Ma-M2T spinel solid solution enhanced magnesium oxide-based ceramic foam filter and preparation method therefor

Patent metadata

Field	Value
Publication number	US-11529577-B2
Application number	US-201816753572-A
Country	US
Kind code	B2
Filing date	Jun 1, 2018
Priority date	Apr 8, 2018
Publication date	Dec 20, 2022
Grant date	Dec 20, 2022

Abstract

An MA-M2T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter and a preparation therefor. The preparation method comprising: 1) preparing a ceramic slurry having a solid content of 60%-70% by dosing 15%-25% by mass of a nanometer alumina sol, 0.8%-1.5% by mass of a rheological agent, and the balance magnesium oxide ceramic powder comprising a nanometer titanium oxide sintering aid, and then adding deionized water and ball milling to mix until uniform, and then vacuum degassing the mixture; 2) soaking a polyurethane foam plastic template into the ceramic slurry, squeezing by a roller press the polyurethane foam plastic template to remove redundant slurry therein to make a biscuit, and drying the biscuit by heating it to 80° C.-120° C.; 3) putting the dried biscuit into a sintering furnace, elevating the temperature to 1400° C.-1600° C. and performing a high temperature sintering, cooling to the room temperature with the furnace to obtain the magnesium oxide-based ceramic foam filter.

First claim

What is claimed is:

1. A method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter wherein the method comprises the steps of:
1) preparing a ceramic slurry having a solid content of 60 wt. %-70 wt. % by dosing 15%-25% by mass of a nanometer alumina sol, 0.8%-1.5% by mass of a rheological agent, and the balance magnesium oxide ceramic powder comprising a nanometer titanium oxide sintering aid, and then adding deionized water and ball milling to mix until uniform, and vacuum degassing the mixture; the rheological agent is a mixture of polyacrylic acid and a cellulose ether, wherein polyacrylic acid accounts for 20% of the mass of the rheological agent, the cellulose ether is one of industrial-use hydroxyethyl cellulose and hydroxy propyl methyl cellulose, or a mixture thereof; the magnesium oxide ceramic powder comprising a nanometer titanium oxide sintering aid is a mixture of a magnesium oxide powder and a nanometer titanium oxide powder;
2) soaking a polyurethane foam plastic template into the ceramic slurry, squeezing by a roller press the polyurethane foam plastic template to remove redundant slurry to make a biscuit, and drying the biscuit by heating it to 80° C.-120° C.;
3) putting the dried biscuit into a sintering furnace, elevating the temperature to 1400° C.-1500° C. and performing a high temperature sintering, cooling to the room temperature with the furnace to obtain the magnesium oxide-based ceramic foam filter.

2. The method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter according to claim 1 , wherein the nanometer alumina sol has a solid content of 20%-25%.

3. The method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter according to claim 1 , wherein the nanometer titanium oxide powder accounts for 1-2% by mass of the ceramic powder.

4. The method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter according to claim 1 , wherein the magnesium oxide powder is a fused magnesium oxide powder having a particle size in the order of 250-500 meshes.

5. The method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter according to claim 2 , wherein the nanometer titanium oxide powder has a particle size of 30-60 nm.

6. The method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter according to claim 1 , wherein a method of preparing the ceramic slurry is: with the ratio, adding a fused magnesium oxide powder into a ball milling tank; making a solution using the nanometer alumina sol, the rheological agent and deionized water and added therein the nanometer titanium oxide powder, ultrasonic treating the mixture for 30-60 minutes to have the nanometer titanium oxide powder fully dispersed in the solution; adding the mixture into the ball milling tank; with a ball to material ratio of 2:1, adding corundum balls and ball milling for 2-4 hours with a rotation speed of 60-120 rpm until a uniform mixture is achieved, and then vacuum degassing for 10-15 minutes at a negative pressure of 0.02 MPa-0.05 MPa.

7. The method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter according to claim 1 , wherein the specification of the polyurethane foam template is 10 PPI-20 PPI; the polyurethane foam template is first soaked in a water solution of 15% -20% NaOH at 40° C.-50° C. for surface etching for 40-60 minutes, washed by clean water and naturally dried, and then soaked into a water solution of 2% -4% wetting agent dodecylbenzene sulfonic acid and taken out and dried.

8. The method for preparing an MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter according to claim 1 , wherein in step 3), the sintering process is: the temperature is first elevated to 550° C. at a temperature rising rate of 30° C./h to have organic substances in the ceramic foam filter biscuit decomposed, gasified and discharged, then the temperature is elevated to 1100° C. at a temperature rising rate of 200° C./h, and finally, the temperature is elevated to 1400° C.-1600° C. at a temperature rising rate of 50° C./h and the temperature is maintained for 2-3 hours.

9. A MA-M 2 T spinel solid solution-reinforced magnesium oxide-based ceramic foam filter prepared according to the method of claim 1 .

Assignees

• Fengyang Aiersi Light Alloy Prec Molding Co Ltd
• Univ Shanghai Jiaotong
• Univ Nanjing Aeronautics & Astronautics
• Shanghai Jiaotong Univ College Of Materials

Inventors

• Ding Zhiguang
• Liu Zili
• Liu Xiqin
• Ye Bing
• Ding Wenjiang

Classifications

• C04B35/63404

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C04B2235/5436

  micrometer sized, i.e. from 1 to 100 micron · CPC title

• C04B38/0615

  the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles (C04B38/0022 takes precedence) · CPC title

• C04B35/053 Primary

  Fine ceramics · CPC title

• B01D39/2093 Primary

  Ceramic foam · CPC title