Sensor formed from conductive nanoparticles and a porous non-conductive substrate

Patent metadata

Field	Value
Publication number	US-11518710-B2
Application number	US-202016990117-A
Country	US
Kind code	B2
Filing date	Aug 11, 2020
Priority date	Jan 28, 2014
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

In various aspects, the sensors include a substrate that is porous and non-conductive with nanoparticles deposited onto the substrate within pores of the substrate by an electrophoretic process to form a sensor element. The nanoparticles are electrically conductive. The sensor includes a detector in communication with the sensor element to measure a change in an electrical property of the sensor element. The change in the electrical property may result from alterations in quantum tunneling between nanoparticles within the sensor element, in various aspects.

First claim

The invention claimed is:

1. A sensor, comprising:
a substrate that is porous and non-conductive;
nanoparticles deposited upon surfaces of pores within an interior of the substrate to form a sensor element that is dry, wherein the nanoparticles are electrically conductive; and
a detector in operable communication with the sensor element to measure a change in an electrical property of the sensor element.

2. The sensor of claim 1 , wherein the nanoparticles comprise carbon.

3. The sensor of claim 1 , wherein the nanoparticles comprise a metal.

4. The sensor of claim 1 , wherein the substrate comprises cellulose.

5. The sensor of claim 1 , further comprising:
a voltage source in communication with the sensor element.

6. The sensor of claim 5 , wherein the voltage source applies a constant voltage across at least portions of the sensor element.

7. The sensor of claim 5 , wherein the voltage source flows a constant current through at least portions of the sensor element.

8. The sensor of claim 1 , wherein the electrical property measured by the detector is selected from a group consisting of resistivity, capacitance, and inductance.

9. The sensor of claim 1 , wherein the change in the electrical property of the sensor element is caused by straining of the sensor element.

10. A sensor, comprising:
a substrate comprised of fibers, the substrate is porous and non-conductive;
nanoparticles deposited upon the fibers within an interior of the substrate to form a sensor element that is dry, wherein the nanoparticles are electrically conductive;
a detector in operable communication with the sensor element to measure a change in an electrical property of the sensor element.

11. The sensor of claim 10 , wherein the fibers comprise a material selected from a group consisting of glass, aromatic polyamide (aramid), polyethylene terephthalate (polyester) and cellulose.

12. The sensor of claim 10 , wherein the nanoparticles comprise carbon.

13. The sensor of claim 10 , wherein the nanoparticles adhere to the surfaces by covalent bond between the nanoparticles and the fibers.

14. The sensor of claim 10 , wherein the electrical property measured by the detector is selected from a group consisting of resistivity, capacitance, and inductance.

15. The sensor of claim 10 , further comprising the step of: wherein the change in the electrical property is caused by straining of the sensor element.

16. A method of sensing with a sensor including a sensor element, comprising the steps of:
inducing an electric field through a substrate that is porous and non-conductive;
contacting a nanoparticle dispersion with the substrate, the nanoparticle dispersion comprising functionalized nanoparticles having a charge;
drawing the functionalized nanoparticles into pores within an interior of the substrate using the electric field;
depositing the functionalized nanoparticles onto upon surfaces of the substrate within the pores;
withdrawing the substrate from contact with the nanoparticle dispersion;
drying the substrate thereby forming said sensor element that is dry, wherein said sensor element comprises the substrate with the functionalized nanoparticles disposed upon surfaces of the substrate within the interior of the substrate; and
detecting a change in an electrical property of said sensor element.

17. The method of claim 16 , further comprising the step of:
deforming said sensor element thereby causing a change in an electrical property of said sensor element.

18. The method of claim 16 , wherein the nanoparticles comprise carbon.

19. The method of claim 16 , wherein the substrate comprises cellulose.

20. The method of claim 16 , wherein the electrical property of said sensor element is selected from a group consisting of resistivity, capacitance, and inductance.

Assignees

• Univ Delaware

Inventors

• Thostenson Erik
• Schumacher Thomas

Classifications

• C25D13/22

  Servicing or operating {apparatus or multistep processes} · CPC title

• Y10T428/254

  Polymeric or resinous material · CPC title

• C08K3/042

  Graphene or derivatives, e.g. graphene oxides · CPC title

• C09D5/4419

  with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08K3/041

  Carbon nanotubes · CPC title