Microemulsions comprising an alkyl propoxylated sulfate surfactant, and related methods

Patent metadata

Field	Value
Publication number	US-11512243-B2
Application number	US-202017078258-A
Country	US
Kind code	B2
Filing date	Oct 23, 2020
Priority date	Oct 23, 2020
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

Microemulsions comprising an alkyl propoxylated sulfate surfactant and related methods, including methods of use in the treatment of subterranean formations, such as oil and condensate wells, are provided. In some embodiments, the microemulsions and/or methods of use achieve ultra-low interfacial tensions (i.e. less than or equal to 0.01 mN/m) between a wide variety of crude oils and well treatment fluids at various reservoir conditions. In some embodiments, the microemulsion comprises water, an anionic alkyl propoxylated sulfate surfactant, a solvent (e.g., a terpene solvent), and a co-solvent. In some embodiments, the microemulsion further comprises a second and/or third surfactant (e.g., a nonionic and/or an anionic surfactant).

First claim

What is claimed is:

1. A microemulsion, comprising:
water;
a terpene solvent;
a surfactant comprising an anionic alkyl propoxylated sulfate surfactant having a carbon chain length from 12 to 15 carbon atoms and having from 6 to 13 propylene oxide units and an anionic alkyl ether sulfate surfactant having a carbon chain length from 8 to 12 carbon atoms and having from 3 to 6 ethylene oxide units, wherein the ratio by weight of the anionic alkyl propoxylated sulfate surfactant to the anionic alkyl ether sulfate surfactant is from 10:1 to 1:5; and
a co-solvent.

2. The microemulsion of claim 1 further comprising a second surfactant comprising an anionic alkyl propoxylated sulfate surfactant having a carbon chain length from 12 to 15 carbon atoms and having from 3 to 5 propylene oxide units.

3. The microemulsion of claim 1 , further comprising a demulsifier.

4. The microemulsion of claim 1 , wherein the microemulsion has an interfacial tension of greater than or equal to 0.00001 mN/m and less than or equal to 0.01 mN/m.

5. The microemulsion of claim 1 , wherein the total amount of surfactant present in the microemulsion is greater than or equal to 10 wt % and less than or equal to 65 wt %.

6. A microemulsion, comprising:
water;
a terpene solvent;
a surfactant comprising an anionic alkyl propoxylated sulfate surfactant having a carbon chain length from 12 to 15 carbon atoms and having from 3 to 5 propylene oxide units and an anionic alkyl ether sulfate surfactant having a carbon chain length from 8 to 12 carbon atoms and having from 3 to 6 ethylene oxide units, wherein the ratio by weight of the anionic alkyl propoxylated sulfate surfactant to the anionic alkyl ether sulfate surfactant is from 1:2 to 1:1; and
a co-solvent.

7. The microemulsion of claim 6 , further comprising a second surfactant comprising a nonionic ethoxylated alcohol surfactant having a carbon chain length from 12 to 15 carbon atoms and from 7 to 12 ethylene oxide units.

8. A method, comprising injecting a microemulsion into an oil and/or condensate well, wherein the microemulsion comprises:
water;
a terpene solvent;
a surfactant comprising an anionic alkyl propoxylated sulfate surfactant having a carbon chain length from 12 to 15 carbon atoms and having from 6 to 13 propylene oxide units and an anionic alkyl ether sulfate surfactant having a carbon chain length from 8 to 12 carbon atoms and having from 3 to 6 ethylene oxide units, wherein the ratio by weight of the anionic alkyl propoxylated sulfate surfactant to the anionic alkyl ether sulfate surfactant is from 10:1 to 1:5; and
a co-solvent.

9. The method of claim 8 , wherein the microemulsion further comprises a second surfactant comprising an anionic alkyl propoxylated sulfate surfactant having a carbon chain length from 12 to 15 carbon atoms and having from 3 to 5 propylene oxide units.

10. The method of claim 8 , wherein the microemulsion further comprises a demulsifier.

11. The method of claim 8 , wherein the microemulsion has an interfacial tension of greater than or equal to 0.00001 mN/m and less than or equal to 0.01 mN/m.

12. The method of claim 8 , wherein the total amount of surfactant present in the microemulsion is greater than or equal to 10 wt % and less than or equal to 65 wt %.

13. A method, comprising injecting the microemulsion of claim 6 into an oil and/or condensate well.

14. The method of claim 13 , wherein the microemulsion further comprises a second surfactant comprising a nonionic ethoxylated alcohol surfactant having a carbon chain length from 12 to 15 carbon atoms and from 7 to 12 ethylene oxide units.

Assignees

• Flotek Chemistry Llc

Inventors

• Trabelsi Siwar
• Hill Randall M

Classifications

• C09K8/584 Primary

  characterised by the use of specific surfactants · CPC title

• E21B43/26

  by forming crevices or fractures · CPC title

• E21B43/16

  Enhanced recovery methods for obtaining hydrocarbons · CPC title