All-solid-state battery production method and all-solid-state battery

Patent metadata

Field	Value
Publication number	US-11522215-B2
Application number	US-202016823804-A
Country	US
Kind code	B2
Filing date	Mar 19, 2020
Priority date	Mar 22, 2019
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

To provide a method for production of an all-solid-state battery in which cracking of the ends of the electrodes can be suppressed even if a negative electrode active material layer including lithium-titanium oxide is roll-pressed, provided is a method for the production of an all-solid-state battery, including roll-pressing to consolidate a negative electrode active material layer; wherein the all-solid-state battery has a structure including a laminate of a positive electrode current collector layer, a positive electrode active material layer, a solid electrolyte layer, the negative electrode active material layer, and a negative electrode current collector layer in this order, the negative electrode active material layer includes a lithium-titanium oxide as a negative electrode active material, and prior to the roll-pressing, a stress relaxation rate of the negative electrode active material layer is 32.5% or more.

First claim

The invention claimed is:

1. A production method of an all-solid-state battery, comprising roll-pressing to consolidate a negative electrode active material layer; wherein
the all-solid-state battery has a structure comprising a positive electrode current collector layer, a positive electrode active material layer, a solid electrolyte layer, the negative electrode active material layer, and a negative electrode current collector layer in this order;
the negative electrode active material layer includes a lithium-titanium oxide as a negative electrode active material;
the negative electrode active material layer further includes a solid electrolyte and a conductive aid, wherein the quantity of the conductive aid included in the negative electrode active material layer relative to the quantity of the lithium-titanium oxide is 2.4% by mass or more and 6.0% by mass or less, and the conductive aid comprises vapor grown carbon fiber;
prior to the roll-pressing, a stress relaxation rate of the negative electrode active material layer is 32.5% or more; and
the roll-pressing is performed on a laminate, the laminate including the positive electrode active material layer, the solid electrolyte layer, the negative electrode active material layer, the negative electrode current collector layer, the negative electrode active material layer, the solid electrolyte layer, and the positive electrode active material layer in this order.

2. The production method of claim 1 , wherein the solid electrolyte included in the negative electrode active material comprises a sulfide solid electrolyte.

3. A production method of an all-solid-state battery, comprising roll-pressing to consolidate a negative electrode active material layer; wherein
the all-solid-state battery has a structure comprising a positive electrode current collector layer, a positive electrode active material layer, a solid electrolyte layer, the negative electrode active material layer, and a negative electrode current collector layer in this order;
the negative electrode active material layer includes a lithium-titanium oxide as a negative electrode active material;
the negative electrode active material layer further includes a solid electrolyte and a conductive aid, wherein the quantity of the conductive aid included in the negative electrode active material layer relative to the quantity of the lithium-titanium oxide is 2.4% by mass or more and 6.0% by mass or less, and the conductive aid comprises vapor grown carbon fiber (VGCF);
prior to the roll-pressing, a stress relaxation rate of ends of the negative electrode active material layer in a direction extending perpendicular to the lamination direction and along the direction of transfer by the roll-pressing is 32.5% or more; and
the roll-pressing is performed on a laminate, the laminate including the positive electrode active material layer, the solid electrolyte layer, the negative electrode active material layer, the negative electrode current collector layer, the negative electrode active material layer, the solid electrolyte layer, and the positive electrode active material layer in this order.

4. The production method according to claim 3 , wherein the negative electrode active material layer includes VGCF in only ends thereof.

Assignees

• Toyota Motor Co Ltd

Inventors

• Nakamura Kota
• Asadachi Hideki
• Ose Norihiro
• Enomoto Yoshihide
• Suzuki Tomoya

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title