Process for preparing carbon fibers

Patent metadata

Field	Value
Publication number	US-11519103-B2
Application number	US-201816761453-A
Country	US
Kind code	B2
Filing date	Nov 2, 2018
Priority date	Nov 4, 2017
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

The present disclosure relates to a process for preparing carbon fibers. The process involves blending a carbon nano-material with a carbon material to obtain a homogenous blend, heating the homogenous blend to obtain mesophase pitch having particles with reduced mesophase sphere size followed by spinning the mesophase pitch to obtain the pitch fibers. The pitch fibers are then carbonized to obtain the carbon fibers. The carbon fibers prepared by the process of the present disclosure have improved tensile properties as compared to the conventional pitch based carbon fibers.

First claim

What is claimed is:

1. A process for preparing carbon fibers, said process comprising the following steps:
blending a carbon nanomaterial and a carbon material to obtain a homogenous blend wherein said carbon nanomaterial is dispersed in a fluid medium prior to being blended with said carbon material;
heating said homogenous blend at a first pre-determined temperature under inert atmosphere to obtain a mesophase pitch having particles with reduced mesophase sphere size;
spinning said mesophase pitch to obtain pitch fibers; and
carbonizing said pitch fibers at a second pre-determined temperature under inert atmosphere to obtain carbon fibers.

2. The process as claimed in claim 1 , wherein said carbon material is selected from clarified slurry oil, coal tar pitch, naptha cracked oil and isotropic pitch.

3. The process as claimed in claim 1 , wherein said carbon nanomaterial is selected from the group consisting of carbon nanotubes, graphene and crumpled graphene.

4. The process as claimed in claim 1 , wherein the weight ratio of said carbon nanomaterial to said carbon material is in the range of 0.001 to 0.05.

5. The process as claimed in claim 1 , wherein said fluid medium is selected from the group consisting of 1,2-dichlorobenzene, N-methyl-pyrrolidone, and dimethylformamide.

6. The process as claimed in claim 1 , wherein said carbon nanomaterial is dispersed in said fluid medium using a surfactant to aid dispersion of the carbon nanomaterial.

7. The process as claimed in claim 6 , wherein said surfactant is selected from sodium dodecyl benzene sulfonate, and polyvinylpyrrolidone.

8. The process as claimed in claim 6 , wherein the weight ratio of said carbon nanomaterial to said surfactant is in the range of 1:5 to 1:15.

9. The process as claimed in claim 1 , wherein first pre-determined temperature is in the range of 350° C. to 450° C., and said second pre-determined temperature is in the range of 900° C. to 1500° C.

10. The process as claimed in claim 1 , wherein the amount of said carbon nanomaterial in said carbon fiber is in the range of 0.1 wt % to 5 wt %.

11. The process as claimed in claim 1 , wherein said blending is carried out by a method selected from ultra-sonication and high shear mixing.

Assignees

• Reliance Industries Ltd

Inventors

• Patil Swanand Dilip
• KHARE Rupesh Arun
• Nandigam Padmavathi
• Khanvilkar Asmita Ashok
• Veedu Sreekumar Thaliyil

Classifications

• D01D1/02

  Preparation of spinning solutions · CPC title

• D01F9/155

  from petroleum pitch · CPC title

• C10C3/002

  by thermal means · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title

• D01F9/15 Primary

  from coal pitch · CPC title