Corrosion protection for glassware in a dishwasher

Patent metadata

Field	Value
Publication number	US-11518959-B2
Application number	US-202017074064-A
Country	US
Kind code	B2
Filing date	Oct 19, 2020
Priority date	Apr 19, 2018
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

A gel which is based on polysaccharide and which includes glass protection additives selected from zinc salts, polyvinyl amide, polyvinyl amine, or combinations thereof. The invention additionally relates to the use of the gel for the corrosion protection of glassware during cleaning and/or rinsing processes, in particular in a dishwasher, and to a method for preventing the corrosion of glassware during cleaning and/or rinsing processes, in particular in a dishwasher.

First claim

What is claimed is:

1. A gel suitable for the corrosion protection of glassware comprising of
at least one polysaccharide polymer;
at least one glass protection additive selected from zinc salts, polyvinylamine, polyvinylamide or mixtures thereof;
optionally at least one solvent; and
optionally at least one additive; wherein the at least one polysaccharide polymer is a cationic polysaccharide polymer.

2. The gel according to claim 1 , wherein
(a) the at least one polysaccharide polymer is contained in 0.1 wt. % to 3 wt. % based on the total weight of the gel; and/or
(b) the at least one glass protection additive is contained in 0.1 to 15.0 wt. % based on the total weight of the gel.

3. The gel according to claim 1 , wherein the at least one glass protection additive is selected from zinc chloride, zinc acetate, zinc ricinoleate, polyvinylamine, polyvinylamide and mixtures thereof being contained.

4. The gel according to claim 1 , wherein the at least one zinc salt is contained in 0.5 to 15.0 wt. % based on the total weight of the gel, and/or in that the polyvinylamine is contained in 0.1 to 10 wt. % based on the total weight of the gel.

5. The gel according to claim 1 , wherein
(a) the at least one solvent is an organic solvent; and/or
(b) the at least one solvent is contained in 20.0 to 90.0 wt. % based on the total weight of the gel.

6. The gel according to claim 1 , wherein the gel further contains at least one additive selected from alkali and alkaline-earth metal salts.

7. The gel according to claim 1 , wherein the at least one additive is contained in an amount of 0.1 to 40 wt. % in each case based on the total weight of the gel.

8. A method for inhibiting the corrosion of glassware, comprising the steps of:
i) bringing the glassware into contact with the gel according to claim 1 , wherein the gel has been dissolved in water;
ii) optionally carrying out a cleaning or rinsing step.

9. The gel according to claim 1 , wherein the at least one polysaccharide polymer is selected from the group of cationic cellulose polymers and/or cationic guar derivatives.

10. The gel according to claim 2 , wherein
(a) the at least one polysaccharide polymer is contained in 0.2 wt. % to 1.5 wt. % based on the total weight of the gel; and/or
(b) the at least one glass protection additive is contained in 2.0 to 10.0 wt. % based on the total weight of the gel.

11. The gel according to claim 3 , wherein the at least one glass protection additive is polyvinylamine and at least one zinc salt selected from zinc chloride, zinc acetate and zinc ricinoleate being contained.

12. The gel according to claim 4 , wherein zinc chloride, zinc acetate or zinc ricinoleate is contained in 2 to 10 wt. % based on the total weight of the gel, and/or in that the polyvinylamine is contained in 1 to 5 wt. % based on the total weight of the gel.

13. The gel according to claim 5 , wherein the at least one solvent is a mixture of a polar and a non-polar solvent.

14. The gel according to claim 5 , wherein the at least one solvent is an organic solvent having at least one hydroxy group being contained and/or a non-polar organic solvent.

15. The gel according to claim 5 , wherein the at least one organic solvent is contained in 50.0 to 85 wt. % based on the total weight of the gel.

16. The gel according to claim 5 , wherein the at least one organic solvent is contained in 70.0 to 80.0 wt. % based on the total weight of the gel.

17. The gel according to claim 6 , wherein the gel further contains at least one additive selected from sodium sulfate, fillers, builders, corrosion inhibitors, enzymes, foam inhibitors, surfactants, bitterns, sequestering agents, electrolytes, fragrances, antimicrobial active ingredients and dyes.

18. The gel according to claim 7 , wherein the at least one additive is contained in an amount of 5 to 30 wt. % in each case based on the total weight of the gel.

19. The gel according to claim 7 , wherein the at least one additive is contained in an amount of 15 to 25 wt. % in each case based on the total weight of the gel.

20. The gel according to claim 1 , further comprising of at least one solvent.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Doering Thomas
• Weber Thomas

Classifications

• C11D17/042

  Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions · CPC title

• C11D3/2068

  Ethers · CPC title

• C11D3/0073 Primary

  Anticorrosion compositions · CPC title

• C11D17/003

  Colloidal solutions, e.g. gels; Thixotropic solutions or pastes · CPC title

• C11D3/43

  Solvents · CPC title