Electrode, secondary battery, battery pack, vehicle and stationary power source

Patent metadata

Field	Value
Publication number	US-11508957-B2
Application number	US-202016804322-A
Country	US
Kind code	B2
Filing date	Feb 28, 2020
Priority date	Sep 13, 2018
Publication date	Nov 22, 2022
Grant date	Nov 22, 2022

Abstract

An electrode comprises a current collector; and an active material-containing layer having active materials on the current collector. The active material-containing layer has a first surface contacting the current collector and a second surface which is opposite side of the first surface. At least one part of the second surface is covered by a compound containing Zn. When an image of the second surface is taken by Scanning Electron Microscope, the image is divided into 100 blocks, a ratio of existence of blocks having hexagonal platelet shaped compound containing Zn to the 100 blocks is calculated, and the ratio of existence of blocks is calculated with respect to 10 images, an average of the ratio of existence of blocks with respect to the 10 images is 20% or less (including 0).

First claim

What is claimed is:

1. A secondary battery comprising:
an aqueous electrolyte, the aqueous electrolyte comprising 0.001 wt % to 0.1 wt % of at least one selected from the group consisting of unsaturated alcohol and coumarin;
a positive electrode; and
a negative electrode,
the negative electrode comprising:
a current collector; and
an active material-containing layer having active materials on the current collector,
wherein the active material-containing layer has a first surface contacting the current collector and a second surface which is opposite side of the first surface,
at least one part of the second surface is covered by a compound containing Zn, and
when an image of the second surface is taken by Scanning Electron Microscope, the image is divided into 100 blocks, a ratio of existence of blocks having hexagonal platelet shaped compound containing Zn to the 100 blocks is calculated, and the ratio of existence of blocks is calculated with respect to 10 images,
an average of the ratio of existence of blocks with respect to the 10 images is 20% or less (including 0).

2. The secondary battery according to claim 1 ,
wherein the average of existence of blocks with respect to the 10 images is 15% or less (including 0).

3. The secondary battery according to claim 1 ,
wherein the compound containing Zn comprises at least one element selected from the group consisting of Sn, Hg, In, Cd, and Pb.

4. The secondary battery according to claim 1 ,
wherein the aqueous electrolyte comprises an organic solvent which is comprised 20 vol % or less in the aqueous electrolyte.

5. The secondary battery according to claim 1 ,
wherein the electrode active material in the negative electrode has a lithium ion insertion/extraction potential range of 1 V or more and 3 V or less (vs. Li/Li + ) based on metallic lithium electrical potential.

6. The secondary battery according to claim 1 ,
wherein a positive active material in the positive electrode has a lithium ion insertion/extraction potential range of 2.5 V or more and 5.5 V or less (vs. Li/Li + ) based on metallic lithium electrical potential.

7. A battery pack comprising the secondary battery according to claim 1 .

8. The battery pack according to claim 7 , further comprising:
an external terminal for electrically connecting; and
a protective circuit.

9. The battery pack according to claim 7 ,
wherein a plurality of the secondary batteries are electrically connected in series, in parallel or a combination of series and parallel.

10. A vehicle comprising the battery pack according to claim 7 .

11. The vehicle according to claim 10 ,
wherein the battery pack is recharged by regenerative energy of driving forth of the vehicle.

12. A stationary power source comprising the battery pack according to claim 7 .

13. A secondary battery comprising:
an aqueous electrolyte, the aqueous electrolyte comprising 0.001 wt % to 0.1 wt % of at least one selected from the group consisting of unsaturated alcohol and coumarin;
a positive electrode; and
a negative electrode,
the negative electrode comprising:
a current collector; and
an active material-containing layer on the current collector, the active material-containing layer comprising active materials and having a first surface in contact with the current collector and a second surface on a side opposite thereto,
at least a part of the second surface being covered by a compound containing Zn, and an average of a ratio of existence of a hexagonal platelet shaped compound comprising Zn is 20% or less (including 0).

Assignees

• Toshiba Kk

Inventors

• Hotta Yasuyuki
• Matsuno Shinsuke
• Takami Norio

Classifications

• H01M4/42

  Alloys based on zinc · CPC title

• H01M4/02

  Electrodes composed of, or comprising, active material · CPC title

• H01M4/485 Primary

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M2220/10

  Batteries in stationary systems, e.g. emergency power source in plant · CPC title