Compositions and method to improve the durability of calcium silicate-based cements and concretes

Patent metadata

Field	Value
Publication number	US-11518715-B2
Application number	US-201816197961-A
Country	US
Kind code	B2
Filing date	Nov 21, 2018
Priority date	Nov 21, 2017
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

Calcium silicate-based cements and concretes are disclosed, which result in concrete compositions that have an increased durability. A cement product includes a plurality of particles of a carbonatable calcium silicate cement and a hydrophobic organic acid, or a salt thereof, or a silane, or a polysiloxane.

First claim

The invention claimed is:

1. A non-hydraulic cement comprising:
a plurality of particles of a carbonatable calcium silicate phases, the calcium silicate comprising one or more discrete calcium silicate phase selected from CS (wollastonite or pseudowollastonite), C3S2 (rankinite), C2S (belite, larnite, bredigite), and an amorphous phase at about 30% or more by mass of the total phases; and
a hydrophobic organic acid, or a salt thereof, or a silane, or a polysiloxane.

2. The cement of claim 1 , wherein the hydrophobic organic acid, or a salt thereof, is one or more fatty acid(s), or one or more salt(s) thereof.

3. The cement of claim 2 , wherein the fatty acid, or a salt thereof, is selected from the group consisting of a valeric acid, or a salt thereof; stearic acid, or a salt thereof; an oleic acid, or a salt thereof; an arachidic acid, or a salt thereof; a palmitic acid, or a salt thereof; an arachidonic acid, or a salt thereof; an erucic acid, or a salt thereof; a linoleic acid, or a salt thereof; a linolenic acid, or a salt thereof and a lauric acid, or a salt thereof or a combination thereof.

4. The cement of claim 3 , wherein a salt of the fatty acid is a calcium stearate.

5. A concrete comprising:
the cement of claim 1 , wherein the cement product is cured with carbon dioxide to produce a structure comprising of a core, wherein the core comprises of a portion of an unreacted calcium silicate particle;
a silica-rich layer covering at least a portion of the surface of the core; and
an exterior layer covering at least a portion of the silica-rich first layer, wherein, the exterior layer comprises calcium carbonate;
and a plurality of aggregate particles.

6. A method for preparing a concrete product comprising:
mixing the cement of claim 1 with a plurality of aggregate particles to form a concrete product having a plurality of pores;
placing and forming the concrete product in molds;
curing the formed concrete product with carbon dioxide to produce a structure comprising of a core, wherein the core comprises of a portion of an unreacted carbonatable calcium silicate particle;
a silica-rich layer covering at least a portion of the surface of the core; and
an exterior layer covering at least a portion of the silica-rich first layer, wherein, the exterior layer comprises calcium carbonate.

7. A carbonatable composition comprising:
one or more discrete calcium silicate phases selected from CS (wollastonite or pseudowollastonite), C3S2 (rankinite), C2S (belite, larnite, bredigite), and an amorphous calcium silicate phase at about 30% or more by mass of the total phases; and
calcium aluminate accounting for about 0.1% to about 2.5% by weight of the carbonatable composition, wherein elemental Ca and elemental Si are present in the composition at a molar ratio from about 0.8 to about 1.2; and metal oxides of Al, Fe and Mg are present in the composition at about 30% or less by mass, and
a hydrophobic organic acid, or a salt thereof, or a silane, or a polysiloxane.

8. The carbonatable composition of claim 7 , wherein the salt is a calcium stearate.

Assignees

• Solidia Technologies Inc

Inventors

• Pommier Guillaume
• Lecomte Gilles
• Huet Bruno
• Mosquet Martin
• Meyer Vincent
• Sahu Sadananda
• Tas Ahmet Cuneyt
• Ravikumar Deepak
• Bryant Jason Elizan
• Seth Anuj

Classifications

• C04B2111/27

  Water resistance, i.e. waterproof or water-repellent materials · CPC title

• C04B28/188 Primary

  the Ca-silicates being present in the starting mixture · CPC title

• C04B24/08

  Fats; Fatty oils; Ester type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats · CPC title

• Y02P40/18

  Carbon capture and storage [CCS] · CPC title

• C04B2111/29

  Frost-thaw resistance · CPC title