Preparation of nanosheets via ball milling in the presence of reactive gases

Patent metadata

Field	Value
Publication number	US-11529635-B2
Application number	US-201716309157-A
Country	US
Kind code	B2
Filing date	Jun 14, 2017
Priority date	Jun 14, 2016
Publication date	Dec 20, 2022
Grant date	Dec 20, 2022

Abstract

A process for producing a material in the form of nanosheets by ball milling of crystals of the material, wherein the ball milling takes place in the presence of a reactive gas.

First claim

The invention claimed is:

1. A process for producing non-functionalized nanosheets or doped nanosheets of a bulk crystalline material having a layered structure, the process comprising providing a dry ball milling apparatus; and using the dry ball milling apparatus to ball mill the bulk crystalline material in a reactive gas selected from ammonia and a hydrocarbon, wherein the non-functionalized nanosheets or doped nanosheets (i) are formed in the ball milling apparatus during ball milling by adjusting one or more dry ball milling parameters of the dry ball milling apparatus selected from milling time, milling speed, milling ball size and milling ball-to-bulk crystalline material weight ratio, and (ii) have a thickness of less than 10 nm.

2. A process according to claim 1 , wherein the bulk crystalline material having a layered structure is selected from graphite, boron nitride, molybdenum disulphide and tungsten disulphide.

3. A process according to claim 1 , wherein the hydrocarbon gas is selected from, methane, ethane, ethene, ethyne and propane.

4. A process according to any one of claims 1 to 3 , wherein the ball milling takes place using a mixture of the reactive gases to produce doped nanosheets.

5. A process according to any one of claims 1 to 3 , wherein the bulk crystalline material comprises a mixture of bulk crystalline material having layered structures, and the mixture is milled in the dry ball milling apparatus to produce composite nanosheets.

6. A process according to any one of claims 1 to 3 , wherein the ball milling takes place for less than 30 hours.

7. A process according to any one of claims 1 to 3 , wherein the ball milling speed is selected from 140, 150 or 160 rpm.

8. A process according to any one of claims 1 to 3 , wherein the milling ball size ranges form 1-25 mm in diameter.

9. A process according to any one of claims 1 to 3 , wherein the milling ball-to-bulk crystalline material weight ratio ranges from 5:1 to 20:1.

Assignees

• Univ Deakin

Inventors

• Chen Ying
• Mateti Srikanth

Classifications

• C01B35/146

  Compounds containing boron and nitrogen, e.g. borazoles (ammonium tetrafluoborates C01B35/063; ammonium borates C01B35/12) · CPC title

• B02C17/1885 Primary

  the applied gas acting to effect material separation (B02C17/1895 takes precedence) · CPC title

• C01B35/14

  Compounds containing boron and nitrogen, phosphorus, sulfur, selenium or tellurium · CPC title

• C01B32/21 Primary

  After-treatment · CPC title

• C01P2004/03

  obtained by SEM · CPC title