Polylactic acid composite and use thereof

Patent metadata

Field	Value
Publication number	US-11530294-B2
Application number	US-201816644509-A
Country	US
Kind code	B2
Filing date	Jun 26, 2018
Priority date	Nov 27, 2017
Publication date	Dec 20, 2022
Grant date	Dec 20, 2022

Abstract

The present invention discloses a polylactic acid composite and use thereof. The polylactic acid composite includes the following components: (A) 89 to 98 parts by weight of polylactic acid; (B) 1 to 4 parts by weight of talcum powder; and (C) 1 to 7 parts by weight of a plasticizer. In the component (A), the polylactic acid has a polydispersity index P satisfying the following relationship: 1.55≤P≤2.02. In the component (B), the talcum powder has a particle size D(50) satisfying: 1 μm≤D(50)≤2.6 μm. In the component (C), the plasticizer has a relative molecular weight M satisfying: 180≤M≤670. Through research, the present invention has unexpectedly discovered that by using the polylactic acid having the polydispersity index P satisfying the relationship 1.55≤P≤2.02 as a matrix, adding a specific range of content of ultrafine talcum powder as a nucleating agent, and selecting the plasticizer of a specific molecular weight as a crystallization promotion agent, the prepared polylactic acid composite has a light transmittance T≥80%, a haze H≤40%, and a heat deflection temperature HDT≥90° C., having significantly improved heat resistance and transparency.

First claim

What is claimed is:

1. A polylactic acid composite, comprising:
(A) 89 to 98 parts by weight of polylactic acid;
(B) 1-4 parts by weight of talcum powder; and
(C) 1-7 parts by weight of a plasticizer;
wherein in the component (A), a polydispersity index P of the polylactic acid satisfies the following relationship: 1.94≤P≤1.97, and the polylactic acid is synthesized using only lactide as a monomer;
in the component (B), a particle size D(50) of the talcum powder satisfies: 1μm≤D(50)≤2.6μm;
in the component (C), a relative molecular weight M of he plasticizer satisfies: 180≤M≤670,
wherein the plasticizer is one or a mixture of PEG-200, PEG-400, and triacetin.

2. The polylactic acid composite according to claim 1 , wherein in parts by weight, the polylactic acid composite further comprises 0 to 10 parts by weight of a flexibilizer, and the flexibilizer is one or a mixture of aliphatic polyester, aliphatic-aromatic copolyester, ethylene-vinyl acetate copolymer, methyl methacrylate-butadiene-styrene terpolymer, and polyvinyl alcohol.

3. The polylactic acid composite according to claim 2 , wherein the aliphatic polyester is one or a mixture of polycaprolactone (PCL), poly(butylene succinate) (PBS), and polyhydroxybutyrate (PHB); and the aliphatic-aromatic copolyester is an aliphatic-aromatic copolyester of a diacid-diol type.

4. The polylactic acid composite according to claim 1 , wherein in parts by weight, the polylactic acid composite further comprises 0 to 5 parts by weight of an organic filler or an inorganic filler, the organic filler is one or a mixture of natural fiber, straw, and starch; and the inorganic filler is one or a mixture of montmorillonite, kaolin, chalk, calcium carbonate, gypsum, calcium chloride, titanium white, iron oxide, dolomite, silicon dioxide, wollastonite, titanium dioxide, silicate, mica, glass fiber, and mineral fiber.

5. The polylactic acid composite according to claim 1 , wherein in parts by weight, the polylactic acid composite further comprises 0 to 4 parts by weight of other additives as follows: release agent, surfactant, wax, antistatic agent, dye or other plastic additives.

6. The polylactic acid composite according to claim 1 , wherein the polylactic acid composite has a light transmittance T≥80%, a haze H≤40%, and HDT≥90° C.

7. A heat-resistant transparent product comprising the polylactic acid composite according to claim 1 .

8. A heat-resistant transparent product comprising the polylactic acid composite according to claim 2 .

9. A heat-resistant transparent product comprising the polylactic acid composite according to claim 3 .

10. A heat-resistant transparent product comprising the polylactic acid composite according to claim 4 .

Assignees

• Kingfa Science & Technology Co
• Zhuhai Wango Chem Co Ltd

Inventors

• Lu Changli
• Yuan Zhimin
• Cai Tongmin
• Huang Xianbo
• Zeng Xiangbin
• Jiao Jian
• Xiong Kai
• Yang Hui
• Mai Kaijin
• Dong Xueteng
• He Shihua

Classifications

• C08K3/34

  Silicon-containing compounds · CPC title

• C08L2205/24

  Crystallisation aids · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08K2201/003

  Additives being defined by their diameter · CPC title