Room temperature curable compositions

Patent metadata

Field	Value
Publication number	US-11512237-B2
Application number	US-202017132475-A
Country	US
Kind code	B2
Filing date	Dec 23, 2020
Priority date	Nov 20, 2015
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

A room temperature curable sealant/adhesive composition is disclosed. The room temperature curable sealant/adhesive composition comprises: A) one or more organopolysiloxanes; B) a hydrophilic material; C) a cross-linker; D) a titanate catalyst and/or a zirconate catalyst; and E) one or more optional ingredients. A silicone elastomer formed therefrom and related methods are also disclosed. In general, such compositions (upon several hours of contact with water) do not repel water, but rather retain and pick-up water and/or can be wetted by aqueous materials subsequent to exposure.

First claim

What is claimed is:

1. A silicone room temperature curable sealant/adhesive composition comprising:
A) at least 50% by weight of one or more organopolysiloxanes selected from:
(i) (R″O) 3-a (R) a Si—Z—(Si(R) 2 —O) X —Si(R) 2 —Z—Si(OR″) 3-a (R) a

where each R is free of aliphatic unsaturation and is independently selected from the group consisting of monovalent hydrocarbon, monovalent halohydrocarbon, and monovalent cyanoalkyl radicals having from 1 to 18 carbon atoms, each R″ is independently a monovalent hydrocarbon group having 1 to 6 carbon atoms, Z is a divalent hydrocarbon radical or combination of divalent hydrocarbon radicals and siloxane radicals, a is 0 or 1, and x is of a value such that component A)(i) has a viscosity of from 0.5 to 3000 Pa·s at 25° C.;
(ii) alpha, omega-diorganopolysiloxanes of the formula
(HO) 3-b (R) b Si—O—(Si(R) 2 —O) y —Si(OH) 3-b (R) b

where each R is free of aliphatic unsaturation and is independently selected from the group consisting of monovalent hydrocarbon, monovalent halohydrocarbon, and monovalent cyanoalkyl radicals having from 1 to 18 carbon atoms, b is 0, 1 or 2, and y is of a value such that component A)(ii) has a viscosity of from 0.5 to 3000 Pa·s at 25° C.; or
(iii) mixtures of the above;

B) 5 to 35% by weight of a hydrophilic material selected from:
(i) hydrophilic and/or water soluble resins based on polyethylene oxide and/or polypropylene oxide;
(ii) one or more anionic surfactants;
(iii) polymers containing ionisable groups; and
(iv) mixtures of two or more of (i), (ii) and (iii);

C) 0.5 to 7.5% by weight of a cross-linker selected from a silane or siloxane cross linker containing at least two alkoxy or alkenyloxy groups, or silyl functional molecules having at least two silyl groups, each silyl group containing at least one alkoxy or alkenyloxy group;
D) 0.5 to 5% by weight titanate or zirconate catalyst; and
E) optionally, one or more ingredients selected from fillers, co-catalysts, rheological modifiers, plasticisers, adhesion promoters, compatibilizers, pigments, heat stabilizers, flame retardants, UV stabilizers, chain extenders, electrically and/or heat conductive fillers, and/or fungicides/biocides;
wherein the total % weight of A)+B)+C)+D)+E) is 100%;
wherein component B) comprises component B)(i);
wherein component B)(i) comprises polyoxyalkylene polymers comprising recurring oxyalkylene units illustrated by the average formula (—C n H 2n —O—) y wherein n is an integer from two to four and y is an integer of at least four; and
wherein the number average molecular weight of each polyoxyalkylene polymer is greater than 50000.

2. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein component B)(i) is free of silane or siloxane modification.

3. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein the number average molecular weight of each polyoxyalkylene polymer is greater than 75000.

4. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein component B) comprises component B)(ii) and wherein the one or more anionic surfactants are selected from sodium/potassium sulphonates, alkenyl sulphonates, alkyl sulphates, alkyl-benzene sulphonates, potassium alkyl phosphates, alkyl succinates, alkyl sulphosuccinates and N-alkyl sarcosinates and sodium, magnesium, ammonium, and the mono-, di- and triethanolamine salts of alkyl and aralkyl sulphates as well as the salts of alkaryl sulphonates and/or mixtures thereof.

5. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein component B) comprises component B)(iii) and wherein the hydrophilic material is selected from homopolymers and copolymers comprising vinylsulphonic, styrenesulphonic, naphthalenesulphonic or acrylamidoalkylsulphonic units and their salts and also copolymers thereof with an unsaturated comonomer.

6. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , stored before use in one or two parts.

7. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , which is a one-component composition which, when stored at a temperature above 30° C., prior to cure retains at least 50% of its mechanical strength upon cure.

8. A silicone elastomer resulting from curing the silicone room temperature curable sealant/adhesive composition in accordance with claim 1 .

9. The silicone elastomer of claim 8 , having a water pick-up of at least 0.01 gram of water per gram of silicone elastomer, when the silicone elastomer is immersed in water or phosphate buffer saline for 24h.

10. A sealant comprising the silicone elastomer in accordance with claim 8 .

11. A method of controlling and/or restraining aqueous leaks, said method comprising disposing a silicone elastomer where joint expansion is desired, wherein the silicone elastomer is the silicone elastomer in accordance with claim 9 .

12. A patch comprising the silicone elastomer in accordance with claim 8 .

13. A method of filling a space defined between two substrates so as to form an arrangement, the method comprising:
a) providing the silicone room temperature curable sealant/adhesive composition in accordance with claim 1 ;
b1) applying the composition to a first substrate, and bringing a second substrate in contact with the composition that has been applied to the first substrate; or
b2) filling a space defined by a first substrate and a second substrate with the composition; and
c) curing the composition, thereby forming the arrangement.

14. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein component E) is present.

15. A medical device comprising the silicone elastomer in accordance with claim 8 .

16. A diaper comprising the silicone elastomer in accordance with claim 8 .

17. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein component B)(i) is present in the composition in amount of from about 10 to about 30% by weight.

18. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein component B)(i):
i) has a molecular weight of from about 75,000 to about 20,000,000 g/mol;
ii) has a viscosity of about 6,800 to about 8,800 cP; or
iii) both i) and ii).

19. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein the composition is substantially, or optionally completely free of:
i) silane-modified (poly)akylene oxide compounds;
ii) siloxane-modified (poly)akylene oxide compounds; or
iii) both i) and ii).

20. The silicone room temperature curable sealant/adhesive composition in accordance with claim 1 , wherein the curable sealant/adhesive composition has a skin over time (SOT) of less than 1 hour.

Assignees

• Dow Silicones Corp

Inventors

• Detemmerman Tommy
• Dimitrova Tatiana
• Gubbels Frederic

Classifications

• C08L83/06

  containing silicon bound to oxygen-containing groups (C08L83/12 takes precedence) · CPC title

• C08G2170/00

  Compositions for adhesives · CPC title

• C08K3/36

  Silica · CPC title

• C08L71/08

  Polyethers derived from hydroxy compounds or from their metallic derivatives (C08L71/02 takes precedence) · CPC title

• C08G77/08

  characterised by the catalysts used · CPC title