Thermoplastic prepreg based foam product

Patent metadata

Field	Value
Publication number	US-11518119-B2
Application number	US-202016833794-A
Country	US
Kind code	B2
Filing date	Mar 30, 2020
Priority date	Mar 30, 2020
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

A system for manufacturing a thermoplastic prepreg product includes a belt or conveyor, a prepreg applicator that positions a thermoplastic prepreg atop the belt or conveyor, a foam applicator that applies a foam mixture atop the thermoplastic prepreg, a heating mechanism that heats the thermoplastic prepreg and the foam mixture to cause the foam mixture to react atop the thermoplastic prepreg, and a laminator that is configured to press the thermoplastic prepreg and foam mixture to control a thickness of the resulting thermoplastic prepreg product. The thermoplastic prepreg includes a fabric, mat, or web of fibers and a thermoplastic material that is impregnated within the fabric, mat, or web of fibers. The thermoplastic material is formed from in situ polymerization of monomers and oligomers. The foam mixture includes an isocyanate, a polyol blend, and a blowing agent.

First claim

What is claimed is:

1. A method of forming a thermoplastic prepreg product, the method comprising:
positioning a thermoplastic prepreg atop a belt or conveyor, the thermoplastic prepreg having a length and a width and the thermoplastic prepreg including:
a fabric, mat, or web of fibers, in which the fibers have an average length of 0.5 inches or greater; and
a thermoplastic material that is impregnated within the fabric, mat, or web of fibers, the thermoplastic material being polymerized from monomers and oligomers in which greater than 90% of the monomers or oligomers react to form the thermoplastic material;

pouring a foam mixture onto a top surface of the thermoplastic prepreg so that the foam mixture extends across the length and width of the thermoplastic prepreg, the foam mixture comprising:
an isocyanate;
a polyol blend; and
a blowing agent;

heating the thermoplastic prepreg and the foam mixture to react the foam mixture on the top surface of the thermoplastic prepreg to form a foam core that is bonded with the thermoplastic prepreg; and
laminating the thermoplastic prepreg and the foam mixture as the foam mixture reacts to control a thickness of the resulting thermoplastic prepreg product.

2. The method of claim 1 , further comprising applying a second thermoplastic prepreg atop the foam mixture after the foam mixture is poured onto the top surface of the thermoplastic prepreg such that the foam mixture is sandwiched between opposing thermoplastic prepreg layers, wherein the second thermoplastic prepreg extending across a length and width of the foam mixture.

3. The method of claim 1 , wherein the foam core consists of polyurethane foam having a foam density of 2 pounds per cubic feet (pcf) or less and a thickness of 2 inches or more.

4. The method of claim 1 , wherein the foam core consists of polyisocyanurate foam having a foam density of 2 pounds per cubic feet (pcf) or more and a thickness of 2 inches or less.

5. The method of claim 1 , wherein the thermoplastic material is fully impregnated through the fabric, mat, or web of fibers and forms a barrier such that the foam mixture does not impregnate or penetrate into fibers of the fabric, mat, or web of fibers when the foam mixture is poured onto the top surface of the thermoplastic prepreg.

6. The method of claim 1 , wherein the top surface of the thermoplastic prepreg has a mean roughness of at least 5 micrometers such that reacting the foam mixture on the top surface of the thermoplastic prepreg facilitates in mechanically coupling the foam core to the thermoplastic prepreg.

7. The method of claim 1 , further comprising applying a primer to the top surface of the thermoplastic prepreg prior to pouring the foam mixture onto the top surface of the thermoplastic prepreg.

8. The method of claim 1 , further comprising applying a thin adhesive film on the top surface of the thermoplastic prepreg prior to pouring the foam mixture onto the top surface of the thermoplastic prepreg, the thin adhesive film promoting bonding between the thermoplastic prepreg and the foam core.

9. The method of claim 1 , wherein the thermoplastic material consists essentially of polyamide, and wherein the polyamide is adhered to the foam core without using a primer or other adhesion promoter.

10. The method of claim 1 , wherein the thermoplastic material is partially impregnated within the fabric, mat, or web of fibers such that the thermoplastic material is impregnated within a first portion of fibers of the fabric, mat, or web of fibers and a second portion of fibers of the fabric, mat, or web of fibers is free of the thermoplastic material, wherein the foam mixture is poured onto the top surface of the thermoplastic prepreg so that the foam mixture impregnates or penetrates into fibers of the second portion of fibers of the fabric, mat, or web of fibers.

11. The method of claim 1 , further comprising heating the thermoplastic prepreg prior to pouring the foam mixture onto the top surface of the thermoplastic prepreg, the thermoplastic prepreg being heated to above a glass transition temperature of the thermoplastic material and below a melting temperature of the thermoplastic material.

12. The method of claim 1 , wherein the fabric, mat, or web of fibers include glass fibers, carbon fibers, basalt fibers, metal fibers, ceramic fiber, natural fibers, synthetic organic fibers, aramid fibers, inorganic fibers, or combinations thereof.

13. The method of claim 1 , wherein the thermoplastic material comprises polyamides polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polycarbonate (PC), thermoplastic polyurethane (TPU), poly(methyl methacrylate) (PMMA), or combinations thereof.

14. The method of claim 1 , wherein the thermoplastic prepreg has a void content of less than 3%.

Assignees

• Johns Manville

Inventors

• Nandi Malay
• Zhang Mingfu
• Wang Lance
• Asrar Jawed

Classifications

• B29B15/122

  with a matrix in liquid form, e.g. as melt, solution or latex · CPC title

• B29C44/326

  Joining the preformed parts, e.g. to make flat or profiled sandwich laminates · CPC title

• B32B27/36

  comprising polyesters · CPC title

• B32B2262/101

  Glass fibres · CPC title

• B32B2262/02

  Synthetic macromolecular fibres · CPC title