Polyalkyl(meth)acrylates for improving fuel economy, dispersancy and deposits performance

Patent metadata

Field	Value
Publication number	US-11518955-B2
Application number	US-202017439951-A
Country	US
Kind code	B2
Filing date	Mar 18, 2020
Priority date	Mar 20, 2019
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

Polyalkyl(meth)acrylates contain specified amounts of long-chain alkyl (meth)acrylates and functional monomers. Lubricant compositions can contain such polyalkyl(meth)acrylates, and the polyalkyl(meth)acrylates can be used as viscosity index (VI) improvers with good fuel economy as well as soot-dispersant function. The polyalkyl(meth)acrylates can provide equal or even unproved deposits in lubricant compositions, especially in engine oil (EO) compositions.

First claim

The invention claimed is:

1. A polyalkyl(meth)acrylate polymer, comprising the following monomers:
(a) 10to 25% by weight of the esters of (meth)acrylic acid and a hydroxylated hydrogenated polybutadiene;
(b) 45% to 60% by weight of the C 1-4 alkyl (meth)acrylates;
(c) 10% to 15% by weight of the styrene;
(d) 15% to 30% by weight of the C 10-30 alkyl (meth)acrylates; and
(e) 3% to 7% by weight of the N-containing monomers selected from the group consisting of N,N-dimethylaminoethvl methacrylate (DMAEMA), N-(3-(dimethylamino)propyl)methacrylamide (DMAPMAm), and N-vinylpyrrolidinone (NVP),
wherein the weight-average molecular weight of the polyalkyl(meth)acrylate polymer is in the range of 200,000 to 700,000 g/mol.

2. The polyalkyl (meth)acrylate polymer according to claim 1 , wherein the number-average molecular weight is in the range of 20,000 to 200,000 g/mol.

3. A process for improving deposit formation of a lubricating oil composition, the process comprising:
adding the polyalkyl(meth)acrylate polymer according to claim 1 to the lubricating oil composition,
wherein the polyalkyl(meth)acrylate polymer comprises N,N-dimethylaminoethyl methacrylate (DMAEMA) as the N-containing monomers.

4. An additive composition, comprising:
(A) 60 to 80% by weight of a base oil, and
(B) 20 to 40% by weight of the polyalkyl(meth)acrylate polymer of claims 1 .

5. A lubricating oil composition, comprising:
(A) 80 to 99.5% by weight of a base oil;
(B) 0.5 to 5% by weight of the polyalkyl(meth)acrylate comb polymer of claim 1 ; and
(C) 0 to 15% by weight of one or more further additives.

6. The lubricating oil composition according to claim 5 , comprising between 3% and 5% by weight of the polyalkyl(meth)acrylate comb polymer,
wherein the lubricating oil composition does not comprise a DI package.

7. The lubricating oil composition according to claim 5 , comprising between 1% and 2% by weight of the polyalkyl(meth)acrylate comb polymer,
wherein the lubricating oil composition further comprises a DI package.

8. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the C 10-30 alkyl (meth)acrylates are C 12-14 alkyl methacrylates.

9. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the N-containing mono er is DMAEMA.

10. The polyalkyl(meth)acrylate polymer according to claim 1 , comprising the following monomers:
(a) 10 to 20% by weight of the esters of (meth)acrylic acid and a hydroxylated hydrogenated polybutadiene;
(b) 45% to 55% by weight of the C 1-4 alkyl (meth)acrylates;
(c) 10% to 15% by weight of the styrene;
(d) 15% to 25% by weight of C 12-14 alkyl methacrylates; and
(e) 3% to 7% by weight of N,N-dimethylaminoethyl methacrylate (DMAEMA).

11. The polyalkyl(meth)acrylate polymer according to claim 1 , consisting of the following monomers:
(a) 10 to 25% by weight of the esters of (meth)acrylic acid and a hydroxy lated hydrogenated polybutadiene;
(b) 45% to 60% by weight of the C 1-4 alkyl (meth)acrylates;
(c) 10% to 15% by weight of the styrene;
(d) 15% to 30% by weight of the C 10-30 alkyl (meth)acrylates; and
(e) 3% to 7% by weight of the N-containing monomers selected from the group consisting of N,N-dimethylaminoethyl methacrylate (DMAEMA), N-(3-(dimethylamino)propyl)methacrylamide (DMAPMAm), and N-vinyl pyrrolidinone (NVP).

12. A polyalkyl(meth)acrylate polymer, comprising the following monomers:
(a) 10 to 25% by weight of the esters of (meth)acrylic acid and a hydroxylated hydrogenated polybutadiene;
(b) 30% to 45% by weight of the C 1-4 alkyl (meth)acrylates;
(c) 19% to 30% by weight of the styrene;
(d) 15% to 30% by weight of the C 10-30 alkyl (meth)acrylates; and
(e) 3% to 7% by weight of the N-containing monomers selected from the group consisting of N,N-dimethylaminoethyl methacrylate (DMAEMA), N-(3-(dimethylamino)propyl)methacrylamide (DMAPMAm), and N-vinylpyrrolidinone (NVP),
wherein the weight-average molecular weight of the polvalkyl(meth)acrylate polymer is in the range of 200,000 to 700,000 g/mol.

13. A process for improving deposit formation of a lubricating oil composition, the process comprising:
adding the polyalkyl(meth)acrylate polymer according to claim 12 to the lubricating oil composition, wherein the polyalkyl(meth)acrylate polymer comprises
N,N-dimethylaminoethyl methacrylate (DMAEMA) as the N-containing monomers.

14. An additive composition, comprising:
(A) 60 to 80% by weight of a base oil, and
(B) 20 to 40% by weight of the polyalkyl(meth)acrylate polymer of claim 12 .

15. A lubricating oil composition, comprising:
(A) 80 to 99.5% by weight of a base oil;
(B) 0.5 to 5% by weight of the polyalkyl(meth)acrylate polymer of claim 12 ; and
(C) 0 to 15% by weight of one or more further additives.

16. The polyalkyl(meth)acrylate polymer according to claim 12 , wherein the number-average molecular weight is in the range of 20,000 to 200,000 g/mol.

17. The polyalkyl(meth)acrylate polymer according to claim 12 , wherein the C 10-30 alkyl (meth)acrylates are C 12-14 alkyl methacrylates.

18. The polyalkyl(meth)acrylate polymer according to claim 12 , wherein the N-containing monomer is DMAEMA.

19. The polyalkyl(meth)acrylate polymer according to claim 12 , consisting of the following monomers:
(a) 10 to 25% by weight of the esters of acrylic acid and a hydroxylated hydrogenated polybutadiene;
(b) 30% to 45% by weight of the C 1-4 alkyl (meth)acrylates;
(c) 19% to 30% by weight of the styrene;
(d) 15% to 30% by weight of the C 10-30 alkyl (meth)acrylates; and
(e) 3% to 7% by weight of the N-containing monomers selected from the group consisting of N,N-dimethylaminoethyl methacrylate (DMAEMA), N-(3-(dimethylamino)propyl)methacrylamide (DMAPMAm), and N-vinylpyrrolidinone (NVP).

Assignees

• Evonik Operations Gmbh

Inventors

• Schoeller Katrin
• Ziegler Fabian
• Eisenberg Boris
• Shakhvorostov Dmitriy
• Schimossek Klaus

Classifications

• C10M145/14 Primary

  Acrylate; Methacrylate · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10M2209/084

  Acrylate; Methacrylate · CPC title

• C08F236/10

  with vinyl-aromatic monomers · CPC title