Multilayer tube

Patent metadata

Field	Value
Publication number	US-11518155-B2
Application number	US-201917418631-A
Country	US
Kind code	B2
Filing date	Oct 25, 2019
Priority date	Dec 27, 2018
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

This is to provide a multilayer tube excellent in interlayer adhesiveness and durability thereof while maintaining various characteristics such as low temperature impact resistance, bursting pressure strength and flexibility.In a multilayer tube having at least two kinds of layers and the both layers are adjacent to each other, an aliphatic polyamide composition constituting one of the layers contains an aliphatic polyamide having a ratio of a number of methylene groups to a number of amide groups of a specific value or more and a copolymerized polyamide having a specific unit, and an elastomeric polymer which may contain a constitutional unit derived from an unsaturated compound having a carboxyl group(s) and/or an acid anhydride group(s).

First claim

The invention claimed is:

1. A multilayer tube which comprises
two or more layers containing Layer (a) and Layer (b), wherein
at least a pair of the Layer (a) and the Layer (b) are disposed adjacent to each other,
the Layer (a) contains an aliphatic polyamide composition (A),
the Layer (b) contains an aliphatic polyamide composition (B),
the aliphatic polyamide composition (A) contains a polyamide (A1), a polyamide (A2) and an elastomeric polymer (A3),
the polyamide (A1) is an aliphatic polyamide which has a ratio of a number of methylene groups to a number of amide groups of 8.0 or more, and which does not contain a copolymer containing a unit “a” derived from ε-caprolactam or ε-aminocaproic acid and a unit “b” derived from aminododecanoic acid or w-laurolactam, and is contained in an amount of 30% by mass or more and 85% by mass or less in the aliphatic polyamide composition (A),
the polyamide (A2) is an aliphatic polyamide which contains a copolymer containing a unit “a” derived from ε-caprolactam or ε-aminocaproic acid and a unit “b” derived from aminododecanoic acid or ω-laurolactam, and is contained in an amount of 10% by mass or more and 35% by mass or less in the aliphatic polyamide composition (A),
the elastomeric polymer (A3) is an elastomeric polymer which may contain a constitutional unit derived from an unsaturated compound having a carboxyl group(s) and/or an acid anhydride group(s), and is contained in an amount of 5% by mass or more and 30% by mass or less in the aliphatic polyamide composition (A),
the aliphatic polyamide composition (B) contains a polyamide (B1) and an elastomeric polymer (B2),
the polyamide (B1) is an aliphatic polyamide which has a ratio of a number of methylene groups to a number of amide groups of less than 8.0, and is contained in an amount of 55% by mass or more and 95% by mass or less in the aliphatic polyamide composition (B),
the elastomeric polymer (B2) is an elastomeric polymer which contains a constitutional unit derived from an unsaturated compound having a carboxyl group(s) and/or an acid anhydride group(s), and is contained in an amount of 5% by mass or more and 30% by mass or less in the aliphatic polyamide composition (B) and
the wall thickness of the multilayer tube is 0.5 mm or more and 25 mm or less.

2. The multilayer tube according to claim 1 , wherein the polyamide (A1) is at least one kind of a homopolymer selected from the group consisting of polyundecamide (polyamide 11), polydodecamide (polyamide 12), polyhexamethylene dodecamide (polyamide 612), polydecamethylene sebacamide (polyamide 1010), polydecamethylene dodecamide (polyamide 1012) and polydodecamethylene dodecamide (polyamide 1212), and/or at least one kind of a copolymer using two or more kinds of raw material monomers forming the homopolymers.

3. The multilayer tube according to claim 1 , wherein the polyamide (A2) is polyamide 6/12 and/or polyamide 6/66/12.

4. The multilayer tube according to claim 1 , wherein the polyamide (A2) contains the unit “a” derived from ε-caprolactam or ε-aminocaproic acid in an amount of 50% by mass or more.

5. The multilayer tube according to claim 1 , wherein the elastomeric polymer (A3) contains an elastomeric polymer which contains a constitutional unit derived from an unsaturated compound having a carboxyl group(s) and/or an acid anhydride group(s) in an amount of 60% by mass or more in 100% by mass of the elastomeric polymer (A3).

6. The multilayer tube according to claim 1 , wherein the polyamide (B1) is at least one kind of a homopolymer selected from the group consisting of polycaproamide (polyamide 6), polyhexamethylene adipamide (polyamide 66), polyhexamethylene azelamide (polyamide 69), and polyhexamethylene sebacamide (polyamide 610), and/or at least one kind of a copolymer using two or more kinds of raw material monomers forming the homopolymers.

7. The multilayer tube according to claim 1 , wherein when the terminal amino group concentration which is summed values of the respective terminal amino group concentrations (μeq/g) of the polyamide (A1) and the polyamide (A2) per 1 g of the aliphatic polyamide composition (A) multiplying a mixing mass ratio thereof is made [A](μeq/g), and when the terminal carboxyl group concentration which is summed values of the respective terminal carboxyl group concentrations (μeq/g) of the polyamide (A1) and the polyamide (A2) per 1 g of the aliphatic polyamide composition (A) multiplying a mixing mass ratio thereof is made [B] (μeq/g), then [A]>[B]+5.

8. The multilayer tube according to claim 1 , wherein the Layer (a) contains 40% by mass or more and 100% by mass or less of the aliphatic polyamide composition (A), and the Layer (b) contains 60% by mass or more and 100% by mass or less of the aliphatic polyamide composition (B).

9. The multilayer tube according to claim 1 , which is produced by coextrusion molding.

10. The multilayer tube according to claim 1 , which is used as a chemical solution and/or gas transport tube.

11. The multilayer tube according to claim 1 , wherein a shape is a hollow body.

12. The multilayer tube according to claim 11 , which has at least one layer of the Layer (b) disposed inside the Layer (a).

13. The multilayer tube according to claim 11 , wherein the Layer (a), the Layer (b) and the Layer (a) are laminated in this order from outside, and the respective layers are adjacent to each other.

Assignees

• Ube Industries

Inventors

• Tsuboi Kazutoshi
• NAKAO Yukiko
• Sasaki Ryousuke
• FUKUDA Ryu

Classifications

• B32B27/36

  comprising polyesters · CPC title

• B32B15/09

  comprising polyesters · CPC title

• B32B15/082

  comprising vinyl resins; comprising acrylic resins · CPC title

• B32B27/10

  of paper or cardboard · CPC title

• B32B2307/732

  Dimensional properties · CPC title