Methods for removing amine contaminants from equipment used in the production of polyether polyols

Patent metadata

Field	Value
Publication number	US-11529657-B2
Application number	US-202117196075-A
Country	US
Kind code	B2
Filing date	Mar 9, 2021
Priority date	Mar 9, 2021
Publication date	Dec 20, 2022
Grant date	Dec 20, 2022

Abstract

Methods of removing amine contaminants from equipment used in the production of polyether polyols. These methods include: (a) contacting the equipment with an aqueous solution of a first acid; (b) discharging the aqueous solution of the first acid from the equipment; (c) contacting the equipment with an aqueous solution of an acidic metal conditioner; (d) discharging the aqueous solution of the acidic metal conditioner from the equipment; (e) contacting the equipment with an aqueous solution of an alkali metal hydroxide; and (f) discharging the aqueous solution of the alkali metal hydroxide from the equipment.

First claim

What is claimed is:

1. A method of removing amine contaminants from equipment used in the production of polyether polyols, comprising:
(a) contacting the equipment with an aqueous solution consisting essentially of a first acid and water;
(b) discharging the aqueous solution of the first acid from the equipment;
(c) following step (b), contacting the equipment with an aqueous solution of an acidic metal conditioner that is different from the aqueous solution of the first acid;
(d) discharging the aqueous solution of the acidic metal conditioner from the equipment;
(e) following step (d), contacting the equipment with an aqueous solution of an alkali metal hydroxide that is different from the aqueous solution of the acidic metal conditioner; and
(f) discharging the aqueous solution of the alkali metal hydroxide from the equipment.

2. The method of claim 1 , further comprising, prior to contacting the equipment with the aqueous solution of the first acid, substantially filling the equipment with water, heating the water to boiling, and then discharging the water from the equipment.

3. The method of claim 1 , further comprising, prior to prior to contacting the equipment with the aqueous solution of the first acid, substantially completely filling the entire volume of the equipment with water and heating the water to a temperature of at least 60° C.

4. The method of claim 1 , wherein the aqueous solution of the first acid comprises p-toluenesulfonic acid, sulfuric acid, hydrochloric acid, hydrobromic acid, nitric acid, trifluoroacetic acid, perchloric acid, or a mixture of any two or more thereof.

5. The method of claim 1 , wherein the aqueous solution of first acid comprises acid in an amount of no more than 5% by weight, based on the total weight of the aqueous solution.

6. The method of claim 1 , wherein alkali metal hydroxide is present in the aqueous solution of alkali metal hydroxide in an amount of no more than 5% by weight, based on the total weight of the aqueous solution.

7. The method of claim 1 , further comprising, after contacting the equipment with the aqueous solution of an alkali metal hydroxide, adding water to the equipment in an amount to fill at least 60% of the equipment volume and heating the water to boiling.

8. The method of claim 1 , wherein the first acid has a pKa of less than about −6.0 at 25° C.

9. The method of claim 1 , wherein the aqueous solution of an acidic metal conditioner consists essentially of a weak acid, water, a surfactant, and, optionally a corrosion inhibitor.

10. The method of claim 1 , further comprising, between steps (d) and (e), the steps of charging water to the equipment and discharging the water from the equipment.

11. The method of claim 1 , wherein step (a) comprises contacting the equipment with an aqueous solution consisting of the first acid and the water.

12. The method of claim 1 , wherein the polyether polyols comprise an amine-initiated polyether polyol and a non-amine initiated polyether polyol, wherein the amine-initiated polyether polyol and the non-amine initiated polyether polyol are prepared using an alkaline catalyst.

13. The method of claim 1 , wherein the equipment comprises a reactor that produces amine-initiated polyether polyol and non-amine initiated polyether polyol.

14. The method of claim 13 , wherein:
(1) the amine-initiated polyether polyol has a functionality of 2 to 6, a number average molecular weight of 200 Da to 12,000 Da, and a hydroxyl number of 300 to 500 mg KOH/g; and
(2) the non-amine initiated polyether polyol has a functionality of 2 to 8, a number average molecular weight of at least 700 Da, and a hydroxyl number of 28 to 150 mg KOH/gram.

15. The method of claim 1 , wherein the acidic metal conditioner comprises an acid and a surfactant, wherein the acid comprises phosphoric acid, hydrofluoric acid, boric acid, or a mixture of any two or more thereof.

16. The method of claim 15 , wherein the acidic metal conditioner is present in the aqueous solution of acidic metal conditioner in an amount of no more than 5% by weight, based on the total weight of the aqueous solution of acidic metal conditioner.

Assignees

• Covestro Llc

Inventors

• Caputo Jenna L
• Christman Ii Mark A
• Starkey Charles D
• Wagner Daniel R
• Barksby Nigel

Classifications

• C08G65/30 Primary

  Post-polymerisation treatment, e.g. recovery, purification, drying · CPC title

• C08G65/2696 Primary

  characterised by the process or apparatus used · CPC title

• C08G65/2627

  containing aromatic or arylaliphatic amine groups · CPC title

• C08G65/2609

  containing aliphatic hydroxyl groups · CPC title

• B01J8/10

  moved by stirrers or by rotary drums or rotary receptacles {or endless belts} · CPC title