Adhesive sheet and adhesive material using the same

Patent metadata

Field	Value
Publication number	US-11512227-B2
Application number	US-201916692056-A
Country	US
Kind code	B2
Filing date	Nov 22, 2019
Priority date	Nov 23, 2018
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

An adhesive sheet utilizes an acrylic resin composition without using a separate primer layer, thus providing excellent adhesion, high reliability due to its excellent light resistance under the sunlight exposure, and excellent elastic modulus, and can be easily used as an adhesive material in various fields such as building materials and automobiles.

First claim

What is claimed is:

1. An adhesive sheet comprising:
an adhesive layer formed of a resin composition and
a loss elastic modulus of said adhesive sheet satisfying an Equation 1:
|log LM −10° C. −log LM 0° C. |≤0.600

wherein a log LM −10° C. is a log value of said loss elastic modulus measured at a rate of 5° C./min of under a condition of −10° C., 1 Hz, and 1% strain, and a log LM 0° C. is a log value of said loss elastic modulus measured at a rate of 5° C./min under a condition of at 0° C., 1 Hz and 1% strain, and
wherein the resin composition includes:
(a) 100 parts by weight of an alkyl (meth) acrylate having a straight or a branched chain alkyl group having 1 to 10 carbon atoms;
(b) 58 to 62 parts by weight of hydroxyl-containing monomers;
(c) 70 to 110 parts by weight of an aliphatic saturated hydrocarbon ring-containing monomer having 4 to 20 carbon atoms;
(d) 28 to 35 parts by weight of a UV absorber; and
(e) 5 parts by weight or less of a photo polymerization initiator.

2. The adhesive sheet of claim 1 , wherein an average light transmittance of a light transmitting through said adhesive sheet is 10% or less, and
wherein a range of a wavelength of said light is 300 nm to 400 nm.

3. The adhesive sheet according to the claim 1 , wherein said loss elastic modulus is 0.25 MPa to 0.65 MPa measured at 25° C. and 1 Hz.

4. The adhesive sheet of claim 1 , wherein said alkyl (meth) acrylates has one or more elements selected from the group consisting of an n-butyl acrylate, an iso-butyl acrylate, a pentyl acrylate, a hexyl acrylate, a 2-ethylhexyl acrylate (2-EHA), an iso-octyl acrylate, an n-nonyl (meth) acrylate, an iso-nonyl acrylate, an n-decyl (meth) acrylate and an iso-decyl (meth) acrylate.

5. The adhesive sheet of claim 1 , wherein said hydroxyl-containing monomers has one or more elements selected from the group consisting of a 2-hydroxyethyl (meth) acrylate (2-HEA), a 2-hydroxypropyl (meth) acrylate, a 4-hydroxybutyl (meth) acrylate, a 6-hydroxyhexyl (meth) acrylate, an 8-hydroxyoctyl (meth) acrylate, a 2-hydroxyethylene glycol (meth) acrylate and a 2-hydroxypropylene glycol (meth) acrylate.

6. The adhesive sheet of claim 1 , wherein said aliphatic saturated hydrocarbon ring-containing monomer has one or more elements selected from the group consisting of an isobornyl (meth) acrylate, a cyclohexyl (meth) acrylate, a norbornanyl (meth) acrylate, a norbornenyl (meth) acrylate, a dicyclo pentadienyl (meth) acrylate, an ethynylcyclohexane (meth) acrylate, and an ethynylcyclohexene (meth) acrylate.

7. The adhesive sheet of claim 1 , wherein said photo polymerization initiator has one or more elements selected from the group consisting of a 1-hydroxy cyclohexyl phenylketone, a 2,2-dimethoxy-2-phenyl acetophenone, a 2-hydroxy-2-methyl-1-phenyl-propan-1-one, a 2-methyl-1-[4-(methylthio) phenyl]-2-morpholinopropane-1-one, a 2-benzyl-2-dimethyl amino-1-(4-morpholinophenyl)-butan-1-one, a 2-chlorothioxanthone, a 2,4-dimethylthioxanthone, a 2,4-diisopropylthioxanthone, an isopropyl thioxanthone, a 2,4,6-trimethylbenzoyl diphosphine oxide and a bis ((2,6-dimethoxybenzoyl)-2,4,4-trimethylpentyl) phosphine oxide.

8. The adhesive sheet of claim 1 , wherein said UV absorber has one or more elements selected from the group consisting of a benzophenone compound, an oxalanilide compound, a benzotriazole compound and a triazine compound.

9. The adhesive sheet of claim 1 , wherein said resin composition has one or more elements selected from the group consisting of an amide containing monomer and an aromatic ring containing monomer.

10. The adhesive sheet of claim 9 , wherein a content of the amide-containing monomer or the aromatic ring-containing monomer is 1 to 50 parts by weight based on 100 parts by weight of said alkyl (meth) acrylate.

11. The adhesive sheet of claim 9 , wherein said amide containing monomer has one or more elements selected from the group consisting of an N, N-dimethylacrylamide, an N, N-diethylacrylamide, and an N, N-dimethylmethacrylamide.

12. The adhesive sheet of claim 9 , wherein said aromatic ring containing monomer has one or more elements selected from the group consisting of a phenoxyethyl (meth) acrylate, a benzyl (meth) acrylate, a phenoxydiethylene glycol (meth) acrylate, an ethylene oxide modified phenoxy nonyl (meth) acrylate, and an ethylene oxide (meth) acrylate modified cresol.

13. The adhesive sheet of claim 1 , wherein said resin composition has one or more of a silane coupling agent and a crosslinking agent.

14. The adhesive sheet of claim 13 , wherein said silane coupling agent has one or more elements selected from the group consisting of a γ-glycidoxy propyltrimethoxysilane, a γ-glycidoxy propyltriethoxysilane, a γ-aminopropyltrimethoxysilane, and an N-phenyl-aminopropyltrimethoxysilane.

15. The adhesive sheet of claim 13 , wherein said crosslinking agent has one or more multifunctional acrylate elements selected from the group consisting of a dipentaerythritol hexaacrylate, a tetramethylolmethane tetraacrylate, a tetramethylolmethane triacrylate, a trimethanolpropane triacrylate, a 1,6-bis (3-acryloyloxy-2-hydroxypropyloxy) hexane, a poly (ethylene glycol) diacrylate (PEGDA) and a pentaerythritol triacrylate.

16. The adhesive sheet of claim 1 , wherein an average thickness of said adhesive sheet is 100 μm to 1 mm.

17. The adhesive sheet of claim 1 , wherein a coordinate value of b* is 6 to 8 when a CIE color coordinate is measured.

Assignees

• Lms Co Ltd

Inventors

• Choi Junsik
• Yeom Jinseok
• Lee Woongki
• Na Hoseong

Classifications

• C08K5/3492

  Triazines · CPC title

• C09J11/06

  organic · CPC title

• C08F220/18

  with acrylic or methacrylic acids · CPC title

• C09J7/00

  Adhesives in the form of films or foils · CPC title

• C08F220/1808

  C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate · CPC title