Composite material for removal of hydrophobic components from fluid mixtures

Patent metadata

Field	Value
Publication number	US-11517859-B2
Application number	US-202016897946-A
Country	US
Kind code	B2
Filing date	Jun 10, 2020
Priority date	Jun 10, 2020
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

Composite materials for removing hydrophobic components from a fluid include a porous matrix polymer, carbon nanotubes grafted to surfaces of the porous matrix polymer, and polystyrene chains grafted to the carbon nanotubes. Examples of porous matrix polymer include polyurethanes, polyethylenes, and polypropylenes. Membranes of the composite material may be enclosed within a fluid-permeable pouch to form a fluid treatment apparatus, such that by contacting the apparatus with a fluid mixture containing water and a hydrophobic component, the hydrophobic component absorbs selectively into the membrane. The apparatus may be removed from the fluid mixture and reused after the hydrophobic component is expelled from the membrane. The composite material may be prepared by grafting functionalized carbon nanotubes to a porous matrix polymer to form a polymer-nanotube composite, then polymerizing styrene onto the carbon nanotubes of the polymer-nanotube composite.

First claim

What is claimed is:

1. A composite material for removing hydrophobic components from a fluid, the composite material comprising:
a porous matrix polymer comprising a polyurethane, a polyethylene, or a polypropylene;
carbon nanotubes grafted to surfaces of the porous matrix polymer; and
polystyrene chains grafted to the carbon nanotubes, and in which the composite material has an average pore size from 100 nm to 1000 nm.

2. The composite material of claim 1 , in which the porous matrix polymer is a polyurethane.

3. The composite material of claim 1 , in which the porous matrix polymer is a polyurethane foam.

4. The composite material of claim 1 , wherein the surfaces of the porous matrix polymer comprise outer surfaces of the porous matrix polymer and internal pore surfaces of the porous matrix polymer.

5. The composite material of claim 1 , comprising:
from 2% to 20% by weight porous matrix polymer, based on the total weight of the composite material;
from 1% to 10% by weight carbon nanotubes, based on the total weight of the composite material; and
from 70% to 97% by weight polystyrene chains, based on the total weight of the composite material.

6. The composite material of claim 1 , comprising:
from 4% to 15% by weight porous matrix polymer, based on the total weight of the composite material;
from 2% to 6% by weight carbon nanotubes, based on the total weight of the composite material; and
from 80% to 94% by weight polystyrene chains, based on the total weight of the composite material.

7. The composite material of claim 1 , comprising:
from 8% to 10% by weight porous matrix polymer, based on the total weight of the composite material;
from 4% to 5% by weight carbon nanotubes, based on the total weight of the composite material; and
from 80% to 88% by weight polystyrene chains, based on the total weight of the composite material.

8. The composite material of claim 1 , in which the composite material exhibits a water contact angle greater than 120°, as measured by ASTM D7334.

9. The composite material of claim 1 , in which the composite material exhibits a hexane absorption capacity of at least 30 grams hexane per gram of composite material.

10. The composite material of claim 1 , in which the carbon nanotubes are grafted to the surfaces of the porous matrix polymer through oxygen-containing functional groups on the carbon nanotubes chemically linked to a polymer backbone of the porous matrix polymer.

11. A fluid treatment apparatus for removing hydrophobic components from a fluid comprising:
a membrane comprising a composite material, the composite material comprising:
a porous matrix polymer comprising a polyurethane, a polyethylene, or a polypropylene,
carbon nanotubes grafted to surfaces of the porous matrix polymer, and
polystyrene chains grafted to the carbon nanotubes; and

a fluid-permeable pouch, the membrane being enclosed within the fluid-permeable pouch.

12. A method for removing hydrophobic fluids from a fluid mixture containing water and a hydrophobic component, the method comprising:
contacting a fluid treatment apparatus according to claim 11 with the fluid mixture;
allowing the fluid mixture to absorb through the fluid-permeable pouch to contact the membrane of the composite material;
allowing at least a portion of the hydrophobic component to adsorb onto the membrane of the composite material; and
removing the fluid treatment apparatus from the fluid mixture.

13. The method of claim 12 , further comprising expelling the hydrophobic component adsorbed onto the membrane from the fluid treatment apparatus.

14. The method of claim 13 , further comprising reusing the fluid treatment apparatus to absorb additional hydrophobic component from the fluid mixture.

15. The method of claim 12 , in which the fluid mixture is produced water.

16. The method of claim 12 , in which the fluid mixture is contaminated seawater.

17. A filtration apparatus comprising a membrane of the composite material according to claim 1 in fluidic communication with a produced water source.

18. A method for preparing a composite material for removing hydrophobic components from a fluid, the method comprising:
exposing a membrane of a porous polymer material to a dispersion of hydroxyl-functionalized carbon nanotubes in a hydrophilic solvent, the porous matrix polymer comprising a polyurethane, a polyethylene, or a polypropylene;
allowing the hydroxyl-functionalized carbon nanotubes in the dispersion to graft to the porous matrix polymer and form a polymer—nanotube composite membrane;
drying the polymer—nanotube composite membrane to remove the hydrophilic solvent;
contacting the polymer—nanotube composite membrane with styrene to form a polymerization mixture;
exposing the polymerization mixture to ultraviolet radiation to polymerize the styrene and form the composite material, the composite material comprising the porous matrix polymer, carbon nanotubes grafted to the porous matrix polymer, and polystyrene chains grafted to the carbon nanotubes, and in which the composite material has an average pore size from 100 nm to 1000 nm.

19. The method of claim 18 , in which the porous matrix polymer is a polyurethane foam.

Assignees

• Saudi Arabian Oil Co
• King Fahd Univ Of Petroleum And Materials

Inventors

• Alghunaimi Fahd Ibrahim
• Baig Nadeem
• Aldossary Hind
• Saleh Tawfik A

Classifications

• B01J20/3278

  Polymers being grafted on the carrier · CPC title

• B01D71/82

  characterised by the presence of specified groups, e.g. introduced by chemical after-treatment · CPC title

• B01J20/3297

  Coatings in the shape of a sheet · CPC title

• B01D2323/385

  involving radiation · CPC title

• C02F1/681

  by addition of solid materials for removing an oily layer on water · CPC title