Rechargeable lithium battery

Patent metadata

Field	Value
Publication number	US-11508992-B2
Application number	US-202016863679-A
Country	US
Kind code	B2
Filing date	Apr 30, 2020
Priority date	May 3, 2019
Publication date	Nov 22, 2022
Grant date	Nov 22, 2022

Abstract

Rechargeable lithium battery includes a negative electrode including a negative active material layer and a negative electrode functional layer disposed on the negative active material layer; a positive electrode including a positive active material; an electrolyte solution, wherein the negative electrode functional layer includes flake-shaped polyethylene particles, the electrolyte solution includes a lithium salt and a non-aqueous organic solvent, and the non-aqueous organic solvent includes about 60 volume % to about 80 volume % of a propionate-based solvent and about 20 volume % to about 40 volume % of a carbonate-based solvent.

First claim

What is claimed is:

1. A rechargeable lithium battery, comprising:
a negative electrode, comprising:
a negative active material layer; and
a negative electrode functional layer disposed on the negative active material layer;

a positive electrode, comprising:
a positive active material; and

an electrolyte solution,
wherein the negative electrode functional layer comprises:
flake-shaped polyethylene particles,

wherein the electrolyte solution comprises:
a lithium salt; and
a non-aqueous organic solvent, and

wherein the non-aqueous organic solvent comprises:
about 60 volume % to about 80 volume % of a propionate-based solvent; and
about 20 volume % to about 40 volume % of a carbonate-based solvent.

2. The rechargeable lithium battery of claim 1 , wherein the propionate-based solvent comprises: at least one selected from methyl propionate, ethyl propionate, propyl propionate, and butyl propionate.

3. The rechargeable lithium battery of claim 1 , wherein the carbonate-based solvent comprises: at least one selected from ethylene carbonate, propylene carbonate, butylene carbonate, fluoroethylene carbonate, dimethyl carbonate, methyl ethyl carbonate, diethyl carbonate, methylpropyl carbonate, and methylbutyl carbonate.

4. The rechargeable lithium battery of claim 1 , wherein the electrolyte solution comprises an additive,
wherein the additive is included in an amount of about 3 wt % to about 20 wt % based on a total amount of the electrolyte solution.

5. The rechargeable lithium battery of claim 1 , wherein the flake-shaped polyethylene particles have a particle size of about 1 μm to about 8 μm.

6. The rechargeable lithium battery of claim 1 , wherein a ratio of the long axis length relative to the short axis length of the flake-shaped polyethylene particles is about 1 through about 5.

7. The rechargeable lithium battery of claim 1 , wherein the flake-shaped polyethylene particles have a thickness of about 0.2 μm to about 4 μm.

8. The rechargeable lithium battery of claim 1 , wherein the negative electrode functional layer optionally further comprises:
inorganic particles; and
a binder.

9. The rechargeable lithium battery of claim 8 , wherein a sum amount of the flake-shaped polyethylene particles and an amount of the inorganic particles over the binder are a weight ratio of about 80:20 to about 99:1.

10. The rechargeable lithium battery of claim 8 , wherein the flake-shaped polyethylene particles and the inorganic particles are included in a weight ratio of 95:5 to 10:90.

11. The rechargeable lithium battery of claim 1 , wherein the negative electrode functional layer has a thickness of about 1 μm to about 10 μm.

12. The rechargeable lithium battery of claim 1 , wherein a ratio between thicknesses of the negative active material layer and the negative electrode functional layer is about 50:1 to about 10:1.

13. The rechargeable lithium battery of claim 1 , wherein the positive active material layer comprises:
a first positive active material comprising:
at least one of a composite oxide of metal selected from cobalt, manganese, nickel, and a combination thereof; and
lithium; and

a second positive active material comprising:
a compound represented by Chemical Formula 1
Li a Fe 1−x M x PO 4   [Chemical Formula 1]

wherein, in Chemical Formula 1, 0.90≤a≤1.8, 0≤x≤0.7, and M is Mn, Co, Ni, or a combination thereof.

14. The rechargeable lithium battery of claim 13 , wherein the first positive active material comprises: one of LiCoO 2 , Li b M 1 1−y1−z1 M 2 y1 M 3 z1 O 2 (0.9≤b≤1.8, 0≤y1≤1, 0≤z1≤1, 0≤y1+z1≤1, M 1 , M 2 , and M 3 are independently a metal of Ni, Co, Mn, Al, Sr, Mg, or La), and a combination thereof.

15. The rechargeable lithium battery of claim 13 , wherein the second positive active material comprises LiFePO 4 .

16. The rechargeable lithium battery of claim 13 , wherein the positive active material layer further comprises:
a positive electrode functional layer disposed on the positive active material layer.

17. The rechargeable lithium battery of claim 16 , wherein
the first positive active material is included in the positive active material layer, and
the second positive active material is included in at least one of the positive active material layer and the positive electrode functional layer.

18. The rechargeable lithium battery of claim 13 , wherein the first positive active material and the second positive active material are included in a weight ratio of about 97:3 to about 80:20.

19. The rechargeable lithium battery of claim 13 , wherein the first positive active material is included in an amount of about 70 wt % to about 99 wt % based on a total amount of the positive active material layer, and
the second positive active material is included in an amount of about 1 wt % to about 30 wt % based on a total amount of the positive active material layer.

20. The rechargeable lithium battery of claim 1 , wherein the flake-shaped polyethylene particles have a melting point of between 90° C. and 160° C. and a weight average molecular weight of between 300 g/mole to 10,000 g/mole.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Ha Jaehwan
• Kim Kijun
• Yoo Heeeun
• Yoon Yeonhee
• Lee Kyuseo
• Lee Dongmyung

Classifications

• H01M4/366

  as layered products · CPC title

• H01M4/364

  as mixtures · CPC title

• H01M4/133 Primary

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M2300/0042

  Four or more solvents · CPC title

• H01M10/0569 Primary

  characterised by the solvents · CPC title