Thermoplastic composition having improved flame retardant properties

Patent metadata

Field	Value
Publication number	US-11512192-B2
Application number	US-201816771319-A
Country	US
Kind code	B2
Filing date	Dec 13, 2018
Priority date	Dec 15, 2017
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

The invention relates to a composition comprising a) a thermoplastic matrix polymer based on one or more ethylenically unsaturated polymerizable monomer(s), wherein the thermoplastic polymer is selected from the group consisting of polyolefins, polystyrene, polyacrylates, ethylene-vinylacetate copolymer, and copolymers and blends of the aforementioned, b) an inorganic flame retardant, c) a polymer based on one or more ethylenically unsaturated polymerizable monomers and having a plurality of alkoxysilane and/or acetoxysilane groups covalently linked to the polymer, wherein the ethylenically unsaturated polymerizable monomers of component c) are different or have a different composition than the ethylenically unsaturated monomer(s) of component a) and d) a clay.

First claim

The invention claimed is:

1. A process of preparing a thermoplastic polymer composition, the process comprising:
blending a) a thermoplastic polymer, b) an inorganic flame retardant, c) a polymer, and d) a clay,
the thermoplastic polymer a) being based on one or more ethylenically unsaturated polymerizable monomers, the thermoplastic polymer a) including one or more of a polyolefin, a polystyrene, a polyacrylate, an ethylene-vinylacetate copolymer, and copolymers of the aforementioned, and wherein the thermoplastic polymer a) does not contain alkoxysilane groups,
the polymer c) having been obtained by grafting one or more of an ethylenically unsaturated alkoxysilane functional monomer and an ethylenically unsaturated acetoxysilane functional monomer to a polymer based on one or more ethylenically unsaturated polymerizable monomers, and
the polymer c) improving the flame retardant properties of the thermoplastic polymer composition.

2. The process according to claim 1 wherein the one or more ethylenically unsaturated polymerizable monomers of the polymer c) are different from the one or more ethylenically unsaturated monomers of the thermoplastic polymer a), and if thermoplastic polymer a) comprises the ethylene-vinylacetate copolymer, the sum of the differences of the weight-% for each monomer type in the monomer compositions of thermoplastic polymer a) and polymer c) is at least 15 weight %.

3. The process according to claim 1 , wherein the inorganic flame retardant b) includes one or more of aluminum trihydroxide and magnesium dihydroxide.

4. The process according to claim 1 , wherein at least 15 mol-% of the one or more ethylenically unsaturated polymerizable monomers on which polymer c) is based are different from the one or more ethylenically unsaturated polymerizable monomers on which thermoplastic polymer a) is based.

5. The process according to claim 1 , wherein-the polymer c) is included in an amount in the range of 0.1 to 10.0% by weight, calculated on the total weight of thermoplastic polymer a) and the inorganic flame retardant b).

6. The process according to claim 1 , wherein the polymer c) comprises the grafted one or more of the ethylenically unsaturated alkoxysilane functional monomer and the ethylenically unsaturated acetoxysilane functional monomer in an amount in the range of 0.1 to 10.0% by weight, calculated on the weight of polymer c).

7. The process according to claim 1 , wherein-the thermoplastic polymer a) includes one or more of polyethylene, polypropylene, a copolymer of ethylene with another olefin, and a copolymer of propylene with another olefin.

8. An electrical component comprising an electrically conductive element and an electrical insulator, wherein the electrical insulator comprises a composition, the composition-comprising:
a) thermoplastic polymer based on one or more ethylenically unsaturated polymerizable monomers, the thermoplastic polymer a) including one or more of a polyolefin, a polystyrene, a polyacrylate, an ethylene vinylacetate copolymer, and copolymers of the aforementioned, and wherein the thermoplastic polymer a) does not contain alkoxysilane groups,
b) an inorganic flame retardant,
c) a polymer based on one or more ethylenically unsaturated polymerizable monomers, and the polymer c) having been obtained by grafting at least one ethylenically unsaturated alkoxysilane and/or acetoxysilane functional monomer to a polymer based on one or more ethylenically unsaturated polymerizable monomers, the polymer c) improving the flame retardant properties of the thermoplastic polymer composition, and
d) a clay.

