High-concentration tin sulfonate aqueous solution and method for producing same

Patent metadata

Field	Value
Publication number	US-11525187-B2
Application number	US-202017433909-A
Country	US
Kind code	B2
Filing date	Feb 21, 2020
Priority date	Feb 28, 2019
Publication date	Dec 13, 2022
Grant date	Dec 13, 2022

Abstract

The present invention provides a high-concentration tin sulfonate aqueous solution, in which a divalent tin ion (Sn 2+ ) concentration is 360 g/L to 420 g/L, a tetravalent tin ion (Sn 4+ ) concentration is 10 g/L or less, a free methanesulfonic acid concentration is 40 g/L or less, a Hazen unit color number (APHA) is 240 or less, and a turbidity is 25 FTU or less. This aqueous solution is produced such that stannous oxide powder whose temperature is adjusted to a temperature of 10° C. or lower is added to an aqueous methanesulfonic acid solution having a concentration of 60% by mass to 90% by mass when the aqueous solution circulates in a state of being maintained at the temperature of 10° C. or lower, and the stannous oxide powder is dissolved.

First claim

What is claimed is:

1. A method for producing a high-concentration tin sulfonate aqueous solution the method comprising:
a step of diluting methanesulfonic acid with pure water to obtain an aqueous methanesulfonic acid solution having a concentration of 60% by mass to 90% by mass;
a step of causing the aqueous methanesulfonic acid solution to circulate in a state of being maintained at a temperature of 10° C. or lower;
a step of subjecting the aqueous methanesulfonic acid solution and a first stannous oxide powder to a neutralization reaction by adding the first stannous oxide powder whose temperature is adjusted to a temperature of 10° C. or lower to the circulating aqueous methanesulfonic acid solution and dissolving the first stannous oxide powder; and
a step of adding a second stannous oxide powder and pure water to adjust a concentration of Sn 2+ in a range of 360 g/L to 420 g/L.

2. The method for producing a high-concentration tin sulfonate aqueous solution according to claim 1 ,
wherein the circulating aqueous methanesulfonic acid solution is bubbled with nitrogen gas and/or degassed with a hollow fiber membrane degassing module.

3. The method for producing a high-concentration tin sulfonate aqueous solution according to claim 1 ,
wherein the stannous oxide powder contains impurities of a plurality of metals, and a total content of the plurality of kinds of metals is 30 mg/L or less in terms of metal.

4. The method for producing a high-concentration tin sulfonate aqueous solution according to claim 3 ,
wherein the plurality of metals includes sodium, potassium, lead, iron, nickel, copper, zinc, arsenic, antimony, aluminum, silver, bismuth, magnesium, calcium, titanium, chromium, manganese, cobalt, indium, tungsten, thallium, and cadmium.

5. The method for producing a high-concentration tin sulfonate aqueous solution according to claim 3 ,
wherein a content of each of the plurality of metals is 10 mg/L or less in terms of metal.

6. The method for producing a high-concentration tin sulfonate aqueous solution according to claim 1 ,
wherein the first stannous oxide powder contains chloride ions, and
a content of the chloride ions is 10 mg/L or less.

7. The method for producing a high-concentration tin sulfonate aqueous solution according to claim 1 , wherein the high-concentration tin sulfonate aqueous solution contains:
a divalent tin ion (Sn 2+ ) concentration is 360 g/L to 420 g/L,
a tetravalent tin ion (Sn 4+ ) concentration is 10 g/L or less,
a free methanesulfonic acid concentration is 40 g/L or less,
a Hazen unit color number (APHA) is 240 or less, and
a turbidity is 25 FTU or less.

Assignees

• Mitsubishi Materials Corp

Inventors

• Tatsumi Koji
• Mineo Kyohei
• Hirano Hirotaka

Classifications

• C25D21/12 Primary

  Process control or regulation (controlling or regulating in general G05) · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C25D3/30 Primary

  of tin · CPC title

• C25D21/14

  Controlled addition of electrolyte components · CPC title

• C25B1/01

  Products · CPC title