Pyrolysis to determine hydrocarbon expulsion efficiency of hydrocarbon source rock

Patent metadata

Field	Value
Publication number	US-11518941-B2
Application number	US-202016841561-A
Country	US
Kind code	B2
Filing date	Apr 6, 2020
Priority date	May 20, 2015
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

An open system pyrolysis of a first hydrocarbon source rock sample obtained from a natural system is performed within a pyrolysis chamber by maintaining the pyrolysis chamber at a substantially constant temperature. Hydrocarbons are recovered from the pyrolysis chamber released by the first hydrocarbon source rock sample. A thermo-vaporization is performed within the pyrolysis chamber on the pyrolyzed sample at a substantially constant temperature. A first hydrocarbon expulsion efficiency of hydrocarbon source rock is determined. A second hydrocarbon rock sample is ground to a grain size less than or equal to or less than 250 micrometers. A second pyrolysis is performed on the ground hydrocarbon source rock sample by maintaining the chamber at a substantially constant temperature. A second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system is determined. The first hydrocarbon expulsion efficiency is verified using the second hydrocarbon expulsion efficiency.

First claim

The invention claimed is:

1. A system comprising:
an integrated sample-crusher and thermo-vaporization chamber configured to retain a hydrocarbon rock sample;
a heating element configured to heat the integrated sample-crusher and thermo-vaporization chamber;
a sensor configured to detect hydrocarbons released within the integrated sample-crusher and thermo-vaporization chamber;
a controller configured to control the heating element to a set temperature for a set amount of time, the controller configured to control the integrated sample-crusher, the controller configured to:
heat the integrated sample-crusher and thermo-vaporization chamber, by the heating element, to a temperature of substantially 375° C.;
maintain, within the integrated sample-crusher and thermo-vaporization chamber, a constant temperature of substantially 375° C., by the heating element, while the integrated sample-crusher and thermo-vaporization chamber is in use;
determine a first hydrocarbon expulsion efficiency of hydrocarbon source rock in a natural system based on recovered hydrocarbons released by a first hydrocarbon source rock sample in response to the maintained temperature, the amount of recovered hydrocarbons determined by the sensor and interpreted by the controller;
grind a second hydrocarbon rock sample of a pre-defined mass resulting in a ground hydrocarbon source rock sample having a grain size less than or equal to 250 micrometers, wherein the grinding is performed within the integrated sample-crusher and thermo-vaporization chamber;
re-heat the integrated sample-crusher and thermo-vaporization chamber to a temperature of substantially 375° C.;
maintain, within the integrated sample-crusher and thermo-vaporization chamber, a constant temperature of substantially 375° C. while the integrated sample-crusher and thermo-vaporization chamber contains the second hydrocarbon rock sample in the ground state;
determine a second hydrocarbon expulsion efficiency of the hydrocarbon source rock in the natural system based maintaining the temperature on the second hydrocarbon source rock sample, the amount of recovered hydrocarbons determined by the sensor and interpreted by the controller; and
verify the first hydrocarbon expulsion efficiency using the second hydrocarbon expulsion efficiency.

2. The system of claim 1 , wherein the integrated sample-crusher and thermo-vaporization chamber comprises electrically driven grinding blades.

3. The system of claim 1 , wherein the integrated sample-crusher and thermo-vaporization chamber is configured to contain a sample size of at least 100 grams.

4. The system of claim 1 , wherein the integrated sample-crusher and thermo-vaporization chamber has a volume of at least 1 liter.

Assignees

• Saudi Arabian Oil Co

Inventors

• Inan Sedat

Classifications

• G01N30/7206

  interfaced to gas chromatograph (interfaces in general for introducing or extracting samples to be analysed with specially adapted mass spectrometer, see H01J49/04) · CPC title

• C10G9/18

  Apparatus · CPC title

• G01N2030/125

  pyrolising · CPC title

• G01N2001/4033

  sample concentrated on a cold spot, e.g. condensation or distillation · CPC title

• G01N2030/123

  using more than one trap · CPC title