Concentrated solution of poly(furfuryl alcohol) for sizing organic or mineral fibres

Patent metadata

Field	Value
Publication number	US-11518851-B2
Application number	US-201816493128-A
Country	US
Kind code	B2
Filing date	Mar 14, 2018
Priority date	Mar 15, 2017
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

The present invention relates to an aqueous poly(furfuryl alcohol) solution containing:from 40% to 85% by weight of poly(furfuryl alcohol),from 15% to 60% by weight of water andless than 1.5% by weight of furfuryl alcohol, said solution being characterized in that it exhibits a pH of greater than 7.0, preferably of between 7.2 and 10.0. The invention also relates to a process for the manufacture of a product based on mineral or organic fibers which are bonded by an organic binder, using such an aqueous poly(furfuryl alcohol) solution in the diluted form.

First claim

The invention claimed is:

1. A process for manufacturing a product based on mineral or organic fibers which are bonded by an organic binder, said process comprising:
(a) preparing a binding composition exhibiting a pH of greater than 7 by dilution with water of an aqueous poly(furfuryl alcohol) solution,
(b) applying the binding composition to mineral or organic fibers,
(c) forming an assemblage of mineral or organic fibers, wherein stage (b) precedes stage (c), and
(d) heating the assemblage of mineral or organic fibers until curing of the binding composition,
wherein the aqueous poly(furfuryl alcohol) solution comprises:
from 40% to 85% by weight of poly(furfuryl alcohol);
from 15% to 60% by weight of water; and
less than 1.5% by weight of furfuryl alcohol, and

wherein the aqueous poly(furfuryl alcohol) solution exhibits a pH of greater than 7.0.

2. The process as claimed in claim 1 , wherein the stage (a) of preparing the binding composition additionally comprises the addition of adjuvants.

3. The process as claimed in claim 1 , wherein stage (a) does not comprise the addition of an acid to the aqueous poly(furfuryl alcohol) solution.

4. The process as claimed in claim 1 , wherein the assemblage of mineral or organic fibers is a woven or nonwoven textile, a mat of fibers, a board of fibers or a fiber-based molded product.

5. The process as claimed in claim 1 , wherein the binding composition exhibits a dry matter content of between 2% and 20% by weight.

6. The process as claimed in claim 1 , wherein the fibers are mineral fibers and the assemblage of mineral fibers exhibits, after the curing stage (d), a loss on ignition (LOT) of between 1% and 20%.

7. The process as claimed in claim 1 , wherein stage (d) comprises the heating of the assemblage of mineral or organic fibers at a temperature of between 120 and 250° C. for a time of between 1 and 10 minutes.

8. A process for manufacturing a product based on mineral or organic fibers which are bonded by an organic binder, said process comprising:
(a) preparing a binding composition exhibiting a pH of greater than 7 by dilution with water of an aqueous poly(furfuryl alcohol) solution,
(b) applying the binding composition to mineral or organic fibers, before or after stage (b),
(c) forming an assemblage of mineral or organic fibers, and
(d) heating the assemblage of mineral or organic fibers until curing of the binding composition,
wherein the aqueous poly(furfuryl alcohol) solution comprises:
from 40% to 85% by weight of poly(furfuryl alcohol);
from 15% to 60% by weight of water; and
less than 1.5% by weight of furfuryl alcohol,
wherein the aqueous poly(furfuryl alcohol) solution exhibits a pH of greater than 7.0, and
wherein the binding composition exhibits a dry matter content of between 2% and 20% by weight.

9. The process as claimed in claim 8 , wherein the stage (a) of preparing the binding composition additionally comprises the addition of adjuvants.

10. The process as claimed in claim 8 , wherein stage (a) does not comprise the addition of an acid to the aqueous poly(furfuryl alcohol) solution.

11. The process as claimed in claim 8 , wherein the assemblage of mineral or organic fibers is a woven or nonwoven textile, a mat of fibers, a board of fibers or a fiber-based molded product.

12. The process as claimed in claim 8 , wherein the binding composition exhibits a dry matter content of between 2.5% and 15% by weight.

13. The process as claimed in claim 8 , wherein the fibers are mineral fibers and the assemblage of mineral fibers exhibits, after the curing stage (d), a loss on ignition (LOI) of between 1% and 20%.

14. The process as claimed in claim 8 , wherein stage (d) comprises the heating of the assemblage of mineral or organic fibers at a temperature of between 120 and 250° C. for a time of between 1 and 10 minutes.

15. A process for manufacturing a product based on mineral fibers which are bonded by an organic binder, said process comprising:
(a) preparing a binding composition exhibiting a pH of greater than 7 by dilution with water of an aqueous poly(furfuryl alcohol) solution,
(b) applying the binding composition to mineral fibers, before or after stage (b),
(c) forming an assemblage of mineral fibers, and
(d) heating the assemblage of mineral fibers until curing of the binding composition,
wherein the aqueous poly(furfuryl alcohol) solution comprises:
from 40% to 85% by weight of poly(furfuryl alcohol);
from 15% to 60% by weight of water; and
less than 1.5% by weight of furfuryl alcohol, and
wherein the aqueous poly(furfuryl alcohol) solution exhibits a pH of greater than 7.0, and
wherein the assemblage of mineral fibers exhibits, after the curing stage (d), a loss on ignition (LOI) of between 1% and 20%.

16. The process as claimed in claim 15 , wherein the stage (a) of preparing the binding composition additionally comprises the addition of adjuvants.

17. The process as claimed in claim 15 , wherein stage (a) does not comprise the addition of an acid to the aqueous poly(furfuryl alcohol) solution.

18. The process as claimed in claim 15 , wherein the assemblage of mineral fibers is a woven or nonwoven textile, a mat of fibers, a board of fibers or a fiber-based molded product.

19. The process as claimed in claim 15 , wherein the binding composition exhibits a dry matter content of between 2% and 20% by weight.

20. The process as claimed in claim 15 , wherein the assemblage of mineral fibers exhibits, after the curing stage (d), a loss on ignition (LOI) of between 1% and 7%.

21. The process as claimed in claim 15 , wherein stage (d) comprises the heating of the assemblage of mineral fibers at a temperature of between 120 and 250° C. for a time of between 1 and 10 minutes.

Assignees

• Saint Gobain Isover

Inventors

• Salomon Pierre
• Jaffrennou Boris

Classifications

• D06M15/53

  Polyethers (polyacetals D06M15/39) · CPC title

• C08G65/36 Primary

  Furfuryl alcohol · CPC title

• D06M2200/40

  Reduced friction resistance, lubricant properties; Sizing compositions · CPC title

• C08J3/07

  from polymer solutions · CPC title