Method for producing a polyisocyanurate composite material

Patent metadata

Field	Value
Publication number	US-11530290-B2
Application number	US-201716098006-A
Country	US
Kind code	B2
Filing date	May 3, 2017
Priority date	May 4, 2016
Publication date	Dec 20, 2022
Grant date	Dec 20, 2022

Abstract

The invention relates to a process for producing a composite polyisocyanurate material, comprising the following steps: a) providing a polyisocyanate composition A) which comprises oligomeric polyisocyanates and is low in monomeric diisocyanates, “low in monomeric diisocyanates” meaning that the polyisocyanate composition A) has a content of monomeric diisocyanates of not more than 20% by weight, and b) catalytically trimerizing the polyisocyanate composition A) in the presence of at least one fibrous filler B) and of a trimerization catalyst C) to give the composite polyisocyanurate material, where the trimerization catalyst C) comprises at least one metal salt and/or quaternary ammonium salt. The invention further relates to composite polyisocyanurate materials obtainable by the process according to the invention and to the use thereof for production of a component, and to components consisting of or comprising a composite polyisocyanurate material according to the invention.

First claim

The invention claimed is:

1. A process for producing a composite polyisocyanurate material, comprising the following steps:
a) providing a polyisocyanate composition A) consisting of one or more oligomeric polyisocyanates and not more than 0.5% by weight of one or more unconverted monomeric diisocyanates, based on the weight of the polyisocyanate composition A), and
b) catalytically trimerizing the polyisocyanate composition A) in the presence of at least one fibrous filler B) and of a trimerization catalyst C) to give the composite polyisocyanurate material,
wherein the trimerization catalyst C) comprises at least one of a metal salt and a quaternary ammonium salt and an optional polyether; and the trimerization catalyst C) is provided in an amount of from 0.4% to 15.0% by weight based on the weight of the polyisocyanate composition A);
wherein each of the one or more oligomeric polyisocyanates is prepared by: reacting an excess of monomeric diisocyanate, yielding the oligomeric polyisocyanate and the unconverted monomeric diisocyanate, and removing at least a portion of the unconverted monomeric diisocyanate; and
wherein at least 70 wt % of the one or more oligomeric polyisocyanates are oligomeric aliphatic polyisocyanates and/or oligomeric alicyclic polyisocyanates.

2. The process according to claim 1 , wherein at least 80%, 85%, 90%, 95%, 98% or 99% by weight of the one or more oligomeric polyisocyanates are oligomeric aliphatic polyisocyanates and/or oligomeric alicyclic polyisocyanates.

3. The process according to claim 1 , wherein the polyisocyanate composition A) has a mean NCO functionality of 1.0 to 6.0.

4. The process according to claim 1 , wherein at least 50 mol %, based on the sum total of the oligomeric polyisocyanates in the polyisocyanate composition A), have a structure selected from the group consisting of uretdione, urethane, isocyanurate, allophanate, biuret, iminooxadiazinedione and oxadiazinetrione.

5. The process according to claim 1 , wherein 100 mol %, based on the sum of the oligomeric polyisocyanates in the polyisocyanate composition A), have a structure selected from the group consisting of uretdione, allophanate, biuret, iminooxadiazinedione and oxadiazinetrione.

6. The process according to claim 1 , wherein the fibrous filler B) is selected from the group consisting of glass fibres, basalt fibres, carbon fibres and mixtures thereof.

7. The process according to claim 1 , wherein the fibrous filler B) is glass fibres.

8. The process according to claim 1 , wherein the trimerization catalyst C) comprises an alkali metal salt or alkaline earth metal salt of a carboxylic acid.

9. The process according to claim 1 , wherein the trimerization catalyst C) comprises potassium acetate.

10. The process according to claim 1 , wherein the trimerization catalyst C) further comprises a polyethylene glycol as the polyether.

11. The process according to claim 1 , wherein the catalytic trimerization is conducted at a temperature of greater than 150° C. within less than 10 minutes, at least up to a conversion level at which only at most 20% of isocyanate groups originally present in the polyisocyanate composition A) are still present.

12. The process according to claim 11 , wherein the conversion level is a conversion level at which only at most 10% of the isocyanate groups originally present in the polyisocyanate composition A) are present.

13. A composite polyisocyanurate material obtained by a process according to claim 1 .

14. The composite polyisocyanurate material according to claim 13 , wherein the amount of nitrogen in the composite polyisocyanurate material is at least 9% by weight, based on the total weight of the polyisocyanurate plastic matrix in the composite polyisocyanurate material.

15. The composite polyisocyanurate material according to claim 13 , wherein the proportion by weight of metal or metal ions in the composite polyisocyanurate material is at least 0.00025% by weight, based on the polyisocyanate composition A).

16. The composite polyisocyanurate material according to claim 13 , wherein the composite polyisocyanurate material has a density of greater than 1.30 g/cm 3 determined according to DIN EN ISO 1183-1.

17. Components consisting of or comprising a composite polyisocyanurate material according to claim 13 .

Assignees

• Covestro Deutschland Ag

Inventors

• Hocke Heiko
• Matner Mathias
• Achten Dirk
• Heinz Paul

Classifications

• C08G18/092 Primary

  oligomerisation to isocyanurate groups · CPC title

• C08G18/1875

  containing ammonium salts or mixtures of secondary of tertiary amines and acids · CPC title

• C08G18/022

  the polymeric products containing isocyanurate groups · CPC title

• C08K7/06

  Elements · CPC title

• C08G18/792 Primary

  formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates · CPC title