9. The electrical component according to claim 8 , wherein the electrical component is a cable comprising an electrically conductive core and an electrically insulating cable.

10. A composition comprising
a) a thermoplastic polymer based on one or more ethylenically unsaturated polymerizable monomers, the thermoplastic polymer a) including one or more of a polyolefin, a polystyrene, a polyacrylate, an ethylene-vinylacetate copolymer, and copolymers of the aforementioned, and wherein the thermoplastic polymer a) does not contain alkoxysilane groups,
b) an inorganic flame retardant,
c) a polymer based on one or more ethylenically unsaturated polymerizable monomers, the polymer c) including a plurality of one or more of alkoxysilane groups and acetoxysilane groups, and having been obtained by grafting at least one ethylenically unsaturated alkoxysilane and/or acetoxysilane functional monomer to a polymer based on one or more ethylenically unsaturated polymerizable monomers, wherein the one or more ethylenically unsaturated polymerizable monomers on which polymer c) is based are different from the one or more ethylenically unsaturated-monomers on which thermoplastic polymer a) is based, and if thermoplastic polymer a) comprises the ethylene-vinylacetate copolymer, the sum of the differences of the weight-% for each monomer type in the monomer compositions of thermoplastic polymer a) and polymer c) is at least 15 weight-%, the polymer c) improving the flame retardant properties of the thermoplastic polymer composition, and
d) a clay.

11. The process according to claim 1 , wherein the polymer c) is included in an amount in the range of 0.5 to 7.0% by weight, calculated on the total weight of thermoplastic polymer a) and the inorganic flame retardant b).

12. The process according to claim 1 , wherein the polymer c) comprises the grafted one or more of the ethylenically unsaturated alkoxysilane functional monomer and the ethylenically unsaturated acetoxysilane functional monomer in an amount in the range of 0.2 to 6.0% by weight, calculated on the weight of polymer c).

13. The process according to claim 1 , wherein the polymer c) comprises the grafted one or more of the ethylenically unsaturated alkoxysilane functional monomer and the ethylenically unsaturated acetoxysilane functional monomer in an amount in the range of 0.3 to 5.0% by weight, calculated on the weight of polymer c).

14. A composition comprising:
a) a thermoplastic polymer comprising one or more of a polyolefin, a polystyrene, a polyacrylate, an ethylene-vinylacetate copolymer, and copolymers thereof, the thermoplastic polymer a) not containing alkoxysilane groups,
b) an inorganic flame retardant,
c) a polymer including a structure formed from a material comprising ethylenically unsaturated monomers and having been obtained by grafting one or more of ethylenically unsaturated alkoxysilane functional monomers and acetoxysilane functional monomers to a polymer based on one or more ethylenically unsaturated polymerizable monomers, wherein the polymer c) is included in the range of 0.5 to 7.0% by weight, calculated on the total weight of thermoplastic polymer a) and the inorganic flame retardant b),
the polymer c) improving flame the retardant properties of the thermoplastic polymer composition, and
d) a clay.

15. The composition according to claim 14 , wherein at least 15 mol-% of the ethylenically unsaturated polymerizable monomers used to form the structure of polymer c) are different from the ethylenically unsaturated monomers used to form the structure of thermoplastic polymer a).

16. The process according to claim 1 , wherein the thermoplastic polymer a) comprises an ethylene-vinylacetate copolymer.

17. The process according to claim 1 , wherein the thermoplastic polymer a) comprises an ethylene-vinylacetate copolymer and a polyolefin.

18. The process according to claim 1 , the polymer c) having been obtained by grafting an ethylenically unsat

Assignees

• Byk Chemie Gmbh

Inventors

• Piestert Frederik
• Rapthel Inno
• Kröller Thorsten
• Wilms Jochen
• Levering Dennis
• Borth Markus
• Eichler Hans-Jürgen
• Oostendorp Patricia

Classifications

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• H01B3/442

  from aromatic vinyl compounds · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title

• H01B7/295

  using material resistant to flame · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title