Thermoplastic resin composition and light diffusion sheet produced therefrom

Patent metadata

Field	Value
Publication number	US-11518879-B2
Application number	US-202016882912-A
Country	US
Kind code	B2
Filing date	May 26, 2020
Priority date	May 31, 2019
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

A thermoplastic resin composition comprises about 100 parts by weight of a polycarbonate resin; and about 0.5 parts by weight to about 3 parts by weight of polystyrene-poly(methyl methacrylate) copolymer particles, wherein the polystyrene-poly(methyl methacrylate) copolymer particles include about 41 wt % to about 59 wt % of polystyrene and about 41 wt % to about 59 wt % of poly(methyl methacrylate) and have an average particle diameter of about 3 μm to about 9 μm and a coefficient of variation (CV) of about 20% to about 40%. The thermoplastic resin composition can have good properties in terms of light transmission, light diffusion and balance therebetween.

First claim

What is claimed is:

1. A thermoplastic resin composition comprising:
about 100 parts by weight of a polycarbonate resin; and
about 0.5 parts by weight to about 3 parts by weight of particles comprising a copolymer of styrene and methyl methacrylate,
wherein the copolymer of styrene and methyl methacrylate comprises about 45 wt % to about 55 wt % of styrene and about 45 wt % to about 55 wt % of methyl methacrylate and wherein the particles formed of the copolymer of styrene and methyl methacrylate have an average particle diameter of about 3 μm to about 9 μm and a coefficient of variation (CV) of about 20% to about 40%, as calculated by Equation 1:
Coefficient of variation (CV)=[σ/ M ]×100%  [Equation 1]

where M is an average particle diameter of the copolymer particles and σ is a standard deviation of particle diameters of the copolymer particles,
wherein the thermoplastic resin composition has a transmittance of about 96% or more and a transmittance of about 92% or more, as measured on a 1.0 mm thick specimen and a 2.0 mm thick specimen in accordance with ASTM D1003, respectively; and a luminosity angle of about 3° to about 20° corresponding to half of luminosity at 0°, as measured on a 1.0 mm thick specimen using a goniophotometer, and a luminosity angle of about 10° to about 30° corresponding to half of luminosity at 0°, as measured on a 2.0 mm thick specimen using the goniophotometer.

2. The thermoplastic resin composition according to claim 1 , wherein the polycarbonate resin has a weight average molecular weight of about 20,000 g/mol to about 30,000 g/mol.

3. The thermoplastic resin composition according to claim 1 , comprising about 1 part by weight to about 2 parts by weight of the particles comprising the copolymer of styrene and methyl methacrylate, the particles comprising the copolymer of styrene and methyl methacrylate having an average particle diameter of about 3 μm to about 7 μm.

4. The thermoplastic resin composition according to claim 3 , wherein the particles comprising the copolymer of styrene and methyl methacrylate have an average particle diameter of about 4 μm to about 6 μm.

5. A light diffusion sheet comprising a polycarbonate resin matrix and a light diffusing agent dispersed in the polycarbonate resin matrix,
wherein the light diffusing agent comprises particles comprising a copolymer of styrene and methyl methacrylate,
wherein the copolymer of styrene and methyl methacrylate comprises about 45 wt % to about 55 wt % of styrene and about 45 wt % to about 55 wt % of methyl methacrylate and wherein the particles formed of the copolymer of styrene and methyl methacrylate have an average particle diameter of about 3 μm to about 9 μm and a coefficient of variation (CV) of about 20% to about 40%, as calculated by Equation 1:
Coefficient of variation (CV)=[σ/ M ]×100%  [Equation 1]

where M is an average particle diameter of the copolymer particles and σ is a standard deviation of particle diameters of the copolymer particles,
wherein the composition of the light diffusion sheet has a transmittance of about 96% or more and a transmittance of about 92% or more, as measured on a 1.0 mm thick specimen and a 2.0 mm thick specimen in accordance with ASTM D1003, respectively; and a luminosity angle of about 3° to about 20° corresponding to half of luminosity at 0°, as measured on a 1.0 mm thick specimen using a goniophotometer, and a luminosity angle of about 10° to about 30° corresponding to half of luminosity at 0°, as measured on a 2.0 mm thick specimen using the goniophotometer.

6. The light diffusion sheet according to claim 5 , comprising: about 100 parts by weight of the polycarbonate resin matrix; and about 0.5 parts by weight to about 3 parts by weight of the light diffusing agent.

7. The light diffusion sheet according to claim 5 , wherein the particles comprising the copolymer of styrene and methyl methacrylate have an average particle diameter of about 3 μm to about 7 μm.

8. The light diffusion sheet according to claim 7 , wherein the particles comprising the copolymer of styrene and methyl methacrylate have an average particle diameter of about 4 μm to about 6 μm.

Assignees

• Lotte Chemical Corp

Inventors

• Lee Sang Hoon
• Kang Tae Gon
• Woo Eun Taek
• Jeong Da Heen

Classifications

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• G02B5/0242 Primary

  by means of dispersed particles · CPC title

• C08F212/08

  Styrene · CPC title

• C08L33/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title