Optical article

Patent metadata

Field	Value
Publication number	US-11526031-B2
Application number	US-201916727582-A
Country	US
Kind code	B2
Filing date	Dec 26, 2019
Priority date	Mar 30, 2018
Publication date	Dec 13, 2022
Grant date	Dec 13, 2022

Abstract

An optical article, such as a spectacle lens, includes, on a substrate, a photochromic layer containing a photochromic dye and a resin component, and a protective layer. The indentation hardness of the photochromic layer in the thickness direction is in a range from 0.1 to 10 mgf/μm2. The value defined by the indentation hardness of the protective layer in the thickness direction multiplied by the thickness of the protective layer is five or more times and nine thousand or less times the value defined by the indentation hardness of the photochromic layer in the thickness direction multiplied by the thickness of the photochromic layer.

First claim

The invention claimed is:

1. An optical article comprising:
a substrate;
a protective layer; and
at least a photochromic layer between the substrate and the protective layer, the photochromic layer containing a photochromic dye and a resin component,
wherein an indentation hardness of the photochromic layer in a thickness direction is in a range of from 0.1 to 10 mgf/μm2, and
wherein a result of multiplying an indentation hardness of the protective layer in a thickness direction and a thickness of the protective layer is at least five times, and is not more than nine thousand times, a result of multiplying the indentation hardness of the photochromic layer in the thickness direction and a thickness of the photochromic layer.

2. The optical article according to claim 1 , wherein the result of multiplying the indentation hardness of the photochromic layer in the thickness direction and the thickness of the photochromic layer is in a range of from 1 to 500 mgf/μm.

3. The optical article according to claim 1 , wherein the thickness of the photochromic layer is in a range of from 10 μm to 50 μm.

4. The optical article according to claim 3 , wherein the resin component in the photochromic layer includes an uncured curable component and a cured resin formed by curing an ultraviolet curable component.

5. The optical article according to claim 4 , wherein the curable component includes a high hardness monomer and a low hardness monomer.

6. The optical article according to claim 3 , wherein the optical article is a spectacle lens with power or a spectacle lens without power.

7. The optical article according to claim 1 , wherein the indentation hardness of the protective layer in the thickness direction is in a range of from 10 to 200 mgf/μm2.

8. The optical article according to claim 7 , wherein the resin component in the photochromic layer includes an uncured curable component and a cured resin formed by curing an ultraviolet curable component.

9. The optical article according to claim 8 , wherein the curable component includes a high hardness monomer and a low hardness monomer.

10. The optical article according to claim 7 , wherein the optical article is a spectacle lens with power or a spectacle lens without power.

11. The optical article according to claim 1 , wherein the thickness of the protective layer is in a range of from 3 μm to 45 μm.

12. The optical article according to claim 1 , wherein the result of multiplying the indentation hardness of the protective layer in the thickness direction and the thickness of the protective layer is in a range of from 30 to 9000 mgf/μm.

13. The optical article according to claim 1 , wherein the protective layer includes at least one of a polymer protective layer, a hard coat film, or an anti-reflection film.

14. The optical article according to claim 1 , wherein the resin component in the photochromic layer includes an uncured curable component and a cured resin formed by curing an ultraviolet curable component.

15. The optical article according to claim 14 , wherein the curable component includes a high hardness monomer and a low hardness monomer.

16. The optical article according to claim 1 , wherein the optical article is a spectacle lens with power or a spectacle lens without power.

17. The optical article according to claim 1 , wherein the optical article is a goggle lens.

18. The optical article according to claim 1 , wherein the optical article is a brim portion of a sun visor.

19. The optical article according to claim 1 , wherein the optical article is a shield member of a helmet.

20. A method of manufacturing an optical article, the method comprising:
forming, on a substrate, at least a photochromic layer, the photochromic layer containing a photochromic dye and a resin component; and
forming, on the at least the photochromic layer, a protective layer,
wherein an indentation hardness of the photochromic layer in a thickness direction is in a range of from 0.1 to 10 mgf/μm2, and
wherein a result of multiplying an indentation hardness of the protective layer in a thickness direction and a thickness of the protective layer is at least five times, and is not more than nine thousand times, a result of multiplying the indentation hardness of the photochromic layer in the thickness direction and a thickness of the photochromic layer.

Assignees

• Hoya Lens Thailand Ltd

Inventors

• Shimada Takuya
• Hamamoto Terufumi
• Katsukake Yusuke
• Yamashita Teruo
• Watanabe Tsuyoshi

Classifications

• G02B5/23

  Photochromic filters · CPC title

• G02C7/102 Primary

  Photochromic filters · CPC title

• G02B1/14

  Protective coatings, e.g. hard coatings · CPC title