Resistivity value regulating device and resistivity value regulating method

Patent metadata

Field	Value
Publication number	US-11524267-B2
Application number	US-201716468049-A
Country	US
Kind code	B2
Filing date	Dec 15, 2017
Priority date	Dec 20, 2016
Publication date	Dec 13, 2022
Grant date	Dec 13, 2022

Abstract

A resistivity regulating apparatus includes: a gas dissolving device that causes a regulating gas to dissolve in a liquid targeted for resistivity regulation to generate a treated liquid in which the regulating gas is dissolved in the liquid, the regulating gas being used to regulate a resistivity of the liquid; and a buffer tank to which the treated liquid discharged from the gas dissolving device is fed.

First claim

The invention claimed is:

1. A resistivity regulating apparatus comprising:
a gas dissolving device that causes a regulating gas to dissolve in an ultrapure water targeted for resistivity regulation to generate a treated liquid in which the regulating gas is dissolved in the ultrapure water, the regulating gas being used to regulate a resistivity of the ultrapure water; and
a buffer tank to which the treated liquid discharged from the gas dissolving device is fed,
wherein the gas dissolving device includes:
a hollow fiber membrane module in which a hollow fiber membrane separates a liquid phase-side region fed with the ultrapure water from a gas phase-side region fed with the regulating gas and in which the regulating gas having passed through the hollow fiber membrane is dissolved in the ultrapure water in a saturated state to generate a regulating gas-saturated liquid;
a liquid feed pipe through which the ultrapure water is fed;
a module feed pipe that communicates with the liquid feed pipe through a diversion section at which the module feed pipe diverges from the liquid feed pipe so as to feed the ultrapure water to the hollow fiber membrane module;
a module discharge pipe through which the regulating gas-saturated liquid is discharged from the hollow fiber membrane module;
a bypass pipe that communicates with the liquid feed pipe through the diversion section and bypasses the hollow fiber membrane module; and
a liquid discharge pipe that communicates with the module discharge pipe and the bypass pipe through a merge section at which the module discharge pipe merges with the bypass pipe.

2. The resistivity regulating apparatus according to claim 1 , wherein the buffer tank is a cylindrical container.

3. The resistivity regulating apparatus according to claim 1 ,
wherein the buffer tank has a feed port for feeding the treated liquid and a discharge port for discharging the treated liquid, and
the feed port and the discharge port are directed along lines different from each other.

4. The resistivity regulating apparatus according to claim 3 ,
wherein the feed port and the discharge port are directed toward positions off a central axis extending in a vertical direction of the buffer tank.

5. The resistivity regulating apparatus according to claim 3 ,
wherein the feed port and the discharge port are disposed in different positions in a vertical direction of the buffer tank.

6. The resistivity regulating apparatus according to claim 5 ,
wherein the discharge port is disposed higher than the feed port.

7. The resistivity regulating apparatus according to claim 5 ,
wherein the feed port is formed in an upper part of the buffer tank.

8. The resistivity regulating apparatus according to claim 1 ,
wherein a capacity of the buffer tank is such that the buffer tank is filled with the treated liquid in 7 to 12 seconds.

9. The resistivity regulating apparatus according to claim 1 , further comprising:
a treated-liquid discharge pipe through which the treated liquid is discharged from the buffer tank;
a pump that is attached to the treated-liquid discharge pipe and delivers the treated liquid;
an on-off valve that is attached to the treated-liquid discharge pipe downstream of the pump and opens and closes the treated-liquid discharge pipe; and
a circulation pipe that diverges from the treated-liquid discharge pipe between the pump and the on-off valve and returns the treated liquid flowing through the treated-liquid discharge pipe to the buffer tank.

10. The resistivity regulating apparatus according to claim 9 ,
wherein the buffer tank has a circulation port through which the treated liquid is fed from the circulation pipe, and
the circulation port is formed in an upper part of the buffer tank.

11. A resistivity regulating apparatus comprising:
a gas dissolving device that causes a regulating gas to dissolve in an ultrapure water targeted for resistivity regulation to generate a treated liquid in which the regulating gas is dissolved in the ultrapure water, the regulating gas being used to regulate a resistivity of the ultrapure water;
a buffer tank to which the treated liquid discharged from the gas dissolving device is fed;
a first regulation pipe through which the ultrapure water is fed to the buffer tank;
a second regulation pipe through which a regulating gas-saturated liquid in which the regulating gas is dissolved in the ultrapure water in a saturated state is fed to the buffer tank; and
a resistivity sensor that measures a resistivity of the treated liquid in the buffer tank;
wherein the gas dissolving device includes:
a hollow fiber membrane module in which a hollow fiber membrane separates a liquid phase-side region fed with the ultrapure water from a gas phase-side region fed with the regulating gas and in which the regulating gas having passed through the hollow fiber membrane is dissolved in the ultrapure water in a saturated state to generate the regulating gas-saturated liquid;
a liquid feed pipe through which the ultrapure water is fed;
a module feed pipe that communicates with the liquid feed pipe through a diversion section at which the module feed pipe diverges from the liquid feed pipe so as to feed the ultrapure water to the hollow fiber membrane module;
a module discharge pipe through which the regulating gas-saturated liquid is discharged from the hollow fiber membrane module;
a bypass pipe that communicates with the liquid feed pipe through the diversion section and bypasses the hollow fiber membrane module; and
a liquid discharge pipe that communicates with the module discharge pipe and the bypass pipe through a merge section at which the module discharge pipe merges with the bypass pipe.

12. The resistivity regulating apparatus according to claim 11 , wherein the first regulation pipe is connected to the liquid feed pipe or the bypass pipe, and the second regulation pipe is connected to the module discharge pipe.

13. A resistivity regulating method using the resistivity regulating apparatus of claim 1 , comprising:
causing a regulating gas to dissolve in a liquid targeted for resistivity regulation to generate a treated liquid in which the regulating gas is dissolved in the liquid, the regulating gas being used to regulate a resistivity of the liquid; and
feeding the generated treated liquid to a buffer tank.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Anzai Daijirou
• Hada Naoki
• Oi Kazumi

Classifications

• B01F35/80

  Forming a predetermined ratio of the substances to be mixed (controlling ratio of two or more flows of fluid or fluent material G05D11/02) · CPC title

• B01F25/52

  with a rotary stirrer in the recirculation tube · CPC title

• C02F2301/043

  Treatment of partial or bypass streams · CPC title

• B01F21/10 Primary

  using driven stirrers · CPC title

• B01F21/00 Primary

  Dissolving (separating by dissolving B01D; dissolving to effect cooling F25D5/00) · CPC title