Powder and granule, process for making such powder and granule, and use thereof

Patent metadata

Field	Value
Publication number	US-11518965-B2
Application number	US-202016857791-A
Country	US
Kind code	B2
Filing date	Apr 24, 2020
Priority date	Feb 13, 2014
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

The present invention is directed towards a process for making a powder or granule containing
(A) at least one chelating agent selected from methyl glycine diacetic acid (MGDA) and glutamic acid diacetate (GLDA) and iminodisuccinic acid (IDS) and their respective alkali metal salts, (B) at least one homo- or copolymer of (meth)acrylic acid, partially or fully neutralized with alkali,

said process comprising the steps of
(a) mixing the at least one chelating agent (A) and the at least one homo- or copolymer (B) in the presence of water, (b) removing most of said water by spray-drying or spray granulation using a gas with an inlet temperature of at least 125° C.

First claim

The invention claimed is:

1. A process for making a powder or granule comprising
(A) in the range of from 80 to 99% by weight of methyl glycine diacetic acid (MGDA) or an alkali metal salt thereof,
(B) in the range of from 1 to 20% by weight of a polymer selected from (i) polyacrylic acid, (ii) copolymers of (meth)acrylic acid and a comonomer having at least one sulfonic acid group, and (iii) salts thereof, wherein the polymer has an average molecular weight Mw in the range of from 1,200 to 30,000 g/mol, determined by gel permeation chromatography and referring to the respective free acid,
percentages referring to the solids content of said powder or granule, the process comprising;
(a) mixing (A) and (B) in the presence of water thereby forming a solution; and
(b) removing most of said water from the solution by spray-drying or spray granulation using a gas with an inlet temperature of at least 125° C. to form the powder or granule.

2. The process according to claim 1 , wherein (B) is a per-sodium salt of polyacrylic acid.

3. The process of claim 1 , wherein the water is removed from the solution by spray-drying to form the powder in which (A) and (B) are in molecularly disperse form.

4. The process of claim 3 , wherein all f the particles of the powder contain both (A) and (B).

5. The process of claim 1 , wherein the inlet temperature during the spray-drying or spray granulation is from 150° C. to 220° C.

6. The process of claim 1 , wherein (A) is a trisodium salt of methylglycine diacetic acid, and (B) is a polyacrylic acid that is at least 25% neutralized and has a Mw of 4,000-30,000 g/mol, determined by GPC and referring to the free acid.

7. The process of claim 1 , wherein the water is removed from the solution by spray granulation to form a fluidized bed of particles.

Assignees

• Basf Se

Inventors

• Hartmann Markus
• Reinoso Garcia Marta
• Mueller Michael Klemens
• Boehn Roland
• Biel Markus Christian

Classifications

• C11D11/02

  Preparation in the form of powder by spray drying · CPC title

• C11D17/06

  Powder; Flakes; Free-flowing mixtures; Sheets · CPC title

• C11D3/33 Primary

  Amino carboxylic acids · CPC title

• C11D3/3761

  in solid compositions · CPC title

• C11D3/3942 Primary

  Inorganic per-compounds (C11D3/3902 takes precedence) · CPC title