Solid-state energy storage devices and methods of making the same

Patent metadata

Field	Value
Publication number	US-11508951-B2
Application number	US-201916682064-A
Country	US
Kind code	B2
Filing date	Nov 13, 2019
Priority date	Nov 13, 2018
Publication date	Nov 22, 2022
Grant date	Nov 22, 2022

Abstract

An aspect of the present disclosure is a system that includes a first deposition system that includes a first cylinder having a first outer surface configured to hold a first substrate, a first spray nozzle configured to receive at least a first fluid, and a first fiber nozzle configured to receive at least a second fluid, where the first spray nozzle is configured to operate at a first voltage, the first fiber nozzle is configured to operate at a second voltage, the first cylinder is configured to be electrically connected to ground, the first spray nozzle is configured to apply onto the substrate a first plurality of at least one of particles or droplets from the first fluid, the first fiber nozzle is configured to apply onto the substrate a first fiber from the second fluid, and the first plurality of particles or droplets and the first fiber combine to form a first composite layer on the substrate.

First claim

What is claimed is:

1. A roll-to-roll system for manufacturing a solid-state battery, the system comprising:
a first deposition system configured to deposit a first composite electrode layer onto a substrate, the first deposition system comprising:
a first cylinder configured to receive the substrate;
a first spray nozzle configured to receive a first fluid comprising a first electrode active material; and
a first fiber nozzle configured to receive a second fluid comprising a first polymer and a first salt, wherein:
the first spray nozzle is configured to transform the first fluid into at least one of a first plurality of particles or a first plurality of droplets,
the first fiber nozzle is configured to transform the second fluid into a first fiber,
the first spray nozzle is configured to direct the at least one of the first plurality of particles or the first plurality of droplets towards the first cylinder and a first fixed location in space,
the first fiber nozzle is configured to direct the first fiber towards the first cylinder and the first fixed location in space, and
the first spray nozzle and the first fiber nozzle are configured such that the at least one of the first plurality of particles or the first plurality of droplets and the first fiber combine on the substrate in the first fixed location in space to form the first composite electrode layer;

a second deposition system configured to deposit a solid electrolyte layer onto the first composite electrode layer; and
a third deposition system configured to deposit a second composite electrode layer onto the solid electrolyte layer.

2. The system of claim 1 , wherein the first spray nozzle comprises a first tip having an inside diameter between 0.05 mm and 3.0 mm.

3. The system of claim 1 , wherein the first fluid comprises a cathode active material.

4. The system of claim 1 , wherein the first fiber nozzle comprises a second tip having an inside diameter between 0.05 mm and 3.0 mm.

5. The system of claim 1 , wherein the first polymer comprises at least one of poly(ethylene oxide), polyacrylonitrile, poly(vinylidene fluoride), or poly(methyl methacrylate).

6. The system of claim 1 , wherein the first salt comprises at least one of LiClO 4 , LiTFSI, or LiFSI.

7. The system of claim 1 , wherein the substrate comprises an electrically conductive material.

8. The system of claim 1 , wherein:
the first deposition system further comprises a compression system positioned downstream of the first deposition system and configured to transform the first composite electrode layer having a first solid density to a second composite layer having a second solid density, and
the second solid density is greater than the first solid density.

9. The system of claim 8 , wherein:
the first compression system comprises:
a first roller positioned adjacent to a second roller;
the first roller has a first outer surface,
the second roller has a second outer surface,
the first outer surface and the second outer surface are positioned substantially parallel to each other,
the first outer surface and the second outer surface are separated by a gap, and
the substrate and first composite electrode layer are configured to pass through the first gap.

10. The system of claim 9 , wherein the gap is between 1 μm and about 500 μm.

11. The system of claim 1 , wherein:
the second deposition system comprises:
a second cylinder configured to receive the substrate with the first composite electrode layer deposited thereon; and
a second fiber nozzle configured to receive a third fluid comprising a second polymer and a second salt, wherein:
the second fiber nozzle is configured to transform the third fluid into a second fiber, and
the second fiber nozzle is configured to direct the second fiber towards the second cylinder such that the second fiber forms the solid electrolyte layer on the first composite electrode layer.

12. The system of claim 11 , wherein:
the third deposition system comprises:
a third cylinder configured to receive the substrate with the first composite electrode layer and the solid electrolyte layer deposited thereon;
a second spray nozzle configured to receive a fourth fluid comprising a second electrode active material; and
a third fiber nozzle configured to receive a fifth fluid comprising a third polymer and a third salt, wherein:
the second spray nozzle is configured to transform the fourth fluid into at least one of a second plurality of particles or a second plurality of droplets,
the third fiber nozzle is configured to transform the fifth fluid into a third fiber,
the second spray nozzle is configured to direct the at least one of the second plurality of particles or the second plurality of droplets towards the third cylinder and a second fixed location in space,
the third fiber nozzle is configured to direct the third fiber towards the third cylinder and the second fixed location in space, and
the second spray nozzle and the third fiber nozzle are configured such that the at least one of the second plurality of particles or the second plurality of droplets and the third fiber combine on the solid electrolyte layer in the second fixed location in space to form the second composite electrode layer.

13. The system of claim 1 , wherein the first cylinder rotates at a speed between 0.1 RPM and 100 RPM.

14. The system of claim 1 , wherein the first cylinder has an outer surface operated at a temperature between 0° C. and 200° C.

15. The system of claim 1 , wherein the first cylinder has a circumference between 2 cm and 250 cm.

16. The system of claim 1 , wherein the first cylinder has a width between 2 cm and 250 cm.

17. The system of claim 1 , wherein the first spray nozzle is configured to operate at a first voltage between 1 kV and 100 kV.

18. The system of claim 1 , wherein the first fiber nozzle is configured to operate at a second voltage between 1 kV and 100 kV.

Assignees

• Alliance Sustainable Energy
• Univ Colorado Regents

Inventors

• Ban Chunmei
• Hafner Simon Elnicki
• Lee Se-Hee

Classifications

• H01M4/043

  involving compressing or compaction · CPC title

• H01M4/1391

  of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/0404 Primary

  by coating on electrode collectors · CPC title

• H01M4/0409

  by a doctor blade method, slip-casting or roller coating · CPC title

• H01M4/0419 Primary

  involving spraying · CPC title