Positive electrode for rechargeable lithium battery, preparing method thereof, and rechargeable lithium battery comprising positive electrode

Patent metadata

Field	Value
Publication number	US-11522189-B2
Application number	US-202017102412-A
Country	US
Kind code	B2
Filing date	Nov 23, 2020
Priority date	Dec 4, 2017
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

A positive electrode for a rechargeable lithium battery includes a positive active material for a rechargeable lithium battery that includes a first positive active material including a secondary particle including at least two agglomerated primary particles, where at least a portion of the primary particles has a radial arrangement structure, and a second positive active material having a monolith structure, wherein the first and second positive active materials each include a nickel-based positive active material, and an X-ray diffraction (XRD) peak intensity ratio (I(003)/I(104)) of the positive electrode is greater than or equal to about 3. Further embodiments provide a method of manufacturing the positive electrode for rechargeable lithium battery, and a rechargeable lithium battery including the same.

First claim

What is claimed is:

1. A positive electrode for a rechargeable lithium battery, comprising:
a positive active material comprising:
a first positive active material comprising a secondary particle comprising at least two agglomerated primary particles, where at least one part of the primary particles has a radial arrangement structure; and
a second positive active material having a monolith structure,

wherein the first positive active material and the second positive active material each comprise a nickel-based positive active material, and
an X-ray diffraction (XRD) peak intensity ratio (I(003)/I(104)) of the positive electrode is greater than or equal to about 3.

2. The positive electrode of claim 1 , wherein the X-ray diffraction (XRD) peak intensity ratio (I(003)/I(104)) of the positive electrode is greater than or equal to about 3.2.

3. The positive electrode of claim 1 , wherein the positive electrode for the rechargeable lithium battery has a mixture density of greater than or equal to about 3.4 g/cc.

4. The positive electrode of claim 1 , wherein the second positive active material is comprised in an amount of about 10 wt % to about 50 wt % based on a total weight of the positive active material.

5. The positive electrode of claim 1 , wherein, in the first positive active material,
the secondary particle comprises a radial arrangement structure, or
the secondary particle comprises an internal part comprising an irregular porous structure and an external part comprising the radial arrangement structure.

6. The positive electrode of claim 1 , wherein, in the first positive active material,
the primary particles have a plate shape, and
a long-axis of the at least one part of the primary particles is arranged in a radial direction.

7. The positive electrode of claim 1 , wherein, in the first positive active material, an average length of the primary particles is about 0.01 μm to about 5 μm.

8. The positive electrode of claim 1 , wherein an average particle diameter of the second positive active material is about 0.05 μm to about 10 μm.

9. The positive electrode of claim 1 , wherein an average particle diameter of the second positive active material is about 3 μm to about 6 μm.

10. The positive electrode of claim 1 , wherein a residual lithium concentration in the positive active material is less than or equal to about 1000 ppm.

11. The positive electrode of claim 1 , wherein the first positive active material is represented by Chemical Formula 1:
Li a (Ni 1-x-y-z Co x Mn y M z )O 2 , and  Chemical Formula 1

wherein, in Chemical Formula 1, M is an element selected from boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), chromium (Cr), iron (Fe), copper (Cu), zirconium (Zr), and aluminum (Al), and
0.95≤a≤1.3, x≤(1−x−y−z), y≤(1−x−y−z), 0<x<1, 0≤y<1, and 0≤z<1.

12. The positive electrode of claim 1 , wherein the second positive active material is represented by Chemical Formula 1:
Li a (Ni 1-x-y-z Co x Mn y M z )O 2 , and  Chemical Formula 1

wherein, in Chemical Formula 1, M is an element selected from boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), chromium (Cr), iron (Fe), copper (Cu), zirconium (Zr), and aluminum (Al), and
0.95≤a≤1.3, x≤(1−x−y−z), y≤(1−x−y−z), 0<x<1, 0≤y<1, and 0≤z<1.

13. A rechargeable lithium battery, comprising:
the positive electrode of claim 1 ;
a negative electrode; and
an electrolyte between the positive electrode and the negative electrode.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Ahn Kiyong
• Kim Jongmin

Classifications

• C01P2006/40

  Electric properties · CPC title

• C01P2002/74

  by peak-intensities or a ratio thereof only · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• H01M4/043

  involving compressing or compaction · CPC title

• C01P2006/11

  Powder tap density · CPC title