Polyvinyl chloride and copolyester compositions and articles made using these compositions

Patent metadata

Field	Value
Publication number	US-11512198-B2
Application number	US-201715628735-A
Country	US
Kind code	B2
Filing date	Jun 21, 2017
Priority date	Jun 21, 2017
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

This disclosure pertains to novel polyvinyl chloride compositions containing polyvinyl chloride resins and copolyesters. More particularly, the present disclosure pertains to polyvinyl chloride compositions including high glass transition temperature (Tg) copolyesters to increase the Tg and the heat distortion temperature under load (HDTUL) of the polyvinyl chloride compositions.

First claim

The invention claimed is:

1. A polyvinyl chloride composition comprising a polyvinyl chloride resin and at least one copolyester which comprises:
(a) a dicarboxylic acid component comprising:
(i) about 90 to about 100 mole % of terephthalic acid residues;
(ii) about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and

(b) a glycol component comprising:
(i) about 20 to about 60 mole % of a of a first modifying glycol having 2 to 20 carbon atoms, wherein the modifying glycol is selected from the group consisting of ethylene glycol, neopentyl glycol, isosorbide, 1,4-cyclohexanedimethanol, and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol; and
(ii) about 40 to about 80 mole % of a second different modifying glycol having 2 to 20 carbon atoms, wherein the second different modifying glycol is selected from the group consisting of ethylene glycol, neopentyl glycol, isosorbide, 1,4-cyclohexanedimethanol, and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol;
wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %;
wherein the copolyester is amorphous;
wherein the copolyester has a crystallization half time of about 5 minutes or greater;
wherein the inherent viscosity of the copolyester is from about 0.50 to about 0.80 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.;
wherein the Tg of the copolyester is at least about 90° C. or higher;
wherein the ratio of polyvinyl chloride resin:copolyester on a weight fraction basis is greater than 1; and
wherein said polyvinyl chloride composition comprises a miscible blend comprising said polyvinyl chloride resin and said at least one copolyester.

2. The polyvinyl chloride composition of claim 1 , wherein the Tg of the copolyester is at least about 100° C. or higher.

3. The polyvinyl chloride composition of claim 1 , wherein the copolyester is about 1 to about 100 parts per hundred resin (phr) based on the content of the polyvinyl chloride resin in the composition.

4. The polyvinyl chloride composition of claim 1 , wherein said polyvinyl chloride resin is a polyvinyl chloride resin, a chlorinated polyvinyl chloride resin, or alloys thereof.

5. The polyvinyl chloride composition of claim 1 , wherein said composition further comprising at least one of the following additives: processing aids, plasticizers, stabilizers, impact modifiers, biocides, flame retardants, foaming agents, blowing agents, thermal stabilizers, UV stabilizers, UV absorbers, minerals, pigments, dyes, colorants, fillers, fibers, waxes, fusion promoters, antioxidants, antistatic agents, release agents, lubricants, additional resins, and heat distortion temperature modifiers.

6. The polyvinyl chloride composition of claim 1 , wherein the copolyester has a viscosity range of about 1,000 to about 1,000,000 poise measured at about 170 to about 230° C. and at 10 1/s shear rate.

7. Films, sheets, profiles and injection molded parts comprising the polyvinyl chloride compositions of claim 1 .

8. An article of manufacture comprising the polyvinyl chloride compositions of claim 1 .

9. The article of claim 8 , wherein the article has an increase in Tg and HDTUL (heat distortion temperature under load) of at least 3° C. compared to an article made from the polyvinyl chloride composition without the copolyester.

10. A method of producing a polyvinyl chloride composition comprising: extruding at least one polyvinyl chloride resin and at least one copolyester which comprises:
(a) a dicarboxylic acid component comprising:
(i) about 90 to about 100 mole % of terephthalic acid residues;
(ii) about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and

(b) a glycol component comprising:
(i) about 20 to about 60 mole % of a first modifying glycol having 2 to 20 carbon atoms, wherein the modifying glycol is selected from the group consisting of ethylene glycol, neopentyl glycol, isosorbide, 1,4-cyclohexanedimethanol, and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol; and
(ii) about 40 to about 80 mole % of a second different modifying glycol having 2 to 20 carbon atoms, wherein the second different modifying glycol is selected from the group consisting of ethylene glycol, neopentyl glycol, isosorbide, 1,4-cyclohexanedimethanol, and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol;
wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %, to produce a viscous blend of thermoplastic material;

introducing the blend of thermoplastic material into a calendering, extrusion or injection molding process to produce polyvinyl chloride articles;
wherein the copolyester is amorphous;
wherein the copolyester has a crystallization half time of about 5 minutes or greater;
wherein the inherent viscosity of the copolyester is from about 0.50 to about 0.80 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.;
wherein the Tg of the copolyester is at least about 90° C. or higher;
wherein the ratio of polyvinyl chloride resin:copolyester on a weight fraction basis is greater than 1;
wherein said blend of thermoplastic material is a miscible blend comprising said at least one polyvinyl chloride resin and at least one copolyester; and
wherein the articles have an increase in Tg and HDTUL (heat distortion temperature under load) of at least 3° C. compared to an article made from the polyvinyl chloride composition without the copolyester.

11. A method of producing a polyvinyl chloride composition comprising: compounding a miscible admixture of at least one polyvinyl chloride resin and at least one copolyester which comprises:
(a) a dicarboxylic acid component comprising:
(i) about 90 to about 100 mole % of terephthalic acid residues;
(ii) about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and

(b) a glycol component comprising:
(i) about 20 to about 60 mole % of a first modifying glycol having 2 to 20 carbon atoms, wherein the modifying glycol is selected from the group consisting of ethylene glycol, neopentyl glycol, isosorbide, 1,4-cyclohexanedimethanol, and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol; and
(ii) about 40 to about 80 mole % of a second different modifying glycol having 2 to 20 carbon atoms, wherein the second different modifying glycol is selected from the group consisting of ethylene glycol, neopentyl glycol, isosorbide, 1,4-cyclohexanedimethanol, and 2,2,4,4,-tetramethyl-1,3-cyclobutanediol;
wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %, to produce a viscous thermoplastic material;

extruding the compound through a die to produce pellets; and
introducing the pellets into a calendering, extrusion or injection molding process to produce polyvinyl chloride articles;
wherein the copolyester is amorphous;
wherein the copolyester has a crystallization half time of about 5 minutes or greater;
wherein the inherent viscosity of the copolyester is from about 0.50 to about 0.80 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.;
wherein the Tg of the copolyester is at least about 90° C. or higher;
wherein the ratio of polyvinyl chloride resin:copolyester on a weight fraction basis is greater than 1; and
wherein the articles have an increase in Tg and HDTUL (heat distortion temperature under load) of at least 3° C.

Assignees

• Eastman Chem Co

Inventors

• Young Robert Erik

Classifications

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08L67/02 Primary

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08G63/18

  the acids or hydroxy compounds containing carbocyclic rings · CPC title

• B29K2067/003

  PET, i.e. poylethylene terephthalate · CPC title

• C08L67/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings · CPC title