Process for preparing rodlike magnetiic ferroferric oxide material and use thereof

Patent metadata

Field	Value
Publication number	US-11512007-B2
Application number	US-202016734970-A
Country	US
Kind code	B2
Filing date	Jan 6, 2020
Priority date	Jan 4, 2019
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

The present invention relates to a process for preparing a rodlike magnetic ferroferric oxide (Fe3O4) material and use thereof. The preparation includes the following steps: step 1: magnetic Fe3O4 nanoparticle preparation; and step 2: self-assembly of magnetic Fe3O4@SiO2 nanoparticles into a rodlike magnetic material. When in use, the rodlike magnetic Fe3O4 material prepared by the process according to claim 1 is used in micro- and nano-motors, which can implement rotation and deflection in an external magnetic field. The present invention provides a process for preparing a rodlike magnetic Fe3O4 material. The rodlike magnetic ferroferric oxide material prepared by the process is suitable for mass production on an industrial scale, featuring identifiable direction of the magnetic moment, strong magnetism, good magnetic response, simple process, and low cost.

First claim

What is claimed is:

1. A process for preparing a rodlike magnetic ferroferric oxide (Fe 3 O 4 ) material, comprising the following steps:
Step 1: preparation of magnetic Fe 3 O 4 nanoparticles
(1) Dissolving 0.675 g of FeCl 3 .6H 2 O in 35 mL of ethylene glycol, and mixing to obtain solution A1;
(2) Adding 1.925 g of CH 3 COONH 4 in solution A1, and stirring for 30 min to obtain solution A2; and
(3) Charging solution A2 into a reactor, heating to 200° C., heating and reacting for 12 h at a constant temperature, cooling down to room temperature, centrifuging and washing 4-6 times, and drying in air at room temperature to obtain Fe 3 O 4 nanoparticles;
Step 2: preparation of a rodlike magnetic Fe 3 O 4 @SiO 2 nanoparticle material
(1) Dissolving 4 mg of Fe 3 O 4 obtained in step 1 in a mixture of 5 mL of deionized water and 25 mL of isopropanol, and sonicating for 30 min to obtain mixed solution B1;
(2) Adding 0.5 mL of ammonia water and 30 μL of tetraethyl orthosilicate (TEOS) into mixed solution B1 to initiate reaction, placing on a tube roller shaker, and reacting for 6 h at room temperature to obtain mixed solution B2; and
(3) After reaction, filtering to obtain filter residues, and washing twice separately with ethanol and deionized water to obtain a rodlike magnetic Fe 3 O 4 @SiO 2 material; storing the magnetic Fe 3 O 4 @SiO 2 material in 30 mL of ethanol for use;
wherein a rodlike structure is formed based on the mechanism that a sub-stable structure formed by self-assembly of magnetic particles is cured to form a permanently fixed structure during SiO 2 shell coating.

2. A process for preparing a rodlike magnetic ferroferric oxide (Fe 3 O 4 ) material, comprising the following steps:
Step 1: preparation of magnetic Fe 3 O 4 nanoparticles
(1) Dissolving 0.675 g of FeCl 3 .6H 2 O in 35 mL of ethylene glycol, and mixing to obtain solution A1;
(2) Adding 1.925 g of CH 3 COONH 4 in solution A1, and stirring for 30 min to obtain solution A2; and
(3) Charging solution A2 into a reactor, heating to 200° C., heating and reacting for 12 h at a constant temperature, cooling down to room temperature, centrifuging and washing 4-6 times, and drying in air at room temperature to obtain Fe 3 O 4 nanoparticles;
Step 2: preparation of a rodlike magnetic Fe 3 O 4 @SiO 2 nanoparticle material
(1) Dissolving 4 mg of Fe 3 O 4 obtained in step 1 in a mixture of 5 mL of deionized water and 25 mL of isopropanol, and sonicating for 30 min to obtain mixed solution B1;
(2) Adding 0.5 mL of ammonia water and 30 μL of tetraethyl orthosilicate (TEOS) into mixed solution B1 to initiate reaction, placing on a tube roller shaker, and reacting for 6 h at room temperature to obtain mixed solution B2; and
(3) After reaction, filtering to obtain filter residues, and washing twice separately with ethanol and deionized water to obtain a rodlike magnetic Fe 3 O 4 @SiO 2 material; storing the magnetic Fe 3 O 4 @SiO 2 material in 30 mL of ethanol for use;
wherein a rodlike structure is formed based on the mechanism that a sub-stable structure formed by self-assembly of magnetic particles is cured to form a permanently fixed structure during SiO 2 shell coating; and
wherein a diameter of the Fe 3 O 4 nanoparticle is 200 to 400 nm.

Assignees

• Harbin Inst Technology Shenzhen
• Harbin Inst Technology

Inventors

• Feng Huanhuan
• Liu Yuhuan
• Ma Xing
• Zheng Tingting
• Zhao Weiwei
• Zhang Jiaheng

Classifications

• C01G49/08 Primary

  Ferroso-ferric oxide [Fe3O4] · CPC title

• C01P2004/16

  Nanowires or nanorods, i.e. solid nanofibres with two nearly equal dimensions between 1-100 nanometer · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• H01F1/0072

  one dimensional, i.e. linear or dendritic nanostructures · CPC title