particles of at least one agricultural material compound; and
(ii) a dispersant system comprising a polyelectrolyte layer-forming block copolymer, wherein the block copolymer comprises (A) a hydrophobic anchoring moiety and (B) at least one hydrophilic charged stabilizing moiety comprising at least one charged monomer,
wherein the block co-polymer is adsorbed on hydrophobic surfaces of the agricultural material compound particles,
wherein the hydrophobic anchoring moiety comprises a hydrophobic monomer selected from the group consisting of methylacrylate, ethylacrylate, n-propylacrylate, n-butylacrylate, 2-ethyl-hexyl acrylate, methylmethacrylate, ethylmethacrylate, n-propylmethacrylate, n-butylmethacrylate and 2-ethyl-hexyl methacrylate,
wherein the at least one charged monomer is an anionic monomer having a sulfonate group, and
wherein:
a) the molar ratio of the hydrophobic anchoring moiety to the hydrophilic charged stabilizing moiety is 1:2-4, and wherein (i) the weight of the polyelectrolyte layer-forming block copolymer is 10,000 to 25,000 g/mol, (ii) the weight of the hydrophilic charged stabilizing moiety is 5,000 to 100,000 g/mol, and/or (iii) the hydrophobic anchoring moiety comprises alkyl acrylate monomers and the weight of the hydrophobic anchoring moiety is 1,500 to 3,500 g/mol,
b) the weight ratio of the hydrophobic anchoring moiety to the hydrophilic charged stabilizing moiety is less than 0.6, and/or
c) at least 60% by weight of the hydrophilic charged stabilizing moiety is charged monomers.

2. The composition of claim 1 , wherein the agricultural material compound is a pesticide, a plant growth regulator, a hormone, or a bio-stimulant.

3. The composition of claim 1 , wherein:
a) the composition is an oil in water emulsion,
b) the composition is a suspension concentrate,
c) the composition is granulated,
d) the concentration of agricultural material particles in the composition is greater than 500 g/L,
e) the composition is high-load and the concentration of agricultural material particles in the composition is 900-1200 g/L,
f) the density of the composition is 1.4-1.6 kg/L, and/or
g) the viscosity of the composition is less than 750 cPs when determined at spindle 62 and 12 RPM of Brookfield viscometer.

4. The composition of claim 1 , wherein:
a) the polyelectrolyte-layer forming block copolymer is a linear block copolymer or a comb block copolymer,
b) the hydrophobic anchoring moiety is a hydrophobic block copolymer,
c) at least 90% of the hydrophobic anchoring moiety is hydrophobic monomers,
d) less than 10% of the hydrophobic anchoring moiety is hydrophilic monomers,
e) at least one hydrophilic charged stabilizing moiety is a hydrophilic block copolymer and at least 60% by weight of monomers in the hydrophilic charged stabilizing moiety are charged monomers, and/or
f) less than 40% by weight of the monomers in the hydrophilic charged stabilizing moiety are neural hydrophilic monomers.

5. The composition of claim 1 , wherein
the hydrophobic monomer is selected from the group consisting of methylacrylate, n propylacrylate, n-butylacrylate, 2-ethyl-hexyl acrylate, methylmethacrylate, ethylmethacrylate, n-propylmethacrylate, n-butylmethacrylate and 2-ethyl-hexyl methacrylate.

6. The composition of claim 5 , wherein the hydrophobic monomer is ethyl acrylate (EA).

7. The composition of claim 1 , wherein the at least one anionic monomer is 2-acrylamido-2-methylpropane sulphonate (AMPS).

8. The composition of claim 4 , wherein the neutral hydrophilic monomer is selected from a group consisting of N-vinylpyrrolidone, ethylene oxide, glycoside acrylate, and acrylamide.

9. The composition of claim 1 , wherein:
a. the block copolymer comprises up to 150 monomers,
b. the weight of the block copolymer is up to 31000 g/mol,
c. the weight of the hydrophilic charged stabilizing moiety is 5,000 to 100,000 g/mol,
d. the weight of the hydrophobic anchoring moiety is 500 to 5,000 g/mol,
e. the weight percentage of the hydrophilic charged stabilizing moiety is 65-90% of the total weight of the block copolymer
f. the molar ratio of the hydrophobic anchoring moiety to the hydrophilic charged stabilizing moiety is 1:2-4, and/or
g. the concentration of the block copolymer in the composition is 0.2-3% w/w.

10. A method of (i) controlling and preventing pest and/or (ii) improving plant growth, wherein the method comprises applying the composition of claim 1 to a locus where the pest is to be controlled and prevented a plant, an area adjacent to a plant, soil adapted to support growth of a plant, a root of a plant, foliage of a plant, and/or a seed adapted to produce a plant so as to thereby control and prevent pest and/or improving plant growth.

11. A process of preparing the composition of claim 1 comprising mixing particles of the agricultural material compound with an amount of the polyelectrolyte-layer forming block co-polymer.

12. The composition of claim 1 , wherein the agricultural material is fluensulfone.

13. The composition of claim 1 , wherein the agricultural material is folpet.

14. The composition of claim 1 , wherein the agricultural material is chlorothalonil or pymetrozine.

15. The agricultural material composition of claim 1 , which does not comprise a second polymeric dispersant.

16. The agricultural material composition of claim 1 , wherein the concentration of the block copolymer in the composition is 0.2-3% w/w.

Assignees

• Adama Makhteshim Ltd
• Rhodia Operations

Inventors

• Silbert Gilad
• Berkovitch Michael
• Wilson David James

Classifications

• C09D5/00

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• A01N25/12

  Powders or granules (A01N25/26 takes precedence) · CPC title

• A01N43/80

  five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2 · CPC title

• A01N51/00

  Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring · CPC title

• C08G81/024

  Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G · CPC title