Bipolar CDI electrode, bipolar cdi electrode module and water treatment apparatus using the same

Patent metadata

Field	Value
Publication number	US-11524910-B2
Application number	US-201916355841-A
Country	US
Kind code	B2
Filing date	Mar 18, 2019
Priority date	Apr 4, 2018
Publication date	Dec 13, 2022
Grant date	Dec 13, 2022

Abstract

A bipolar capacitive deionization (CDI) electrode includes a circular current collector having a central hole and inner and outer circumferential surfaces; a nano-carbon coating layer formed on at least top and bottom surfaces of the circular current collector; and a hydrophobic polymer coating layer respectively disposed over the inner and outer circumferential surfaces of the current collector. Maintenance and management is facilitated by a bipolar CDI electrode module configured such that individual parts are formed to be removably attached. A water treatment apparatus including the bipolar CDI electrode module exhibits high water treatment efficiency, superior long-term stability, and easy maintenance and management, while solving terminal corrosion problems due to the formation of a hydrophobic polymer coating layer on the surface of an electrode terminal.

First claim

What is claimed is:

1. A bipolar capacitive deionization (CDI) electrode module comprising:
a cylindrical module housing having a central hole;
a first inlet cap and an outlet cap respectively provided at opposite ends of the module housing, each of the first inlet cap and the outlet cap having a central hole;
a second inlet cap and at least one bipolar CDI electrode sequentially disposed at predetermined intervals between the first inlet cap and the outlet cap;
a first terminal joined to the second inlet cap through the first inlet cap; and
a second terminal joined to the outlet cap,
wherein each of the first inlet cap, the outlet cap, the second inlet cap, and the at least one bipolar CDI electrode is circular.

2. The bipolar CDI electrode module of claim 1 , wherein the first terminal and the second terminal are made of a copper material.

3. The bipolar CDI electrode module of claim 1 , further comprising a hydrophobic polymer coating layer formed on a portion of an outer circumference of the first terminal.

4. The bipolar CDI electrode module of claim 3 , wherein the hydrophobic polymer coating layer includes at least one selected from the group consisting of polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyethylene terephthalate (PET), polypropylene (PP), and epoxy.

5. The bipolar CDI electrode module of claim 1 ,
wherein the second inlet cap includes:
a first cap housing, and
a first copper layer, a first current collector layer, and a first nano-carbon coating layer sequentially arranged on a surface of the first cap housing, the first copper layer and the first current collector layer being completely sealed by the first cap housing; and
wherein the outlet cap includes:
a second cap housing, and
a second copper layer, a second current collector layer, and a second nano-carbon coating layer sequentially arranged on a surface of the second cap housing, the second copper layer and the second current collector being completely sealed by the second cap housing.

6. The bipolar CDI electrode module of claim 5 , wherein the first terminal is formed to penetrate the second inlet cap up to the first copper layer and is configured to be removably attached to the first inlet cap and the second inlet cap.

7. The bipolar CDI electrode module of claim 1 , further comprising a hydrophobic polymer coating layer respectively disposed over inner and outer circumferential surfaces of each of the at least one bipolar CDI electrode.

8. The bipolar CDI electrode module of claim 7 , wherein the hydrophobic polymer coating layer includes at least one selected from the group consisting of polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyethylene terephthalate (PET), polypropylene (PP), and epoxy.

9. The bipolar CDI electrode module of claim 1 , further comprising a nano-carbon coating layer formed on at least top and bottom surfaces of each of the at least one bipolar CDI electrode.

10. The bipolar CDI electrode module of claim 1 , wherein one of the first terminal and the second terminal is formed as an anode and the other of the first terminal and the second terminal is formed as a cathode.

11. The bipolar CDI electrode module of claim 1 , wherein one surface of each of the at least one bipolar CDI electrode is formed as an anode and the other surface of the bipolar CDI electrode is formed as a cathode.

12. The bipolar CDI electrode module of claim 1 , wherein the at least one bipolar CDI electrode consists of a plurality of bipolar CDI electrodes.

13. The bipolar CDI electrode module of claim 1 , wherein the first inlet cap is configured to be removably attached to the module housing.

14. The bipolar CDI electrode module of claim 13 , wherein the second inlet cap includes an outer circumferential surface on which first screw threads are formed such that the second inlet cap can be removably attached to the module housing, and wherein the outer circumferential surface has a flow path groove.

15. The bipolar CDI electrode module of claim 1 , wherein the outlet cap has an outer circumferential surface on which second screw threads are formed such that the outlet cap can be removably attached to the module housing.

16. A water treatment apparatus comprising:
a raw water supply pipe;
a cartridge filter for filtering particulate matter contained in raw water supplied from the raw water supply pipe; and
a bipolar capacitive deionization (CDI) electrode module for desalinating a filtrate filtered through the cartridge filter, the bipolar CDI electrode module comprising:
a cylindrical module housing having a central hole;
a first inlet cap and an outlet cap respectively provided at opposite ends of the module housing, each of the first inlet cap and the outlet cap having a central hole;
a second inlet cap and at least one bipolar CDI electrode sequentially disposed at predetermined intervals between the first inlet cap and the outlet cap;
a first terminal joined to the second inlet cap through the first inlet cap; and
a second terminal joined to the outlet cap,
wherein each of the first inlet cap, the outlet cap, the second inlet cap, and the at least one bipolar CDI electrode is circular.

17. The water treatment apparatus of claim 16 , wherein the bipolar CDI electrode module consists of a plurality of bipolar CDI electrode modules disposed in an arrangement including at least one of a parallel connection of the bipolar CDI electrode modules and a series connection of the bipolar CDI electrode modules.

Assignees

• Doosan Enerbility Co Ltd

Inventors

• Choi Hyun Sung
• Cho Young Hyun
• You Jang Yong

Classifications

• Y02A20/131

  Reverse-osmosis · CPC title

• C02F2201/46

  Apparatus for electrochemical processes · CPC title

• C02F1/4691 Primary

  Capacitive deionisation · CPC title

• C02F2001/46128

  Bipolar electrodes · CPC title

• C02F1/001 Primary

  Processes for the treatment of water whereby the filtration technique is of importance (C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00) · CPC title