Composition, artificial nail composition, nail decoration material, artificial nail, stored container, image forming apparatus, and image forming method

Patent metadata

Field	Value
Publication number	US-11529302-B2
Application number	US-201916441844-A
Country	US
Kind code	B2
Filing date	Jun 14, 2019
Priority date	Jul 31, 2018
Publication date	Dec 20, 2022
Grant date	Dec 20, 2022

Abstract

Provided is a composition including: an acrylamide compound represented by general formula (1) below; urethane (meth)acrylate having a SI value of 3 or less in a skin sensitization test; and a polymerization initiator having a molecular weight of 800 or greater,

where in general formula (1), R 1 represents an alkyl group containing 1 through 6 carbon atoms, X represents an alkylene group containing 1 through 6 carbon atoms, and Y represents any one selected from the group consisting of general formula (2) below and general formula (3) below,

where in general formula (2), R 2 represents an alkyl group containing 1 through 10 carbon atoms, and * represents a binding site with X above,

where in general formula (3), R 2 represents an alkyl group containing 1 through 10 carbon atoms, and * represents a binding site with X above.

First claim

What is claimed is:

1. A composition, comprising:
49% to 86% by mass relative to the total amount of the composition of an acrylamide compound;
urethane (meth)acrylate; and
a polymerization initiator,
wherein the composition has a Simulation Index (SI) value of 3 or less in a skin sensitization test,
wherein the polymerization initiator is at least one selected from the group consisting of polyethylene glycol 200-di(β-4(4-(2-dimethylamino-2-benzyl)butanonylphenyl)piperazine), 1,3-di({α-[1-chloro-9-oxo-9H-thioxanthen-4-yl)oxy]acetyl poly[oxy(1-methylethylene)]}oxy)-2,2-bis({α-[1-chloro-9-oxo-9H-thioxanthen-4-yl)oxy]acetyl poly[oxy(1-methylethylene)]}oxymethyl)propane, a mixture of 1,3-di({α-4-(dimethylamino)benzoyl poly[oxy(1-methylethylene)]}oxy)-2,2-bis({α-4-(dimethylamino)benzoyl poly[oxy(1-methylethylene)]}oxymethyl)propane with {α-4-(dimethylamino)benzoyl poly(oxyethylene)-poly[oxy(1-methylethylene)]-poly(oxyethylene)}4-(dimethylamino) benzoate, polybutylene glycol bis(9-oxo-9H-thioxanthinyloxy) acetate, and oligomers of 2-hydroxy-1-(4-isopropenylphenyl)-2-methylpropane-1-one,
wherein the acrylamide compound is selected from acrylamides A1-1 to A1-5

2. The composition according to claim 1 ,
wherein the acrylamide compound is A1-1.

3. The composition according to claim 1 ,
wherein a content of the urethane (meth)acrylate is 5% by mass to 40% by mass based on the total amount of the composition.

4. The composition according to claim 1 ,
wherein a content of the polymerization initiator is 1% by mass to 20% by mass based on the total amount of the composition.

5. The composition according to claim 1 ,
wherein the composition is an active-energy-ray-curable composition.

6. A stored container, comprising:
the composition according to claim 1 ; and
a container,
wherein the composition is stored in the container.

7. A two-dimensional or three-dimensional image forming apparatus, comprising:
a storing part which comprises a composition;
an applying unit configured to apply the composition; and
a curing unit configured to cure the composition,
wherein the composition comprises a composition according to claim 1 .

8. A two-dimensional or three-dimensional image forming method, comprising:
applying a composition; and
curing the composition,
wherein the composition comprises a composition according to claim 1 .

9. An artificial nail composition, comprising the composition according to claim 1 .

10. A nail decoration material, comprising the artificial nail composition according to claim 9 .

11. An artificial nail, comprising a cured product of the artificial nail composition according to claim 9 .

12. The composition according to claim 1 , wherein the polymerization initiator is at least one selected from the group consisting of polyethylene glycol 200-di(β-4(4-(2-dimethylamino-2-benzyl)butanonylphenyl)piperazine), 1,3-di({α-[1-chloro-9-oxo-9H-thioxanthen-4-yl)oxy]acetyl poly[oxy(1-methylethylene)]}oxy)-2,2-bis({α-[1-chloro-9-oxo-9H-thioxanthen-4-yl)oxy]acetyl poly[oxy(1-methylethylene)]}oxymethyl)propane, a mixture of 1,3-di({α-4-(dimethylamino)benzoyl poly[oxy(1-methylethylene)]}oxy)-2,2-bis({α-4-(dimethylamino)benzoyl poly[oxy(1-methylethylene)]}oxymethyl)propane with {α-4-(dimethylamino)benzoyl poly(oxyethylene)-poly[oxy(1-methylethylene)]-poly(oxyethylene)}4-(dimethylamino) benzoate, and polybutylene glycol bis(9-oxo-9H-thioxanthinyloxy) acetate.

13. The composition according to claim 1 , wherein the acrylamide compound is selected from acrylamides A1-2 to A1-5.

14. The composition according to claim 1 , wherein the composition comprises 10-40% of the urethane (meth)acrylate, and 5-10% of the initiator.

15. The composition according to claim 1 , which comprises 3-20% of the initiator, and 5-40% of the urethane (meth)acrylate.

16. The composition according to claim 1 , which consists essentially of the acrylamide, urethane (meth)acrylate, and initiator.

17. The composition according to claim 2 , wherein the composition comprises 10-40% of the urethane (meth)acrylate, and 5-10% of the initiator.

18. The composition according to claim 17 , which consists essentially of the acrylamide, urethane (meth)acrylate, and initiator.

19. An artificial nail comprising a cured product of the composition according to claim 18 .

Assignees

• Ricoh Co Ltd

Inventors

• Suenaga Takenori
• Kobayashi Masahide
• Morita Mitsunobu
• Okada Takashi
• Noguchi Soh
• Yamaguchi Tatsuki

Classifications

• A61K8/87 Primary

  Polyurethanes · CPC title

• A45D31/00

  Artificial nails · CPC title

• A61K8/8158

  Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers · CPC title

• A61Q3/02

  Nail coatings · CPC title

• A45D44/00 Primary

  Other cosmetic or toiletry articles, e.g. for hairdressers' rooms · CPC title